Display options
Cite
Li YY, He TY, Dai RR, et al. Bifunctional Gyroidal MOFs: Highly Efficient Lewis Base and Lewis Acid Catalysts. Chem Asian J. 2019;14(20):3682-3687doi: 10.1002/asia.201900853.
Li, Y. Y., He, T. Y., Dai, R. R., Huang, Y. L., Zhou, X. P., Chen, T., & Li, D. (2019). Bifunctional Gyroidal MOFs: Highly Efficient Lewis Base and Lewis Acid Catalysts. Chemistry, an Asian journal, 14(20), 3682-3687. https://doi.org/10.1002/asia.201900853
Li, Yan Yan, et al. "Bifunctional Gyroidal MOFs: Highly Efficient Lewis Base and Lewis Acid Catalysts." Chemistry, an Asian journal vol. 14,20 (2019): 3682-3687. doi: https://doi.org/10.1002/asia.201900853
Li YY, He TY, Dai RR, Huang YL, Zhou XP, Chen T, Li D. Bifunctional Gyroidal MOFs: Highly Efficient Lewis Base and Lewis Acid Catalysts. Chem Asian J. 2019 Oct 15;14(20):3682-3687. doi: 10.1002/asia.201900853. Epub 2019 Jul 30. PMID: 31339652.
Copy Download .nbib Format: NLM
Share it on

Chem Asian J. 2019 Oct 15;14(20):3682-3687. doi: 10.1002/asia.201900853. Epub 2019 Jul 30.

Bifunctional Gyroidal MOFs: Highly Efficient Lewis Base and Lewis Acid Catalysts.

Chemistry, an Asian journal

Yan Yan Li, Tian-Ya He, Rui-Rong Dai, Yong-Liang Huang, Xiao-Ping Zhou, Tianfeng Chen, Dan Li

Affiliations

  1. College of Chemistry and Materials Science, Jinan University, Guangzhou, 510632, P. R. China.
  2. Department of Chemistry, Shantou University, Guangdong, 515063, P. R. China.

PMID: 31339652 DOI: 10.1002/asia.201900853

Abstract

A family of gyroidal metal-organic frameworks (STUs) composited with transition metal ions and bi-imidazolate ligands (BIm) were prepared and applied as both Lewis base and acid catalysts. Benefiting from the intrinsic basicity of the ligands and the Lewis acidic sites of the open metal centres, the STUs materials show excellent catalytic activities as Lewis base for the Knoevenagel condensation reaction between various aldehydes and malononitrile, and as Lewis acid for cyanosilylation reactions. Among these STUs, STU-4 (Ni(BIm)) shows the best catalytic efficiency (conversions >99 %) in both Knoevenagel condensation and cyanosilylation reactions under mild conditions, providing thus an advanced material for both Lewis base and Lewis acid catalysis.

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: Catalysis; Knoevenagel condensation reaction; Lewis acid; Lewis base; Metal-organic frameworks

References

  1. E. Knoevenagel, Angew. Chem. 1922, 35, 29-30. - PubMed
  2. J. Gascon, U. Aktay, M. D. Hernandez-Alonso, G. P. M. van Klink, F. Kapteijn, J. Catal. 2009, 261, 75-87. - PubMed
  3. F. Martínez, G. Orcajo, D. Briones, P. Leo, G. Calleja, Microporous Mesoporous Mater. 2017, 246, 43-50. - PubMed
  4. L. F. Tietze, Chem. Rev. 1996, 96, 115-136. - PubMed
  5. Y. Luan, Y. Qi, H. Gao, R. S. Andriamitantsoa, N. Zheng, G. Wang, J. Mater. Chem. A 2015, 3, 17320-17331. - PubMed
  6. M. J. Climent, A. Corma, I. Dominguez, S. Iborra, M. J. Sabater, G. Sastre, J. Catal. 2007, 246, 136-146. - PubMed
  7. M. B. Ansari, H. Jin, M. N. Parvin, S.-E. Park, Catal. Today 2012, 185, 211-216. - PubMed
  8. Y. Kubota, Y. Nishizaki, Y. Sugi, Chem. Lett. 2000, 29, 998-999. - PubMed
  9. S. Balalaie, M. Sheikh-Ahmadi, M. Bararjanian, Catal. Commun. 2007, 8, 1724-1728. - PubMed
  10. V. S. R. Rajasekhar Pullabhotla, A. Rahman, S. B. Jonnalagadda, Catal. Commun. 2009, 10, 365-369. - PubMed
  11. B. M. Reddy, M. K. Patil, K. N. Rao, G. K. Reddy, J. Mol. Catal. A 2006, 258, 302-307. - PubMed
  12. N. Jiang, H. Jin, Y.-H. Mo, E. A. Prasetyanto, S.-E. Park, Microporous Mesoporous Mater. 2011, 141, 16-19. - PubMed
  13. J. Liu, L. Chen, H. Cui, J. Zhang, L. Zhang, C.-Y. Su, Chem. Soc. Rev. 2014, 43, 6011-6061. - PubMed
  14. L. Jiao, Y. Wang, H.-L. Jiang, Q. Xu, Adv. Mater. 2018, 30, 1703663-1703686. - PubMed
  15. L. Lu, X.-Y. Li, X.-Q. Liu, Z.-M. Wang, L.-B. Sun, J. Mater. Chem. A 2015, 3, 6998-7005. - PubMed
  16. C. Yao, S. Zhou, X. Kang, Y. Zhao, R. Yan, Y. Zhang, L. Wen, Inorg. Chem. 2018, 57, 11157-11164. - PubMed
  17. X.-S. Wang, J. Liang, L. Li, Z.-J. Lin, P. P. Bag, S.-Y. Gao, Y.-B. Huang, R. Cao, Inorg. Chem. 2016, 55, 2641-2649. - PubMed
  18. J. Liang, R.-P. Chen, X.-Y. Wang, T.-T. Liu, X.-S. Wang, Y.-B. Huang, R. Cao, Chem. Sci. 2017, 8, 1570-1575. - PubMed
  19. Y.-B. Huang, J. Liang, X.-S. Wang, R. Cao, Chem. Soc. Rev. 2017, 46, 126-157. - PubMed
  20. T.-T. Liu, J. Liang, R. Xu, Y.-B. Huang, R. Cao, Chem. Commun. 2019, 55, 4063-4066. - PubMed
  21. P. Valvekens, M. Vandichel, M. Waroquier, V. Van Speybroeck, D. De Vos, J. Catal. 2014, 317, 1-10. - PubMed
  22. M. Hartmann, M. Fischer, Microporous Mesoporous Mater. 2012, 164, 38-43. - PubMed
  23. Y. K. Hwang, D. Y. Hong, J. S. Chang, S. H. Jhung, Y. K. Seo, J. Kim, A. Vimont, M. Daturi, C. Serre, G. Ferey, Angew. Chem. Int. Ed. 2008, 47, 4144-4148; - PubMed
  24. Angew. Chem. 2008, 120, 4212-4216. - PubMed
  25. X.-P. Zhou, M. Li, J. Liu, D. Li, J. Am. Chem. Soc. 2012, 134, 67-70. - PubMed
  26. Y. Wu, X.-P. Zhou, J.-R. Yang, D. Li, Chem. Commun. 2013, 49, 3413-3415. - PubMed
  27. J.-J. Du, X. Zhang, X.-P. Zhou, D. Li, Inorg. Chem. Front. 2018, 5, 2772-2776. - PubMed
  28. D. Saliba, M. Ammar, M. Rammal, M. Al-Ghoul, M. Hmadeh, J. Am. Chem. Soc. 2018, 140, 1812-1823. - PubMed
  29. L. Pan, K. M. Adams, H. E. Hernandez, X. Wang, C. Zheng, Y. Hattori, K. Kaneko, J. Am. Chem. Soc. 2003, 125, 3062-3067. - PubMed
  30. S. Ernst, M. Hartmann, S. Sauerbeck, T. Bongers, Appl. Catal. A 2000, 200, 117-123. - PubMed
  31. P. Valvekens, D. Jonckheere, T. De Baerdemaeker, A. Kubarev, M. Vandichel, K. Hemelsoet, M. Waroquier, V. Van Speybroeck, E. Smolders, D. Depla, Chem. Sci. 2014, 5, 4517-4524. - PubMed
  32. U. P. N. Tran, K. K. A. Le, N. T. S. Phan, ACS Catal. 2011, 1, 120-127. - PubMed
  33. J. Juan-Alcañiz, E. V. Ramos-Fernandez, U. Lafont, J. Gascon, F. Kapteijn, J. Catal. 2010, 269, 229-241. - PubMed
  34. A. Corma, S. Iborra, I. Rodriguez, F. Sanchez, J. Catal. 2002, 211, 208-215. - PubMed
  35. I. Rodriguez, G. Sastre, A. Corma, S. Iborra, J. Catal. 1999, 183, 14-23. - PubMed
  36. R. Gupta, M. Gupta, S. Paul, R. Gupta, Bull. Korean Chem. Soc. 2009, 30, 2419-2421. - PubMed
  37. R. Selvin, H.-L. Hsu, T.-M. Her, Catal. Commun. 2008, 10, 169-172. - PubMed
  38. M. North, D. L. Usanov, C. Young, Chem. Rev. 2008, 108, 5146-5226. - PubMed
  39. A. Henschel, K. Gedrich, R. Kraehnertb, S. Kaskel, Chem. Commun. 2008, 4192-4194. - PubMed
  40. S. Neogi, M. K. Sharma, P. K. Bharadwaj, J. Mol. Catal. A Chem. 2009, 299, 1-4. - PubMed
  41. H.-F. Yao, Y. Yang, H. Liu, F.-G. Xi, E.-Q. Gao, J. Mol. Catal A 2014, 394, 57-65. - PubMed
  42. K. Schlichte, T. Kratzke, S. Kaskel, Microporous Mesoporous Mater. 2004, 73, 81-88. - PubMed
  43. R. F. D′Vries, V. A. de la Peña-O'Shea, N. Snejko, M. Iglesias, E. Gutiérrez-Puebla, M. Á. Monge, Cryst. Growth Des. 2012, 12, 5535-5545. - PubMed
  44. O. R. Evans, H. L. Ngo, W. B. Lin, J. Am. Chem. Soc. 2001, 123, 10395-10396. - PubMed
  45. K. Fujita, R. Kawamoto, R. Tsubouchi, Y. Sunatsuki, M. Kojima, S. Iijima, N. Matsumoto, Chem. Lett. 2007, 36, 1284-1285. - PubMed

Publication Types

Grant support