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Kotwica K, Wielgus I, Proń A. Azaacenes Based Electroactive Materials: Preparation, Structure, Electrochemistry, Spectroscopy and Applications-A Critical Review. Materials (Basel). 2021;14(18)doi: 10.3390/ma14185155.
Kotwica, K., Wielgus, I., & Proń, A. (2021). Azaacenes Based Electroactive Materials: Preparation, Structure, Electrochemistry, Spectroscopy and Applications-A Critical Review. Materials (Basel, Switzerland), 14(18), . https://doi.org/10.3390/ma14185155
Kotwica, Kamil, et al. "Azaacenes Based Electroactive Materials: Preparation, Structure, Electrochemistry, Spectroscopy and Applications-A Critical Review." Materials (Basel, Switzerland) vol. 14,18 (2021). doi: https://doi.org/10.3390/ma14185155
Kotwica K, Wielgus I, Proń A. Azaacenes Based Electroactive Materials: Preparation, Structure, Electrochemistry, Spectroscopy and Applications-A Critical Review. Materials (Basel). 2021 Sep 08;14(18). doi: 10.3390/ma14185155. PMID: 34576378; PMCID: PMC8472324.
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Materials (Basel). 2021 Sep 08;14(18). doi: 10.3390/ma14185155.

Azaacenes Based Electroactive Materials: Preparation, Structure, Electrochemistry, Spectroscopy and Applications-A Critical Review.

Materials (Basel, Switzerland)

Kamil Kotwica, Ireneusz Wielgus, Adam Proń

Affiliations

  1. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warszawa, Poland.
  2. Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warszawa, Poland.

PMID: 34576378 PMCID: PMC8472324 DOI: 10.3390/ma14185155

Abstract

This short critical review is devoted to the synthesis and functionalization of various types of azaacenes, organic semiconducting compounds which can be considered as promising materials for the fabrication of n-channel or ambipolar field effect transistors (FETs), components of active layers in light emitting diodes (LEDs), components of organic memory devices and others. Emphasis is put on the diversity of azaacenes preparation methods and the possibility of tuning their redox and spectroscopic properties by changing the C/N ratio, modifying the nitrogen atoms distribution mode, functionalization with electroaccepting or electrodonating groups and changing their molecular shape. Processability, structural features and degradation pathways of these compounds are also discussed. A unique feature of this review concerns the listed redox potentials of all discussed compounds which were normalized vs. Fc/Fc

Keywords: azaacenes; devices; functionalization; redox properties; synthesis

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