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Jarzebski A, Schnakenburg G, Lützen A. Chiral Self-Sorting Effects in the Self-Assembly of Metallosupramolecular Aggregates Comprising Ligands Derived from Tröger's Base. Chempluschem. 2020;85(7):1455-1464doi: 10.1002/cplu.202000387.
Jarzebski, A., Schnakenburg, G., & Lützen, A. (2020). Chiral Self-Sorting Effects in the Self-Assembly of Metallosupramolecular Aggregates Comprising Ligands Derived from Tröger's Base. ChemPlusChem, 85(7), 1455-1464. https://doi.org/10.1002/cplu.202000387
Jarzebski, Andreas, et al. "Chiral Self-Sorting Effects in the Self-Assembly of Metallosupramolecular Aggregates Comprising Ligands Derived from Tröger's Base." ChemPlusChem vol. 85,7 (2020): 1455-1464. doi: https://doi.org/10.1002/cplu.202000387
Jarzebski A, Schnakenburg G, Lützen A. Chiral Self-Sorting Effects in the Self-Assembly of Metallosupramolecular Aggregates Comprising Ligands Derived from Tröger's Base. Chempluschem. 2020 Jul;85(7):1455-1464. doi: 10.1002/cplu.202000387. PMID: 32644289.
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Chempluschem. 2020 Jul;85(7):1455-1464. doi: 10.1002/cplu.202000387.

Chiral Self-Sorting Effects in the Self-Assembly of Metallosupramolecular Aggregates Comprising Ligands Derived from Tröger's Base.

ChemPlusChem

Andreas Jarzebski, Gregor Schnakenburg, Arne Lützen

Affiliations

  1. University of Bonn, Kekulé-Institute of Organic Chemistry and Biochemistry, Gerhard-Domagk-Str. 1, 53121, Bonn, Germany.
  2. University of Bonn, Institute of Inorganic Chemistry, Gerhard-Domagk-Str. 1, 53121, Bonn, Germany.

PMID: 32644289 DOI: 10.1002/cplu.202000387

Abstract

Five ligands with either nitrile or isonitrile metal binding motifs have been synthesized based on the 2,8- or 3,9-disubstituted Tröger's base scaffold, respectively. These ligands self-assemble into dinuclear cyclic metallosupramolecular aggregates upon coordination to [(dppp)Pd(OTf)

© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords: metallosupramolecular chemistry; nitrile ligands; palladium; self-assembly; self-sorting

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