Display options
Cite
Kukoyi A, Micheli EA, Liu B, et al. BODIPY-functionalized 1,10-phenanthroline as a long wavelength sensitizer for near-infrared emission of the ytterbium(iii) ion. Dalton Trans. 2019;48(36):13880-13887doi: 10.1039/c9dt02850a.
Kukoyi, A., Micheli, E. A., Liu, B., He, H., & May, P. S. (2019). BODIPY-functionalized 1,10-phenanthroline as a long wavelength sensitizer for near-infrared emission of the ytterbium(iii) ion. Dalton transactions (Cambridge, England : 2003), 48(36), 13880-13887. https://doi.org/10.1039/c9dt02850a
Kukoyi, Adedayo, et al. "BODIPY-functionalized 1,10-phenanthroline as a long wavelength sensitizer for near-infrared emission of the ytterbium(iii) ion." Dalton transactions (Cambridge, England : 2003) vol. 48,36 (2019): 13880-13887. doi: https://doi.org/10.1039/c9dt02850a
Kukoyi A, Micheli EA, Liu B, He H, May PS. BODIPY-functionalized 1,10-phenanthroline as a long wavelength sensitizer for near-infrared emission of the ytterbium(iii) ion. Dalton Trans. 2019 Sep 17;48(36):13880-13887. doi: 10.1039/c9dt02850a. PMID: 31486443.
Copy Download .nbib Format: NLM
Share it on

Dalton Trans. 2019 Sep 17;48(36):13880-13887. doi: 10.1039/c9dt02850a.

BODIPY-functionalized 1,10-phenanthroline as a long wavelength sensitizer for near-infrared emission of the ytterbium(iii) ion.

Dalton transactions (Cambridge, England : 2003)

Adedayo Kukoyi, Eric A Micheli, Beibei Liu, Hongshan He, P Stanley May

Affiliations

  1. Department of Chemistry and Biochemistry, Eastern Illinois University, Charleston, IL 61920, USA. [email protected].

PMID: 31486443 DOI: 10.1039/c9dt02850a

Abstract

Two BODIPY (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) moieties were chemically appended to the 4,7-positions of 1,10-phenanhtroline resulting in two new ligands (BODIPY-Phen and 4I-BODIPY-Phen) with strong absorption at 507 nm and 540 nm, respectively. BODIPY-Phen emits fluorescence strongly centered at 507 nm, whereas the fluorescence of 4I-BODIPY-Phen was completely quenched due to the introduction of four I atoms at its 2,6 positions. The two ligands reacted readily with tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionate) ytterbium(iii) dihydrate through substitution reactions forming eight-coordinate complexes that emit strongly at 976 nm upon excitation at their absorption maximal positions. Both complexes exhibited a lifetime of ∼11 μs in dichloromethane at room temperature.

Publication Types