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Schranger H, Khosravi S, Fitzek H, et al. Elaborating the Iodine/Polyiodide Equilibrium Effects in Nanoporous Carbon-based Battery Electrode via Extreme Mass Asymmetry in Hybrid Cells. ChemElectroChem. 2021;8(16):3155-3160doi: 10.1002/celc.202100458.
Schranger, H., Khosravi, S., Fitzek, H., & Abbas, Q. (2021). Elaborating the Iodine/Polyiodide Equilibrium Effects in Nanoporous Carbon-based Battery Electrode via Extreme Mass Asymmetry in Hybrid Cells. ChemElectroChem, 8(16), 3155-3160. https://doi.org/10.1002/celc.202100458
Schranger, H, et al. "Elaborating the Iodine/Polyiodide Equilibrium Effects in Nanoporous Carbon-based Battery Electrode via Extreme Mass Asymmetry in Hybrid Cells." ChemElectroChem vol. 8,16 (2021): 3155-3160. doi: https://doi.org/10.1002/celc.202100458
Schranger H, Khosravi S, Fitzek H, Abbas Q. Elaborating the Iodine/Polyiodide Equilibrium Effects in Nanoporous Carbon-based Battery Electrode via Extreme Mass Asymmetry in Hybrid Cells. ChemElectroChem. 2021 Aug 13;8(16):3155-3160. doi: 10.1002/celc.202100458. Epub 2021 Aug 18. PMID: 34595089; PMCID: PMC8457216.
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ChemElectroChem. 2021 Aug 13;8(16):3155-3160. doi: 10.1002/celc.202100458. Epub 2021 Aug 18.

Elaborating the Iodine/Polyiodide Equilibrium Effects in Nanoporous Carbon-based Battery Electrode via Extreme Mass Asymmetry in Hybrid Cells.

ChemElectroChem

H Schranger, S Khosravi, H Fitzek, Q Abbas

Affiliations

  1. Institute for Chemistry and Technology of Materials Stremayrgasse 09 Graz University of Technology 8010 Graz Austria.
  2. Graz Centre for Electron Microscopy Steyrergasse 17 8010 Graz Austria.

PMID: 34595089 PMCID: PMC8457216 DOI: 10.1002/celc.202100458

Abstract

This article discusses the conversion of electrodeposited iodine to polyiodides within the nanopores of carbon electrodes that affect the performance of iodide electrolyte-based electrochemical cells. Here, carbon electrodes have been polarized in aqueous sodium iodide electrolyte to store charge in the form of solid iodine via highly reversible reaction (2I

© 2021 The Authors. ChemElectroChem published by Wiley-VCH GmbH.

Keywords: hybrid energy storage; iodide redox-active electrolyte; iodine electrodeposition; nanoporous carbon; supercapacitor

Conflict of interest statement

The authors declare no conflict of interest.

References

  1. Chem Rev. 2003 May;103(5):1649-84 - PubMed
  2. ChemSusChem. 2014 Nov;7(11):3138-44 - PubMed

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