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Polymers (Basel). 2021 Aug 06;13(16). doi: 10.3390/polym13162621.

Hafnium vs. Zirconium, the Perpetual Battle for Supremacy in Catalytic Olefin Polymerization: A Simple Matter of Electrophilicity?.

Polymers

Antonio Vittoria, Georgy P Goryunov, Vyatcheslav V Izmer, Dmitry S Kononovich, Oleg V Samsonov, Francesco Zaccaria, Gaia Urciuoli, Peter H M Budzelaar, Vincenzo Busico, Alexander Z Voskoboynikov, Dmitry V Uborsky, Christian Ehm, Roberta Cipullo

Affiliations

  1. Dipartimento di Scienze Chimiche, Università di Napoli Federico II, Via Cintia, 80126 Napoli, Italy.
  2. Department of Chemistry, Lomonosov Moscow State University, 1/3 Leninskie Gory, 119991 Moscow, Russia.
  3. Dipartimento di Chimica, Biologia e Biotecnologie and CIRCC, Universitaà di Perugia, 06123 Perugia, Italy.

PMID: 34451163 PMCID: PMC8400551 DOI: 10.3390/polym13162621

Abstract

The performance of

Keywords: QSAR; hafnocenes; high-temperature performance; iPP; molecular catalysts; olefin polymerization

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