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Gao LH, Wang KZ, Wang LY. Preparation and electrochemical and electrocatalytic properties of nanocomposite multilayer film based on a Keggin-type phosphomolybdate. J Nanosci Nanotechnol. 2011;11(11):9861-4doi: 10.1166/jnn.2011.5314.
Gao, L. H., Wang, K. Z., & Wang, L. Y. (2011). Preparation and electrochemical and electrocatalytic properties of nanocomposite multilayer film based on a Keggin-type phosphomolybdate. Journal of nanoscience and nanotechnology, 11(11), 9861-4. https://doi.org/10.1166/jnn.2011.5314
Gao, Li-Hua, et al. "Preparation and electrochemical and electrocatalytic properties of nanocomposite multilayer film based on a Keggin-type phosphomolybdate." Journal of nanoscience and nanotechnology vol. 11,11 (2011): 9861-4. doi: https://doi.org/10.1166/jnn.2011.5314
Gao LH, Wang KZ, Wang LY. Preparation and electrochemical and electrocatalytic properties of nanocomposite multilayer film based on a Keggin-type phosphomolybdate. J Nanosci Nanotechnol. 2011 Nov;11(11):9861-4. doi: 10.1166/jnn.2011.5314. PMID: 22413310.
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J Nanosci Nanotechnol. 2011 Nov;11(11):9861-4. doi: 10.1166/jnn.2011.5314.

Preparation and electrochemical and electrocatalytic properties of nanocomposite multilayer film based on a Keggin-type phosphomolybdate.

Journal of nanoscience and nanotechnology

Li-Hua Gao, Ke-Zhi Wang, Li-Ying Wang

Affiliations

  1. Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048, China.

PMID: 22413310 DOI: 10.1166/jnn.2011.5314

Abstract

An electrostatically self-assembled multilayer film has successfully been prepared on quartz or indium-tin-oxide substrates by alternating adsorption of a Keggin-type phosphomolybdate H3PMo12O40 (PMo12) and 1,10-diaminodecane (1,10-DAD). The formation of (PMo12/1,10-DAD), film was investigated by ultraviolet (UV) spectroscopy. The UV spectra showed that the deposition of the films was uniform and reproducible. The cyclic voltammetry on the PMo12-based multilayer film indicated that the PMo12 anions in the film undergo rapid four 2e(-)/2H+ redox processes, and electrocatalytically active towards the reduction of bromate.

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