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Bailey PJ, Bell NL, Gim LL, et al. "Twisted" scorpionates: synthesis of a tris(2-pyridonyl)borate (Thp) ligand; lessons in the requirements for successful B(L2D)3 type ligands. Chem Commun (Camb). 2011;47(42):11659-61doi: 10.1039/c1cc14473a.
Bailey, P. J., Bell, N. L., Gim, L. L., Yucheng, T., Funnell, N., White, F., & Parsons, S. (2011). "Twisted" scorpionates: synthesis of a tris(2-pyridonyl)borate (Thp) ligand; lessons in the requirements for successful B(L2D)3 type ligands. Chemical communications (Cambridge, England), 47(42), 11659-61. https://doi.org/10.1039/c1cc14473a
Bailey, Philip J, et al. ""Twisted" scorpionates: synthesis of a tris(2-pyridonyl)borate (Thp) ligand; lessons in the requirements for successful B(L2D)3 type ligands." Chemical communications (Cambridge, England) vol. 47,42 (2011): 11659-61. doi: https://doi.org/10.1039/c1cc14473a
Bailey PJ, Bell NL, Gim LL, Yucheng T, Funnell N, White F, Parsons S. "Twisted" scorpionates: synthesis of a tris(2-pyridonyl)borate (Thp) ligand; lessons in the requirements for successful B(L2D)3 type ligands. Chem Commun (Camb). 2011 Nov 14;47(42):11659-61. doi: 10.1039/c1cc14473a. Epub 2011 Sep 30. PMID: 21959268.
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Chem Commun (Camb). 2011 Nov 14;47(42):11659-61. doi: 10.1039/c1cc14473a. Epub 2011 Sep 30.

"Twisted" scorpionates: synthesis of a tris(2-pyridonyl)borate (Thp) ligand; lessons in the requirements for successful B(L2D)3 type ligands.

Chemical communications (Cambridge, England)

Philip J Bailey, Nicola L Bell, Lim Li Gim, Tai Yucheng, Nicholas Funnell, Fraser White, Simon Parsons

Affiliations

  1. EaStCHEM School of Chemistry, Jospeh Black Building, West Mains Road, Edinburgh, EH9 3JJ. [email protected]

PMID: 21959268 DOI: 10.1039/c1cc14473a

Abstract

The synthesis of a new charge-neutral zwitterionic tripodal borate ligand based on 2-hydroxypyridine is reported. (Dimethylaminopyridinium)tris(2-pyridonyl)borate, (DMAP)Thp, has been complexed to copper(I) chloride to give a pseudo-C(3) symmetric complex. The propensity for this ligand and other flexible scorpionates to exhibit such helical chirality upon complexation is discussed.

This journal is © The Royal Society of Chemistry 2011

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