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Smialkowski M, Siegmund D, Pellumbi K, et al. Seleno-analogues of pentlandites (Fe. Chem Commun (Camb). 2019;55(60):8792-8795doi: 10.1039/c9cc01842e.
Smialkowski, M., Siegmund, D., Pellumbi, K., Hensgen, L., Antoni, H., Muhler, M., & Apfel, U. P. (2019). Seleno-analogues of pentlandites (Fe. Chemical communications (Cambridge, England), 55(60), 8792-8795. https://doi.org/10.1039/c9cc01842e
Smialkowski, Mathias, et al. "Seleno-analogues of pentlandites (Fe." Chemical communications (Cambridge, England) vol. 55,60 (2019): 8792-8795. doi: https://doi.org/10.1039/c9cc01842e
Smialkowski M, Siegmund D, Pellumbi K, Hensgen L, Antoni H, Muhler M, Apfel UP. Seleno-analogues of pentlandites (Fe. Chem Commun (Camb). 2019 Jul 23;55(60):8792-8795. doi: 10.1039/c9cc01842e. PMID: 31041942.
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Chem Commun (Camb). 2019 Jul 23;55(60):8792-8795. doi: 10.1039/c9cc01842e.

Seleno-analogues of pentlandites (Fe.

Chemical communications (Cambridge, England)

Mathias Smialkowski, Daniel Siegmund, Kevinjeorjios Pellumbi, Lars Hensgen, Hendrik Antoni, Martin Muhler, Ulf-Peter Apfel

Affiliations

  1. Inorganic Chemistry I - Bioinorganic Chemistry, Ruhr University Bochum, Universitätsstrasse 150, 44801 Bochum, Germany. [email protected].

PMID: 31041942 DOI: 10.1039/c9cc01842e

Abstract

We herein present a series of hitherto unprecedented seleno-pentlandites (Fe4.5Ni4.5S8-YSeY). By analysing the influence of S/Se exchange on the catalyst structure and activity in the electrochemical hydrogen evolution reaction we herein showcase the potential and limitations of homologous S/Se exchanges within pentlandite HER catalysts.

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