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Maaskant RV, Polanco EA, van Lier RCW, et al. Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions. Org Biomol Chem. 2020;18(4):638-641doi: 10.1039/c9ob02223f.
Maaskant, R. V., Polanco, E. A., van Lier, R. C. W., & Roelfes, G. (2020). Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions. Organic & biomolecular chemistry, 18(4), 638-641. https://doi.org/10.1039/c9ob02223f
Maaskant, Ruben V, et al. "Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions." Organic & biomolecular chemistry vol. 18,4 (2020): 638-641. doi: https://doi.org/10.1039/c9ob02223f
Maaskant RV, Polanco EA, van Lier RCW, Roelfes G. Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions. Org Biomol Chem. 2020 Jan 28;18(4):638-641. doi: 10.1039/c9ob02223f. Epub 2020 Jan 09. PMID: 31915767.
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Org Biomol Chem. 2020 Jan 28;18(4):638-641. doi: 10.1039/c9ob02223f. Epub 2020 Jan 09.

Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions.

Organic & biomolecular chemistry

Ruben V Maaskant, Ehider A Polanco, Roos C W van Lier, Gerard Roelfes

Affiliations

  1. Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands. [email protected].

PMID: 31915767 DOI: 10.1039/c9ob02223f

Abstract

Here, we report that the combination of cationic iron porphyrins with sodium dodecyl sulphate (SDS) gives rise to efficient micellar catalysis of cyclopropanation reactions of styrene derivatives, using diazoacetates as carbene precursors. This simple, yet effective approach for cyclopropanations illustrates the power of micellar catalysis.

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