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Muthukumaraswamy Rangaraj V, Wahab MA, Reddy KSK, et al. Metal Organic Framework - Based Mixed Matrix Membranes for Carbon Dioxide Separation: Recent Advances and Future Directions. Front Chem. 2020;8:534doi: 10.3389/fchem.2020.00534.
Muthukumaraswamy Rangaraj, V., Wahab, M. A., Reddy, K. S. K., Kakosimos, G., Abdalla, O., Favvas, E. P., Reinalda, D., Geuzebroek, F., Abdala, A., & Karanikolos, G. N. (2020). Metal Organic Framework - Based Mixed Matrix Membranes for Carbon Dioxide Separation: Recent Advances and Future Directions. Frontiers in chemistry, 8534. https://doi.org/10.3389/fchem.2020.00534
Muthukumaraswamy Rangaraj, Vengatesan, et al. "Metal Organic Framework - Based Mixed Matrix Membranes for Carbon Dioxide Separation: Recent Advances and Future Directions." Frontiers in chemistry vol. 8 (2020): 534. doi: https://doi.org/10.3389/fchem.2020.00534
Muthukumaraswamy Rangaraj V, Wahab MA, Reddy KSK, Kakosimos G, Abdalla O, Favvas EP, Reinalda D, Geuzebroek F, Abdala A, Karanikolos GN. Metal Organic Framework - Based Mixed Matrix Membranes for Carbon Dioxide Separation: Recent Advances and Future Directions. Front Chem. 2020 Jul 03;8:534. doi: 10.3389/fchem.2020.00534. eCollection 2020. PMID: 32719772; PMCID: PMC7350925.
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Front Chem. 2020 Jul 03;8:534. doi: 10.3389/fchem.2020.00534. eCollection 2020.

Metal Organic Framework - Based Mixed Matrix Membranes for Carbon Dioxide Separation: Recent Advances and Future Directions.

Frontiers in chemistry

Vengatesan Muthukumaraswamy Rangaraj, Mohammad A Wahab, K Suresh Kumar Reddy, George Kakosimos, Omnya Abdalla, Evangelos P Favvas, Donald Reinalda, Frank Geuzebroek, Ahmed Abdala, Georgios N Karanikolos

Affiliations

  1. Department of Chemical Engineering, Khalifa University, Abu Dhabi, United Arab Emirates.
  2. Chemical Engineering Program, Texas A&M University at Qatar, Doha, Qatar.
  3. School of Chemistry, Physics and Mechanical Engineering, Faculty of Engineering, Queensland University of Technology, Brisbane, QLD, Australia.
  4. Institute of Nanoscience and Nanotechnology, National Centre of Scientific Research "Demokritos", Attica, Greece.
  5. Center for Catalysis and Separations (CeCaS), Khalifa University, Abu Dhabi, United Arab Emirates.
  6. ADNOC Gas Processing, Department of Research and Engineering R&D, Abu Dhabi, United Arab Emirates.
  7. Research and Innovation Center on CO2 and H2 (RICH), Khalifa University, Abu Dhabi, United Arab Emirates.
  8. Center for Membranes and Advanced Water Technology (CMAT), Khalifa University, Abu Dhabi, United Arab Emirates.

PMID: 32719772 PMCID: PMC7350925 DOI: 10.3389/fchem.2020.00534

Abstract

Gas separation and purification using polymeric membranes is a promising technology that constitutes an energy-efficient and eco-friendly process for large scale integration. However, pristine polymeric membranes typically suffer from the trade-off between permeability and selectivity represented by the Robeson's upper bound. Mixed matrix membranes (MMMs) synthesized by the addition of porous nano-fillers into polymer matrices, can enable a simultaneous increase in selectivity and permeability. Among the various porous fillers, metal-organic frameworks (MOFs) are recognized in recent days as a promising filler material for the fabrication of MMMs. In this article, we review representative examples of MMMs prepared by dispersion of MOFs into polymer matrices or by deposition on the surface of polymeric membranes. Addition of MOFs into other continuous phases, such as ionic liquids, are also included. CO

Copyright © 2020 Muthukumaraswamy Rangaraj, Wahab, Reddy, Kakosimos, Abdalla, Favvas, Reinalda, Geuzebroek, Abdala and Karanikolos.

Keywords: CO2; MOF; membranes; mixture; permeability; polymers; selectivity; separation

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