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H Ni, HA Nash, JG Worden… - Journal of Polymer …, 2002 - Wiley Online Library

Effect of catalysts on the reaction of an aliphatic isocyanate and water.

EPSCoR Research Infrastructure Improvement Program AND Program Evaluation

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GSID: lYNUVNzs-JkJ

Excerpt

The kinetics of the reaction of aliphatic isocyanate with water were investigated with hexyl isocyanate as a model compound. The kinetic study was carried out with a titration method to determine the concentration of the isocyanate group as a function of time. Gas chromatography was used to augment the kinetic data obtained from the titration method. The effects of an organic acid [p‐toluene sulfonic acid monohydrate (p‐TSA)], a tertiary amine {diazabicyclo [2.2. 2] octane (DABCO)}, and an organotin compound [dibutyltin …

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