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Inorg Chem. 2022 Jan 13; doi: 10.1021/acs.inorgchem.1c03077. Epub 2022 Jan 13.

Unraveling the Symmetry Effects on the Second-Order Nonlinear Optical Responses of Molecular Switches: The Case of Ruthenium Complexes.

Inorganic chemistry

Pierre Beaujean, Benoît Champagne

Affiliations

  1. Laboratory of Theoretical Chemistry, Unit of Theoretical and Structural Physical Chemistry, NISM (Namur Institute of Structured Matter), University of Namur, Rue de Bruxelles 61, B-5000 Namur, Belgium.

PMID: 35023732 DOI: 10.1021/acs.inorgchem.1c03077

Abstract

Owing to their odd order, second-order nonlinear optical (NLO) responses are very sensitive to symmetry. Therefore, within hyper-Rayleigh scattering (HRS) technique, the symmetry impacts the amplitude of the molecular responses, the HRS first hyperpolarizability (β

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