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S Nagpure, Q Zhang, MA Khan, SZ Islam… - Advanced Functional …, 2018 - Wiley Online Library

Layer‐by‐Layer Synthesis of Thick Mesoporous TiO2 Films with Vertically Oriented Accessible Nanopores and Their Application for Lithium‐Ion Battery Negative ….

EPSCoR Research Infrastructure Improvement Program AND Program Evaluation

Islam, Khan, Zhang

GSID: b0YAB9mBuFYJ

Excerpt

TiO2 films of varying thicknesses (up to≈ 1.0 µm) with vertically oriented, accessible 7–9 nm nanopores are synthesized using an evaporation‐induced self‐assembly layer‐by‐layer technique. The hypothesis behind the approach is that epitaxial alignment of hydrophobic blocks of surfactant templates induces a consistent, accessible mesophase orientation across a multilayer film, ultimately leading to continuous, vertically aligned pore channels. Characterization using grazing incidence X‐ray scattering, scanning electron microscopy …

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