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Peng H, Yu Q, Wang S, et al. Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes. Adv Sci (Weinh). 2019;6(17):1900431doi: 10.1002/advs.201900431.
Peng, H., Yu, Q., Wang, S., Kim, J., Rowan, A. E., Nanjundan, A. K., Yamauchi, Y., & Yu, J. (2019). Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes. Advanced science (Weinheim, Baden-Wurttemberg, Germany), 6(17), 1900431. https://doi.org/10.1002/advs.201900431
Peng, Huiling, et al. "Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes." Advanced science (Weinheim, Baden-Wurttemberg, Germany) vol. 6,17 (2019): 1900431. doi: https://doi.org/10.1002/advs.201900431
Peng H, Yu Q, Wang S, Kim J, Rowan AE, Nanjundan AK, Yamauchi Y, Yu J. Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes. Adv Sci (Weinh). 2019 Jul 25;6(17):1900431. doi: 10.1002/advs.201900431. eCollection 2019 Sep 04. PMID: 31508272; PMCID: PMC6724361.
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Adv Sci (Weinh). 2019 Jul 25;6(17):1900431. doi: 10.1002/advs.201900431. eCollection 2019 Sep 04.

Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes.

Advanced science (Weinheim, Baden-Wurttemberg, Germany)

Huiling Peng, Qianchuan Yu, Shengping Wang, Jeonghun Kim, Alan E Rowan, Ashok Kumar Nanjundan, Yusuke Yamauchi, Jingxian Yu

Affiliations

  1. Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430074 China.
  2. Key Laboratory of Eco-chemical Engineering College of Chemistry and Molecular Engineering Qingdao University of Science and Technology Qingdao 266042 China.
  3. Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensland Brisbane QLD 4072 Australia.
  4. School of Chemical Engineering Faculty of Engineering Architecture and Information Technology (EAIT) The University of Queensland Brisbane QLD 4072 Australia.
  5. International Center for Materials Nanoarchitectonics (MANA) National Institute for Materials Science (NIMS) 1-1 Namiki Tsukuba Ibaraki 305-0044 Japan.
  6. ARC Centre of Excellence for Nanoscale BioPhotonics (CNBP) School of Chemistry and Physics The University of Adelaide Adelaide SA 5005 Australia.

PMID: 31508272 PMCID: PMC6724361 DOI: 10.1002/advs.201900431

Abstract

To sustainably satisfy the growing demand for energy, organic carbonyl compounds (OCCs) are being widely studied as electrode active materials for batteries owing to their high capacity, flexible structure, low cost, environmental friendliness, renewability, and universal applicability. However, their high solubility in electrolytes, limited active sites, and low conductivity are obstacles in increasing their usage. Here, the nucleophilic addition reaction of aromatic carbonyl compounds (ACCs) is first used to explain the electrochemical behavior of carbonyl compounds during charge-discharge, and the relationship of the molecular structure and electrochemical properties of ACCs are discussed. Strategies for molecular structure modifications to improve the performance of ACCs, i.e., the capacity density, cycle life, rate performance, and voltage of the discharge platform, are also elaborated. ACCs, as electrode active materials in aqueous solutions, will become a future research hotspot. ACCs will inevitably become sustainable green materials for batteries with high capacity density and high power density.

Keywords: aromatic carbonyl compounds; batteries; electrochemical behavior; electrode materials

Conflict of interest statement

The authors declare no conflict of interest.

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