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Showing 13 to 24 of 299 entries
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Ruthenium-catalyzed cycloaddition of propargylic alcohols with phenol derivatives via allenylidene intermediates: catalytic use of the allenylidene ligand as the C(3) unit.

Journal of the American Chemical Society

Nishibayashi Y, Inada Y, Hidai M, Uemura S.
PMID: 12095324
J Am Chem Soc. 2002 Jul 10;124(27):7900-1. doi: 10.1021/ja026168x.

Novel ruthenium-catalyzed cycloaddition of propargylic alcohols with 2-naphthols and phenols bearing electron-donating groups via allenylidene intermediates has been developed to give the corresponding 1H-naphtho[2,1-b]pyrans and 4H-1-benzopyrans, respectively, in moderate to excellent yields with complete regioselectivity.

Efficient synthesis of 4-(2'-alkenyl)-2,5-dihydrofurans and 5,6-dihydro-2H-pyrans via the Pd-catalyzed cyclizative coupling reaction of 2,3- or 3,4-allenols with allylic halides.

The Journal of organic chemistry

Ma S, Gao W.
PMID: 12182649
J Org Chem. 2002 Aug 23;67(17):6104-12. doi: 10.1021/jo0163997.

In the absence of a base, palladium(II) catalysts, such as PdCl(2), PdCl(2)(CH(3)CN)(2), Pd(OAc)(2), and [(pi-C(3)H(5))PdCl](2), can catalyze the cyclizative coupling reaction of 2,3- or 3,4-allenols with allylic halides in DMA at room temperature to provide 2,5-dihydrofurans and 5,6-dihydro-2H-pyrans, respectively,...

Continuous irradiation and flash-photolysis studies of new[3H]naphtho[2,1-b]pyrans linked by covalent bonds to oligothiophene units. Effect of thiophene substituents on the photochromism.

Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology

Frigoli M, Pimienta V, Moustrou C, Samat A, Guglielmetti R, Aubard J, Maurel F, Micheau JC.
PMID: 14521228
Photochem Photobiol Sci. 2003 Aug;2(8):888-92. doi: 10.1039/b301999c.

The influence of oligothiophene substituents on five new [3H]naphtho[2,1-b]pyrans has been investigated using flash photolysis and continuous irradiation techniques. Photochromic properties strongly depend on the number and position of the thienyl units. Thienyl substitution increases the UV/visible absorbance of...

Easy access to trans-2,3-disubstituted cyclobutanones, 2,4,5-trisubstituted 3,6-dihydro-2H-pyrans and cis-substituted phenylcyclopropylsulfones by using the highly versatile 1-phenylsulfenyl- or 1-phenylsulfonyl-cyclopropylketones.

Organic & biomolecular chemistry

Alberti G, Bernard AM, Floris C, Frongia A, Piras PP, Secci F, Spiga M.
PMID: 19675908
Org Biomol Chem. 2009 Sep 07;7(17):3512-9. doi: 10.1039/b906695k. Epub 2009 Jul 06.

The high versatility of 1-phenylsulfenyl- or 1-phenylsulfonyl-cyclopropylketones has been exploited for the regioselective synthesis of trans-2,3-disubstituted cyclobutanones, 2,4,5-trisubstituted 3,6-dihydro-2H-pyrans and cis-2-alkyl- or cis-2-aryl-cyclopropylphenylsulfones.

Transient absorption studies of the photochromic behavior of 3H-naphtho[2,1-b]pyrans linked to thiophene oligomers via an acetylenic junction.

The journal of physical chemistry. A

Moine B, Réhault J, Aloïse S, Micheau JC, Moustrou C, Samat A, Poizat O, Buntinx G.
PMID: 18457379
J Phys Chem A. 2008 May 29;112(21):4719-26. doi: 10.1021/jp711865j. Epub 2008 May 06.

The photophysical and photochemical properties of four 3,3-diphenyl-3H-naphtho[2,1- b]pyrans substituted, via an acetylenic junction, to (thiophene) n oligomers (n = 0-3 units) were investigated by transient absorption in the femtosecond to microsecond time domain and by stationary absorption and...

Synthesis and photochromism of novel phenylene-linked photochromic bispyrans.

Organic letters

Zhao W, Carreira EM.
PMID: 16381577
Org Lett. 2006 Jan 05;8(1):99-102. doi: 10.1021/ol052587y.

[reaction: see text] Phenylene-linked bisnaphthopyrans were synthesized in good yields via the one-pot reaction of bis-propargyl alcohols with naphthols. Temperature-dependent photochromism in 1,4-phenylene-linked bispyrans leads to up to 60 nm bathochromic shift between the colored species formed at room...

Neuroprotection with anaesthetic agents.

Current opinion in anaesthesiology

Hans P, Bonhomme V.
PMID: 17019135
Curr Opin Anaesthesiol. 2001 Oct;14(5):491-6. doi: 10.1097/00001503-200110000-00005.

The term 'neuroprotection' is used to refer to any prophylactic measure that is initiated during the peri-ischaemic period in order to improve neuronal survival. Cell death after ischaemia has an immediate, necrotic and a delayed, apoptotic origin. The major...

A clinical practice guideline update from the CCA.CFCRB-CPG.

The Journal of the Canadian Chiropractic Association

, Anderson-Peacock E, Bryans R, Danis N, Furlan A, Marcoux H, Potter B, Ruegg R, White E.
PMID: 17657287
J Can Chiropr Assoc. 2007 Mar;51(1):19-22.

No abstract available.

Interaction between Chloroplasts and Mitochondria in Microalgae: Role of Glycolysis.

Plant physiology

Rebeille F, Gans P.
PMID: 16666488
Plant Physiol. 1988 Dec;88(4):973-5. doi: 10.1104/pp.88.4.973.

In a mutant strain of Chlamydomonas reinhardtii devoid of active ribulose 1,5-bisphosphate carboxylase oxygenase, the addition of mitochondrial inhibitors in the dark resulted in a pronounced decrease in cellular ATP, a fall of the glucose 6-phosphate content, and a...

Relationship between Respiration and Photosynthesis in Guard Cell and Mesophyll Cell Protoplasts of Commelina communis L.

Plant physiology

Gautier H, Vavasseur A, Gans P, Lascève G.
PMID: 16668030
Plant Physiol. 1991 Feb;95(2):636-41. doi: 10.1104/pp.95.2.636.

A mass spectrometric method combining (16)O/(18)O and (12)C/(13)C isotopes was used to quantify the unidirectional fluxes of O(2) and CO(2) during a dark to light transition for guard cell protoplasts and mesophyll cell protoplasts of Commelina communis L. In...

Isotopic effect in extended x-ray-absorption fine structure of germanium.

Physical review letters

Purans J, Afify ND, Dalba G, Grisenti R, De Panfilis S, Kuzmin A, Ozhogin VI, Rocca F, Sanson A, Tiutiunnikov SI, Fornasini P.
PMID: 18352392
Phys Rev Lett. 2008 Feb 08;100(5):055901. doi: 10.1103/PhysRevLett.100.055901. Epub 2008 Feb 08.

Extended x-ray absorption fine structure has been measured on two powdered samples of (70)Ge and (76)Ge as a function of temperature from 20 to 300 K. The effect of isotopic mass difference on the amplitude of relative atomic vibrations...

Ruthenium-catalyzed transformation of 3-benzyl but-1-ynyl ethers into 1,3-dienes and benzaldehyde via transfer hydrogen.

The Journal of organic chemistry

Yeh KL, Liu B, Lai YT, Li CW, Liu RS.
PMID: 15230591
J Org Chem. 2004 Jul 09;69(14):4692-4. doi: 10.1021/jo049514x.

TpRuPPh(3)(CH(3)CN)(2)PF(6) catalyzed the transformation of various 3-benzyl but-1-ynyl ethers into dienes and benzaldehyde at a catalyst loading of 5 mol %. This process represents an atypical pattern of transfer hydrogenation. This catalytic reaction can be applied to various derivatives...

Showing 13 to 24 of 299 entries