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Chem Commun (Camb). 2011 Nov 14;47(42):11633-5. doi: 10.1039/c1cc14442a. Epub 2011 Sep 26.

Photoreactive gold(I) macrocycles with diphosphine and trans,trans-muconate ligands.

Chemical communications (Cambridge, England)

Mohammad Hedayetullah Mir, Jun Xiang Ong, Goutam Kumar Kole, Geok Kheng Tan, Michael J McGlinchey, Yuyang Wu, Jagadese J Vittal

Affiliations

  1. Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.

PMID: 21952202 DOI: 10.1039/c1cc14442a

Abstract

A pair of trans,trans-muconate ligands have been successfully aligned in two novel Au(I) macrocycles by design from phosphino metal precursors that undergo photochemical cycloaddition reactions quantitatively, resulting in the formation of cyclooctadiene derivatives.

This journal is © The Royal Society of Chemistry 2011

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