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Materials (Basel). 2021 Sep 20;14(18). doi: 10.3390/ma14185445.

Dendritic Iron(III) Carbazole Complexes: Structural, Optical, and Magnetic Characteristics.

Materials (Basel, Switzerland)

Matvey Gruzdev, Ulyana Chervonova, Arkadiy Kolker, Nadezhda Fomina, Ekaterina Zueva, Valerya Vorobeva, Denis Starichenko, Alexander Korolev

Affiliations

  1. G.A. Krestov Institute of Solution Chemistry of Russian Academy of Sciences, 153045 Ivanovo, Russia.
  2. Department of Inorganic Chemistry, Kazan National Research Technological University, 420015 Kazan, Russia.
  3. Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RAS, 420029 Kazan, Russia.
  4. M.N. Mikheev Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences, 620108 Ekaterinburg, Russia.

PMID: 34576669 PMCID: PMC8467834 DOI: 10.3390/ma14185445

Abstract

This paper focuses on the synthesis, structural characterization, and study of the optical, magnetic, and thermal properties of novel architectures combining metal ions as magnetoactive centers and photoactive blocks formed by carbazole units. For this purpose, a series of azomethine complexes of the composition [Fe(L)

Keywords: HS and LS spin state; antiferromagnetic interactions; carbazole; fluorescence; iron(III) complexes; magnetic susceptibility; spin crossover

References

  1. Chemistry. 2015 Sep 7;21(37):12947-59 - PubMed
  2. J Am Chem Soc. 2003 May 7;125(18):5356-65 - PubMed
  3. Chem Soc Rev. 2015 May 21;44(10):2880-92 - PubMed
  4. Chem Rev. 1947 Jun;40(3):359-80 - PubMed
  5. Chem Soc Rev. 2013 Feb 7;42(3):845-56 - PubMed
  6. J Magn Reson. 2006 Jan;178(1):42-55 - PubMed
  7. Chem Commun (Camb). 2011 Nov 21;47(43):11963-5 - PubMed
  8. Nat Protoc. 2013 Aug;8(8):1535-50 - PubMed
  9. Phys Chem Chem Phys. 2014 Jul 28;16(28):14334-56 - PubMed
  10. ACS Appl Mater Interfaces. 2015 May 6;7(17):9015-22 - PubMed

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