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Cervantes-Reyes A, Rominger F, Rudolph M, et al. Gold(I) Complexes Stabilized by Nine- and Ten-Membered N-Heterocyclic Carbene Ligands. Chemistry. 2019;25(50):11745-11757doi: 10.1002/chem.201902458.
Cervantes-Reyes, A., Rominger, F., Rudolph, M., & Hashmi, A. S. K. (2019). Gold(I) Complexes Stabilized by Nine- and Ten-Membered N-Heterocyclic Carbene Ligands. Chemistry (Weinheim an der Bergstrasse, Germany), 25(50), 11745-11757. https://doi.org/10.1002/chem.201902458
Cervantes-Reyes, Alejandro, et al. "Gold(I) Complexes Stabilized by Nine- and Ten-Membered N-Heterocyclic Carbene Ligands." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 25,50 (2019): 11745-11757. doi: https://doi.org/10.1002/chem.201902458
Cervantes-Reyes A, Rominger F, Rudolph M, Hashmi ASK. Gold(I) Complexes Stabilized by Nine- and Ten-Membered N-Heterocyclic Carbene Ligands. Chemistry. 2019 Sep 06;25(50):11745-11757. doi: 10.1002/chem.201902458. Epub 2019 Aug 08. PMID: 31310385; PMCID: PMC6852534.
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Chemistry. 2019 Sep 06;25(50):11745-11757. doi: 10.1002/chem.201902458. Epub 2019 Aug 08.

Gold(I) Complexes Stabilized by Nine- and Ten-Membered N-Heterocyclic Carbene Ligands.

Chemistry (Weinheim an der Bergstrasse, Germany)

Alejandro Cervantes-Reyes, Frank Rominger, Matthias Rudolph, A Stephen K Hashmi

Affiliations

  1. Organisch-Chemisches Institut, Heidelberg University, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
  2. Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, 21589, Saudi Arabia.

PMID: 31310385 PMCID: PMC6852534 DOI: 10.1002/chem.201902458

Abstract

Nine- and ten-membered N-heterocyclic carbene (NHC) ligands have been developed and for the first time their gold(I) complexes were synthesized. The protonated NHC pro-ligands 2 a-h were prepared by the reaction of readily available N,N'-diarylformamidines with bis-electrophilic building blocks, followed by anion exchange. In situ deprotonation of the tetrafluoroborates 2 a-h with tBuOK in the presence of AuCl(SMe

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: N-heterocyclic carbenes; carbenes; catalysis; gold; ligands

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