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Bolbukh Y, Podkoscielna B, Lipke A, et al. Immobilization of Polymeric Luminophor on Nanoparticles Surface. Nanoscale Res Lett. 2016;11(1):206doi: 10.1186/s11671-016-1410-0.
Bolbukh, Y., Podkoscielna, B., Lipke, A., Bartnicki, A., Gawdzik, B., & Tertykh, V. (2016). Immobilization of Polymeric Luminophor on Nanoparticles Surface. Nanoscale research letters, 11(1), 206. https://doi.org/10.1186/s11671-016-1410-0
Bolbukh, Yuliia, et al. "Immobilization of Polymeric Luminophor on Nanoparticles Surface." Nanoscale research letters vol. 11,1 (2016): 206. doi: https://doi.org/10.1186/s11671-016-1410-0
Bolbukh Y, Podkoscielna B, Lipke A, Bartnicki A, Gawdzik B, Tertykh V. Immobilization of Polymeric Luminophor on Nanoparticles Surface. Nanoscale Res Lett. 2016 Dec;11(1):206. doi: 10.1186/s11671-016-1410-0. Epub 2016 Apr 18. PMID: 27090657; PMCID: PMC4835396.
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Nanoscale Res Lett. 2016 Dec;11(1):206. doi: 10.1186/s11671-016-1410-0. Epub 2016 Apr 18.

Immobilization of Polymeric Luminophor on Nanoparticles Surface.

Nanoscale research letters

Yuliia Bolbukh, Beata Podkoscielna, Agnieszka Lipke, Andrzej Bartnicki, Barbara Gawdzik, Valentin Tertykh

Affiliations

  1. Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, 17 General Naumov Str., 03164, Kyiv, Ukraine. [email protected].
  2. Faculty of Chemistry, Maria Curie-Sk?odowska University, pl. Maria Curie-Sk?odowskiej 3, 2-031, Lublin, Poland.
  3. Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, 17 General Naumov Str., 03164, Kyiv, Ukraine.

PMID: 27090657 PMCID: PMC4835396 DOI: 10.1186/s11671-016-1410-0

Abstract

Polymeric luminophors with reduced toxicity are of the priorities in the production of lighting devices, sensors, detectors, bioassays or diagnostic systems. The aim of this study was to develop a method of immobilization of the new luminophor on a surface of nanoparticles and investigation of the structure of the grafted layer. Monomer 2,7-(2-hydroxy-3-methacryloyloxypropoxy)naphthalene (2,7-NAF.DM) with luminophoric properties was immobilized on silica and carbon nanotubes in two ways: mechanical mixing with previously obtained polymer and by in situ oligomerization with chemisorption after carrier's modification with vinyl groups. The attached polymeric (or oligomeric) surface layer was studied using thermal and spectral techniques. Obtained results confirm the chemisorption of luminophor on the nanotubes and silica nanoparticles at the elaborated synthesis techniques. The microstructure of 2,7-NAF.DM molecules after chemisorption was found to be not changed. The elaborated modification approach allows one to obtain nanoparticles uniformly covered with polymeric luminophor.

Keywords: Chemisorption; Luminescence properties; Multiwalled carbon nanotubes; Polymeric luminophor; Silica nanoparticles

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