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Showing 13 to 24 of 856 entries
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Sex pheromone of a conifer-feeding budworm,Choristoneura retiniana, Walsingham.

Journal of chemical ecology

Daterman GE, Cory HT, Sower LL, Daves GD.
PMID: 24318237
J Chem Ecol. 1984 Jan;10(1):153-60. doi: 10.1007/BF00987652.

Sex pheromone components collected from femaleChristoneura retiniana included 11-tetradecenyl acetates and alcohols. The major component wasE-11-tetradecenyl acetate (E11-14∶Ac) with a lesser amount ofZ isomer necessary to induce male response. A 92∶8 ratio ofE,Z11-14∶ Ac appeared optimal. The alcohol component...

Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide.

Chemical communications (Cambridge, England)

Nogi K, Fujihara T, Terao J, Tsuji Y.
PMID: 24966094
Chem Commun (Camb). 2014 Nov 07;50(86):13052-5. doi: 10.1039/c4cc03644a.

The cobalt-catalyzed carboxylation of propargyl acetates with CO2 (1 atm) is described. The reaction proceeds at room temperature in the presence of Mn powder as a reducing reagent. Various propargyl acetates are converted to the corresponding carboxylic acids in...

Formic acid in caustic cephalic secretions of stingless bee,Oxytrigona (Hymenoptera: Apidae).

Journal of chemical ecology

Roubik DW, Smith BH, Carlson RG.
PMID: 24302133
J Chem Ecol. 1987 May;13(5):1079-86. doi: 10.1007/BF01020539.

The cephalic extracts of two species in the stingless bee genusOxytrigona were analyzed. Extracts made in diethyl ether, and then derivatized with diphenyldiazomethane, revealed large quantities of formic acid, potentially a major defensive secretion of this stingless bee group....

Blackheaded fireworm: Laboratory and field studies of its sex pheromone.

Journal of chemical ecology

McDonough LM, Davis HG, Voerman S.
PMID: 24302145
J Chem Ecol. 1987 May;13(5):1235-42. doi: 10.1007/BF01020551.

Electroantennogram (EAG) responses of maleRhopobota naevana (Hübner), the blackheaded fireworm, to all of the monoene straightchain 12- and 14-carbon alcohols and acetates implicated (Z)-11-tetradecenl-1-ol (Z11-14∶OH) and its acetate (Z11-14∶Ac) as sex pheromone components.Z11-14∶Ac produced the strongest EAG response of...

Chemistry and field evaluation of the sex pheromone of western spruce budworm,Choristoneura occidentalis, Freeman.

Journal of chemical ecology

Cory HT, Daterman GE, Daves GD, Sower LL, Shepherd RF, Sanders CJ.
PMID: 24414945
J Chem Ecol. 1982 Feb;8(2):339-50. doi: 10.1007/BF00987782.

Chemical analyses and field bioassays showed a mixture of 92% (E)- and 8% (Z)-11-tetradecenal to be the sex attractant pheromone of the western spruce budworm,Choristoneura occidentalis Freeman. Females were also found to emit small amounts of the corresponding acetates...

Experiments with a two-component sex attractant of the silver Y moth (Autographa gamma L.), and some evidence for the presence of both components in natural female sex pheromone.

Journal of chemical ecology

Tóth M, Szőcs G, Majoros B, Bellas TE, Novák L.
PMID: 24407861
J Chem Ecol. 1983 Sep;9(9):1317-25. doi: 10.1007/BF00994800.

(Z)-7-Dodecen-1-yl acetate and (Z)-7-dodecen-1-ol were synthesized and tested on males of the silver Y moth (Autographa gamma L.) for sex attractant activity. The key step of the synthesis was the isomerization of acetylenic alcohol (III) with potassium 3-amino-propylamide. In...

Insect sex pheromones: Determination of half-lives from formulations by collection of emitted vapor.

Journal of chemical ecology

McDonough LM, Butler LI.
PMID: 24408805
J Chem Ecol. 1983 Nov;9(11):1491-502. doi: 10.1007/BF00988515.

A new method for determining half-lives for the evaporation of sex pheromones from formulations has been developed. A previously unexploited mathematical relationship makes possible the determination of half-lives of over 1000 days by collecting evaporated pheromone for 1-4 hr...

Pd-catalyzed gem-difluoroallylation of arylboronic acids with γ,γ-difluoroallylic acetates.

Chemical communications (Cambridge, England)

Zhang B, Zhang X.
PMID: 26611839
Chem Commun (Camb). 2016 Jan 21;52(6):1238-41. doi: 10.1039/c5cc08394j.

A highly regio- and stereo-selective palladium-catalyzed gem-difluoroallylation of arylboronic acids with γ,γ-difluoroallylic acetates has been described. The method allows the synthesis of a variety of gem-difluoroallylated arenes with a tosyloxy group on the C=C double bond, thus providing a...

Synthesis of Highly Substituted Pyridines through Copper-Catalyzed Condensation of Oximes and α,β-Unsaturated Imines.

Angewandte Chemie (International ed. in English)

Tan WW, Ong YJ, Yoshikai N.
PMID: 28524343
Angew Chem Int Ed Engl. 2017 Jul 03;56(28):8240-8244. doi: 10.1002/anie.201704378. Epub 2017 Jun 09.

A copper-catalyzed condensation reaction of oxime acetates and α,β-unsaturated ketimines to give pyridine derivatives is reported. The reaction features mild conditions, high functional-group compatibility, and high regioselectivity with respect to unsymmetrical oxime acetates, thus allowing the preparation of a...

Cu-Catalyzed Three-Component Cascade Annulation Reaction: An Entry to Functionalized Pyridines.

The Journal of organic chemistry

Jiang H, Yang J, Tang X, Li J, Wu W.
PMID: 26287947
J Org Chem. 2015 Sep 04;80(17):8763-71. doi: 10.1021/acs.joc.5b01621. Epub 2015 Aug 24.

A concise copper-catalyzed N-O bond cleavage/C-C/C-N bond formation procedure has been described for the synthesis of multisubstituted pyridines. Various oxime acetates, activated methylene compounds, and a wide range of aldehydes bearing aryl, heteroaryl, vinyl, and trifluoromethyl groups were employed...

Correction to Catalytic Enantioselective Desymmetrization of 1,3-Diazido-2-propanol via Intramolecular Interception of Alkyl Azides with Diazo(aryl)acetates.

Organic letters

Wu XP, Su Y, Gu P.
PMID: 26962635
Org Lett. 2016 Mar 18;18(6):1498. doi: 10.1021/acs.orglett.6b00564. Epub 2016 Mar 10.

No abstract available.

Synthesis and X-ray Characterization of Alkali Metal 2-Acyl-1,1,3,3-tetracyanopropenides.

The Journal of organic chemistry

Karpov SV, Grigor'ev AA, Kayukov YS, Karpova IV, Nasakin OE, Tafeenko VA.
PMID: 27384963
J Org Chem. 2016 Aug 05;81(15):6402-8. doi: 10.1021/acs.joc.6b01040. Epub 2016 Jul 13.

A novel route for synthesis of 2-acyl-1,1,3,3-tetracyanopropenides (ATCN) salts in high yields and excellent purities starting from readily available methyl ketones, malononitrile, bromine, and alkali metal acetates is reported. The starting aryl(heteroaryl) methyl ketones were oxidized to the corresponding...

Showing 13 to 24 of 856 entries