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Funtan A, Michael P, Rost S, et al. Self-Diagnostic Polymers-Inline Detection of Thermal Degradation of Unsaturated Poly(ester imide)s. Adv Mater. 2021;33(18):e2100068doi: 10.1002/adma.202100068.
Funtan, A., Michael, P., Rost, S., Omeis, J., Lienert, K., & Binder, W. H. (2021). Self-Diagnostic Polymers-Inline Detection of Thermal Degradation of Unsaturated Poly(ester imide)s. Advanced materials (Deerfield Beach, Fla.), 33(18), e2100068. https://doi.org/10.1002/adma.202100068
Funtan, Alexander, et al. "Self-Diagnostic Polymers-Inline Detection of Thermal Degradation of Unsaturated Poly(ester imide)s." Advanced materials (Deerfield Beach, Fla.) vol. 33,18 (2021): e2100068. doi: https://doi.org/10.1002/adma.202100068
Funtan A, Michael P, Rost S, Omeis J, Lienert K, Binder WH. Self-Diagnostic Polymers-Inline Detection of Thermal Degradation of Unsaturated Poly(ester imide)s. Adv Mater. 2021 May;33(18):e2100068. doi: 10.1002/adma.202100068. Epub 2021 Mar 30. PMID: 33783026.
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Adv Mater. 2021 May;33(18):e2100068. doi: 10.1002/adma.202100068. Epub 2021 Mar 30.

Self-Diagnostic Polymers-Inline Detection of Thermal Degradation of Unsaturated Poly(ester imide)s.

Advanced materials (Deerfield Beach, Fla.)

Alexander Funtan, Philipp Michael, Simon Rost, Jürgen Omeis, Klaus Lienert, Wolfgang H Binder

Affiliations

  1. Macromolecular Chemistry, Institute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Von-Danckelmann-Platz 4, 06120, Halle (Saale), Germany.
  2. ELANTAS Europe GmbH, Großmannstraße 105, 20539, Hamburg, Germany.
  3. ALTANA AG, Abelstraße 43, 46483, Wesel, Germany.

PMID: 33783026 DOI: 10.1002/adma.202100068

Abstract

Monitoring polymer degradation is an important quest, particularly relevant for industry. Although many indirect methodologies for assessing polymer degradation exist, only few are applicable for an inline-monitoring via optic detection-systems. An inline-monitoring system is introduced for the thermal degradation of crosslinked poly(ester imide)s (PEIs) by embedding trifluoroacetyl functionalized stilbene molecules, serving as chemosensors to track the release of generated alcoholic byproducts. Nucleophilic addition of an alcohol to the sensors trifluoroacetyl functionality triggers hemiacetal formation which is accompanied by significant changes in optical properties, in turn allowing monitoring of sensor activation by direct spectroscopy. Fluorescence spectroscopy offers an easy detection tool for the inline thermal monitoring of PEI-degradation.

© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.

Keywords: chemosensors; optical sensors; poly(ester imide)s; stilbenes; thermal polymer degradation

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