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Phys Rev Lett. 2015 Jan 16;114(2):024501. doi: 10.1103/PhysRevLett.114.024501. Epub 2015 Jan 14.

Quantum vacuum photon modes and superhydrophobicity.

Physical review letters

Louis Dellieu, Olivier Deparis, Jérôme Muller, Michaël Sarrazin

Affiliations

  1. Research Center in Physics of Matter and Radiation (PMR), Department of Physics, University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium.

PMID: 25635548 DOI: 10.1103/PhysRevLett.114.024501

Abstract

Nanostructures are commonly used for developing superhydrophobic surfaces. However, available wetting theoretical models ignore the effect of vacuum photon-mode alteration on van der Waals forces and thus on hydrophobicity. Using first-principles calculations, we show that superhydrophibicity of nanostructured surfaces is dramatically enhanced by vacuum photon-mode tuning. As a case study, wetting contact angles of a water droplet above a polyethylene nanostructured surface are obtained from the interaction potential energy calculated as a function of the droplet-surface separation distance. This new approach could pave the way for the design of novel superhydrophobic coatings.

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