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Udayakantha M, Handy JV, Davidson RD, et al. Halide Replacement with Complete Preservation of Crystal Lattice in Mixed-Anion Lanthanide Oxyhalides. Angew Chem Int Ed Engl. 2021;60(28):15582-15589doi: 10.1002/anie.202104231.
Udayakantha, M., Handy, J. V., Davidson, R. D., Kaur, J., Villalpando, G., Zuin, L., Chakraborty, S., & Banerjee, S. (2021). Halide Replacement with Complete Preservation of Crystal Lattice in Mixed-Anion Lanthanide Oxyhalides. Angewandte Chemie (International ed. in English), 60(28), 15582-15589. https://doi.org/10.1002/anie.202104231
Udayakantha, Malsha, et al. "Halide Replacement with Complete Preservation of Crystal Lattice in Mixed-Anion Lanthanide Oxyhalides." Angewandte Chemie (International ed. in English) vol. 60,28 (2021): 15582-15589. doi: https://doi.org/10.1002/anie.202104231
Udayakantha M, Handy JV, Davidson RD, Kaur J, Villalpando G, Zuin L, Chakraborty S, Banerjee S. Halide Replacement with Complete Preservation of Crystal Lattice in Mixed-Anion Lanthanide Oxyhalides. Angew Chem Int Ed Engl. 2021 Jul 05;60(28):15582-15589. doi: 10.1002/anie.202104231. Epub 2021 Jun 03. PMID: 33783069.
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Angew Chem Int Ed Engl. 2021 Jul 05;60(28):15582-15589. doi: 10.1002/anie.202104231. Epub 2021 Jun 03.

Halide Replacement with Complete Preservation of Crystal Lattice in Mixed-Anion Lanthanide Oxyhalides.

Angewandte Chemie (International ed. in English)

Malsha Udayakantha, Joseph V Handy, Rachel D Davidson, Jagjit Kaur, Graciela Villalpando, Lucia Zuin, Sudip Chakraborty, Sarbajit Banerjee

Affiliations

  1. Department of Chemistry, Department of Materials Science and Engineering, Texas A&M University, College Station, TX, 77843, USA.
  2. Materials Theory for Energy Scavenging (MATES) Lab, Department of Physics, Indian Institute of Technology Indore, Simrol, Indore, 453552, India.
  3. Canadian Light Source, University of Saskatchewan, Saskatoon, SK, S7N 2V3, Canada.

PMID: 33783069 DOI: 10.1002/anie.202104231

Abstract

A challenge in anion control in periodic solids is to preserve the crystal lattice while substituting for different anions of widely varying size and hardness. Post-synthetic modification routes that place cations or anions in non-equilibrium configurations are promising; however, such methods remain relatively unexplored for anion placement. Here, we report the synthesis of LaOI nanocrystals by a non-hydrolytic sol-gel condensation reaction and their transformation into LaOBr, LaOCl, and LaOF nanocrystals along hard-soft acid-base principles using post-synthetic metathesis reactions with ammonium halides. Anion displacement proceeds along halide planes, preserving the tetragonal matlockite structure. Energy-variant X-ray excited optical luminesce signatures of alloyed Tb

© 2021 Wiley-VCH GmbH.

Keywords: HSAB theory; XEOL; ion exchange; lanthanide oxyhalides; topochemistry

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