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Shokurov AV, Yagodin AV, Martynov AG, et al. Octopus-Type Crown-Bisphthalocyaninate Anchor for Bottom-Up Assembly of Supramolecular Bilayers with Expanded Redox-Switching Capability. Small. 2021;18(2):e2104306doi: 10.1002/smll.202104306.
Shokurov, A. V., Yagodin, A. V., Martynov, A. G., Gorbunova, Y. G., Tsivadze, A. Y., & Selektor, S. L. (2022). Octopus-Type Crown-Bisphthalocyaninate Anchor for Bottom-Up Assembly of Supramolecular Bilayers with Expanded Redox-Switching Capability. Small (Weinheim an der Bergstrasse, Germany), 18(2), e2104306. https://doi.org/10.1002/smll.202104306
Shokurov, Alexander V, et al. "Octopus-Type Crown-Bisphthalocyaninate Anchor for Bottom-Up Assembly of Supramolecular Bilayers with Expanded Redox-Switching Capability." Small (Weinheim an der Bergstrasse, Germany) vol. 18,2 (2022): e2104306. doi: https://doi.org/10.1002/smll.202104306
Shokurov AV, Yagodin AV, Martynov AG, Gorbunova YG, Tsivadze AY, Selektor SL. Octopus-Type Crown-Bisphthalocyaninate Anchor for Bottom-Up Assembly of Supramolecular Bilayers with Expanded Redox-Switching Capability. Small. 2022 Jan;18(2):e2104306. doi: 10.1002/smll.202104306. Epub 2021 Oct 15. PMID: 34655166.
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Small. 2022 Jan;18(2):e2104306. doi: 10.1002/smll.202104306. Epub 2021 Oct 15.

Octopus-Type Crown-Bisphthalocyaninate Anchor for Bottom-Up Assembly of Supramolecular Bilayers with Expanded Redox-Switching Capability.

Small (Weinheim an der Bergstrasse, Germany)

Alexander V Shokurov, Alexey V Yagodin, Alexander G Martynov, Yulia G Gorbunova, Aslan Yu Tsivadze, Sofiya L Selektor

Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Sciences, Leninsky pr. 31-4, Moscow, 119071, Russia.
  2. Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, Leninsky pr. 31, Moscow, 119991, Russia.

PMID: 34655166 DOI: 10.1002/smll.202104306

Abstract

Achievement of information storage at molecular level remains a pressing task in miniaturization of computing technology. One of the promising approaches for its practical realization is development of nanoscale molecular switching materials including redox-active systems. The present work demonstrates a concept of expansion of a number of available redox-states of self-assembled monolayers through supramolecular approach. For this, the authors synthesized an octopus-like heteroleptic terbium(III) bisphthalocyaninate bearing one ligand with eight thioacetate-terminated "tentacles" (octopus-Pc) and a ligand with four crown-ether moieties (H

© 2021 Wiley-VCH GmbH.

Keywords: crown-ethers; molecular switching; phthalocyanine; redox-active monolayers; self-assembled monolayers; supramolecular chemistry

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