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Cashman MA, Kirschenbaum L, Holowachuk J, et al. Identification of hydroxyl and sulfate free radicals involved in the reaction of 1,4-dioxane with peroxone activated persulfate oxidant. J Hazard Mater. 2019;380:120875doi: 10.1016/j.jhazmat.2019.120875.
Cashman, M. A., Kirschenbaum, L., Holowachuk, J., & Boving, T. B. (2019). Identification of hydroxyl and sulfate free radicals involved in the reaction of 1,4-dioxane with peroxone activated persulfate oxidant. Journal of hazardous materials, 380120875. https://doi.org/10.1016/j.jhazmat.2019.120875
Cashman, Michaela A, et al. "Identification of hydroxyl and sulfate free radicals involved in the reaction of 1,4-dioxane with peroxone activated persulfate oxidant." Journal of hazardous materials vol. 380 (2019): 120875. doi: https://doi.org/10.1016/j.jhazmat.2019.120875
Cashman MA, Kirschenbaum L, Holowachuk J, Boving TB. Identification of hydroxyl and sulfate free radicals involved in the reaction of 1,4-dioxane with peroxone activated persulfate oxidant. J Hazard Mater. 2019 Dec 15;380:120875. doi: 10.1016/j.jhazmat.2019.120875. Epub 2019 Jul 13. PMID: 31336268.
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J Hazard Mater. 2019 Dec 15;380:120875. doi: 10.1016/j.jhazmat.2019.120875. Epub 2019 Jul 13.

Identification of hydroxyl and sulfate free radicals involved in the reaction of 1,4-dioxane with peroxone activated persulfate oxidant.

Journal of hazardous materials

Michaela A Cashman, Louis Kirschenbaum, Justin Holowachuk, Thomas B Boving

Affiliations

  1. University of Rhode Island, Department of Geosciences. Kingston, RI, USA.
  2. University of Rhode Island, Department of Chemistry. Kingston, RI, USA.
  3. University of Rhode Island, Department of Geosciences. Kingston, RI, USA; University of Rhode Island, Department of Civil Engineering. Kingston, RI, USA. Electronic address: [email protected].

PMID: 31336268 DOI: 10.1016/j.jhazmat.2019.120875

Abstract

This research investigates the formation of free radical intermediates in an advanced oxidation processes (AOP) capable of destroying recalcitrant contaminants. The AOP studied is marketed as OxyZone® and relies on the premise of successful persulfate activation by peroxone (hydrogen peroxide plus ozone) and the formation of free radicals. The goal of this research was to determine which radicals are involved in the treatment of the model contaminant, 1,4-dioxane, which is a ubiquitous, recalcitrant organic groundwater pollutant difficult to destroy by conventional oxidants. In a parallel study, the peroxone activation persulfate (PAP) solution investigated herein rapidly degraded 1,4-dioxane. The degradation rates of 1,4-dioxane were measured as a function the oxidant:contaminant ratio. Its degradation products or mechanism were not investigated, however. Electron paramagnetic resonance (EPR) spectroscopy spin trapping was used to identify radicals produced in the oxidant solution, its active ingredients, and their possible interplay. The data presented herein indicate that the combination of hydrogen peroxide and dissolved ozone in the presence of persulfate results in the co-occurrence hydroxyl and sulfate radicals and possibly superoxide/hydroperoxyl radicals. These findings progress our understanding of the chemical radicals formed during PAP treatment of aqueous phase contaminants, such as 1,4-dioxane.

Copyright © 2019 Elsevier B.V. All rights reserved.

Keywords: 1,4-Dioxane; Advanced oxidation process (AOP); Electron paramagnetic resonance (EPR); Peroxone activated persulfate (PAP); Radicals

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