Display options
Cite
Eivgi O, Phatake RS, Nechmad NB, et al. Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications. Acc Chem Res. 2020;53(10):2456-2471doi: 10.1021/acs.accounts.0c00495.
Eivgi, O., Phatake, R. S., Nechmad, N. B., & Lemcoff, N. G. (2020). Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications. Accounts of chemical research, 53(10), 2456-2471. https://doi.org/10.1021/acs.accounts.0c00495
Eivgi, Or, et al. "Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications." Accounts of chemical research vol. 53,10 (2020): 2456-2471. doi: https://doi.org/10.1021/acs.accounts.0c00495
Eivgi O, Phatake RS, Nechmad NB, Lemcoff NG. Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications. Acc Chem Res. 2020 Oct 20;53(10):2456-2471. doi: 10.1021/acs.accounts.0c00495. Epub 2020 Sep 29. PMID: 32990427; PMCID: PMC7584343.
Copy Download .nbib Format: NLM
Share it on

Acc Chem Res. 2020 Oct 20;53(10):2456-2471. doi: 10.1021/acs.accounts.0c00495. Epub 2020 Sep 29.

Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications.

Accounts of chemical research

Or Eivgi, Ravindra S Phatake, Noy B Nechmad, N Gabriel Lemcoff

Affiliations

  1. Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel.
  2. Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel.

PMID: 32990427 PMCID: PMC7584343 DOI: 10.1021/acs.accounts.0c00495

Abstract

The most important means for tuning and improving a catalyst's properties is the delicate exchange of the ligand shell around the central metal atom. Perhaps for no other organometallic-catalyzed reaction is this statement more valid than for ruthenium-based olefin metathesis. Indeed, even the simple exchange of an oxygen atom for a sulfur atom in a chelated ruthenium benzylidene about a decade ago resulted in the development of extremely stable, photoactive catalysts. This Account presents our perspective on the development of dormant olefin metathesis catalysts that can be activated by external stimuli and, more specifically, the use of light as an attractive inducing agent.The insight gained from a deeper understanding of the properties of

References

  1. J Am Chem Soc. 2018 Feb 7;140(5):1604-1607 - PubMed
  2. J Am Chem Soc. 2013 Jan 9;135(1):94-7 - PubMed
  3. Beilstein J Org Chem. 2015 Aug 21;11:1469-74 - PubMed
  4. Nat Chem. 2019 May;11(5):488-494 - PubMed
  5. Acc Chem Res. 2001 Jan;34(1):18-29 - PubMed
  6. Chem Commun (Camb). 2006 Jun 21;(23):2489-91 - PubMed
  7. Angew Chem Int Ed Engl. 2016 Mar 7;55(11):3552-65 - PubMed
  8. J Am Chem Soc. 2012 Jan 11;134(1):693-9 - PubMed
  9. J Am Chem Soc. 2019 Jul 10;141(27):10626-10631 - PubMed
  10. Chemistry. 2018 Jan 9;24(2):337-341 - PubMed
  11. Angew Chem Int Ed Engl. 2003 Apr 17;42(15):1743-6 - PubMed
  12. Angew Chem Int Ed Engl. 2015 Feb 2;54(6):1919-23 - PubMed
  13. Inorg Chem. 2009 Nov 16;48(22):10819-25 - PubMed
  14. ChemSusChem. 2018 Sep 21;11(18):3157-3166 - PubMed
  15. Chem Rev. 2017 Aug 9;117(15):10212-10290 - PubMed
  16. Angew Chem Int Ed Engl. 2015 Oct 12;54(42):12384-8 - PubMed
  17. Chem Soc Rev. 2018 Jun 18;47(12):4510-4544 - PubMed
  18. Chemistry. 2001 Aug 3;7(15):3236-53 - PubMed
  19. Chem Soc Rev. 2009 Dec;38(12):3360-72 - PubMed
  20. J Am Chem Soc. 2014 Sep 17;136(37):13029-37 - PubMed
  21. Chemistry. 2018 Jul 20;24(41):10403-10408 - PubMed
  22. Angew Chem Int Ed Engl. 2016 Jan 11;55(2):764-7 - PubMed
  23. J Am Chem Soc. 2012 Nov 21;134(46):18889-91 - PubMed
  24. J Am Chem Soc. 2001 Jul 11;123(27):6543-54 - PubMed
  25. Chemistry. 2014 Oct 20;20(43):14120-5 - PubMed
  26. Beilstein J Org Chem. 2010 Nov 23;6:1106-19 - PubMed
  27. Angew Chem Int Ed Engl. 2012 Aug 20;51(34):8446-76 - PubMed
  28. Angew Chem Int Ed Engl. 2005 Sep 5;44(35):5705-9 - PubMed
  29. J Am Chem Soc. 2013 Mar 6;135(9):3331-4 - PubMed
  30. Angew Chem Int Ed Engl. 2007;46(38):7262-5 - PubMed
  31. Chem Sci. 2018 Mar 14;9(14):3580-3583 - PubMed
  32. J Am Chem Soc. 2019 Dec 11;141(49):19236-19240 - PubMed
  33. Dalton Trans. 2012 Jan 7;41(1):32-43 - PubMed
  34. Molecules. 2020 May 01;25(9): - PubMed
  35. Chem Commun (Camb). 2013 Feb 28;49(17):1679-95 - PubMed
  36. Org Lett. 2015 Feb 6;17(3):740-3 - PubMed
  37. Chem Soc Rev. 2015 Jun 7;44(11):3358-77 - PubMed
  38. Chemistry. 2010 Aug 2;16(29):8726-37 - PubMed
  39. Org Lett. 2007 Jul 5;9(14):2649-51 - PubMed
  40. Chem Soc Rev. 2020 Mar 23;49(6):1867-1886 - PubMed
  41. Org Lett. 1999 Sep 23;1(6):953-6 - PubMed
  42. Chemistry. 2008;14(30):9330-7 - PubMed
  43. Angew Chem Int Ed Engl. 2017 Sep 4;56(37):11024-11036 - PubMed
  44. Chem Commun (Camb). 2010 Oct 14;46(38):7115-7 - PubMed
  45. Nat Commun. 2016 Jul 12;7:12054 - PubMed
  46. J Am Chem Soc. 2002 May 8;124(18):4954-5 - PubMed
  47. Chem Commun (Camb). 2014 Sep 18;50(72):10355-75 - PubMed
  48. Chem Sci. 2015 Aug 1;6(8):4561-4569 - PubMed
  49. Beilstein J Org Chem. 2015 Sep 03;11:1541-6 - PubMed
  50. Inorg Chem. 2018 May 7;57(9):5701-5706 - PubMed
  51. J Am Chem Soc. 2019 May 1;141(17):6791-6796 - PubMed
  52. Chem Commun (Camb). 2015 Mar 4;51(18):3870-3 - PubMed
  53. J Am Chem Soc. 2011 Jun 8;133(22):8525-7 - PubMed
  54. J Am Chem Soc. 2011 Apr 13;133(14):5380-8 - PubMed
  55. Org Lett. 2008 Feb 7;10(3):441-4 - PubMed
  56. Nature. 2018 May;557(7704):223-227 - PubMed
  57. J Am Chem Soc. 2013 Nov 13;135(45):16817-20 - PubMed
  58. Chem Commun (Camb). 2011 Jul 7;47(25):7060-2 - PubMed
  59. Chem Rev. 2009 Aug;109(8):3708-42 - PubMed

Publication Types