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Solid State Nucl Magn Reson. 2019 Sep;101:101-109. doi: 10.1016/j.ssnmr.2019.05.004. Epub 2019 May 13.

Probing Jahn-Teller distortions in Mn(acac).

Solid state nuclear magnetic resonance

Kirill Levin, Scott Kroeker

Affiliations

  1. Department of Chemistry, University of Manitoba, Winnipeg, Manitoba, R3T 2N2, Canada.
  2. Department of Chemistry, University of Manitoba, Winnipeg, Manitoba, R3T 2N2, Canada. Electronic address: [email protected].

PMID: 31150959 DOI: 10.1016/j.ssnmr.2019.05.004

Abstract

The structural and electronic properties of solid coordination compounds are of great interest in a wide variety of applications. The sensitivity of solid-state NMR to local structural environments in the presence of a transition metal with unpaired spins is demonstrated through

Copyright © 2019. Published by Elsevier Inc.

Keywords: Contact shifts; Density-functional theory; Jahn-teller distortion; Paramagnetic NMR; Polymorphism; Solid-state NMR

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