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Palladium-Catalyzed Aerobic Oxidative Coupling of Allylic Alcohols with Anilines in the Synthesis of Nitrogen Heterocycles.

The Journal of organic chemistry

Kumar GS, Singh D, Kumar M, Kapur M.
PMID: 29533639
J Org Chem. 2018 Apr 06;83(7):3941-3951. doi: 10.1021/acs.joc.8b00287. Epub 2018 Mar 19.

We report herein an unprecedented and expedient Pd-catalyzed oxidative coupling of allyl alcohols with anilines to afford β-amino ketones which are converted into substituted quinolines in a one-pot fashion. The exclusive preference for N-alkylation over N-allylation makes this approach...

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Kumar GS, Singh D, Kumar M, et al. Palladium-Catalyzed Aerobic Oxidative Coupling of Allylic Alcohols with Anilines in the Synthesis of Nitrogen Heterocycles. J Org Chem. 2018;83(7):3941-3951doi: 10.1021/acs.joc.8b00287.
Kumar, G. S., Singh, D., Kumar, M., & Kapur, M. (2018). Palladium-Catalyzed Aerobic Oxidative Coupling of Allylic Alcohols with Anilines in the Synthesis of Nitrogen Heterocycles. The Journal of organic chemistry, 83(7), 3941-3951. https://doi.org/10.1021/acs.joc.8b00287
Kumar, Gangam Srikanth, et al. "Palladium-Catalyzed Aerobic Oxidative Coupling of Allylic Alcohols with Anilines in the Synthesis of Nitrogen Heterocycles." The Journal of organic chemistry vol. 83,7 (2018): 3941-3951. doi: https://doi.org/10.1021/acs.joc.8b00287
Kumar GS, Singh D, Kumar M, Kapur M. Palladium-Catalyzed Aerobic Oxidative Coupling of Allylic Alcohols with Anilines in the Synthesis of Nitrogen Heterocycles. J Org Chem. 2018 Apr 06;83(7):3941-3951. doi: 10.1021/acs.joc.8b00287. Epub 2018 Mar 19. PMID: 29533639.
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Asymmetric Enamide-Imine Tautomerism in the Kinetic Resolution of Tertiary Alcohols.

Angewandte Chemie (International ed. in English)

Tang M, Gu H, He S, Rajkumar S, Yang X.
PMID: 34312956
Angew Chem Int Ed Engl. 2021 Sep 20;60(39):21334-21339. doi: 10.1002/anie.202106151. Epub 2021 Aug 18.

An efficient protocol for kinetic resolution of tertiary alcohols has been developed through an unprecedented asymmetric enamide-imine tautomerism process enabled by chiral phosphoric acid catalysis. A broad range of racemic 2-arylsulfonamido tertiary allyl alcohols could be kinetically resolved with...

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Tang M, Gu H, He S, et al. Asymmetric Enamide-Imine Tautomerism in the Kinetic Resolution of Tertiary Alcohols. Angew Chem Int Ed Engl. 2021;60(39):21334-21339doi: 10.1002/anie.202106151.
Tang, M., Gu, H., He, S., Rajkumar, S., & Yang, X. (2021). Asymmetric Enamide-Imine Tautomerism in the Kinetic Resolution of Tertiary Alcohols. Angewandte Chemie (International ed. in English), 60(39), 21334-21339. https://doi.org/10.1002/anie.202106151
Tang, Mengyao, et al. "Asymmetric Enamide-Imine Tautomerism in the Kinetic Resolution of Tertiary Alcohols." Angewandte Chemie (International ed. in English) vol. 60,39 (2021): 21334-21339. doi: https://doi.org/10.1002/anie.202106151
Tang M, Gu H, He S, Rajkumar S, Yang X. Asymmetric Enamide-Imine Tautomerism in the Kinetic Resolution of Tertiary Alcohols. Angew Chem Int Ed Engl. 2021 Sep 20;60(39):21334-21339. doi: 10.1002/anie.202106151. Epub 2021 Aug 18. PMID: 34312956.
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Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates.

Chemical communications (Cambridge, England)

Jiménez-Aquino A, Flegeau EF, Schneider U, Kobayashi S.
PMID: 21779598
Chem Commun (Camb). 2011 Sep 07;47(33):9456-8. doi: 10.1039/c1cc13348a. Epub 2011 Jul 22.

We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be...

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Jiménez-Aquino A, Flegeau EF, Schneider U, et al. Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates. Chem Commun (Camb). 2011;47(33):9456-8doi: 10.1039/c1cc13348a.
Jiménez-Aquino, A., Flegeau, E. F., Schneider, U., & Kobayashi, S. (2011). Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates. Chemical communications (Cambridge, England), 47(33), 9456-8. https://doi.org/10.1039/c1cc13348a
Jiménez-Aquino, Agustín, et al. "Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates." Chemical communications (Cambridge, England) vol. 47,33 (2011): 9456-8. doi: https://doi.org/10.1039/c1cc13348a
Jiménez-Aquino A, Flegeau EF, Schneider U, Kobayashi S. Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates. Chem Commun (Camb). 2011 Sep 07;47(33):9456-8. doi: 10.1039/c1cc13348a. Epub 2011 Jul 22. PMID: 21779598.
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Rhodium(III)-catalyzed oxidative annulation of isoquinolones with allyl alcohols: synthesis of isoindolo[2,1-.

Organic & biomolecular chemistry

Jiang J, Liu J, Yang Z, Zheng J, Tian X, Zheng L, Liu ZQ.
PMID: 34908095
Org Biomol Chem. 2022 Jan 05;20(2):339-344. doi: 10.1039/d1ob02305e.

An efficient rhodium(III)-catalyzed direct C-H oxidative annulation of isoquinolones with allyl alcohols as C1 synthons has been successfully developed. This protocol enables the straightforward synthesis of structurally diverse isoindolo[2,1-

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Jiang J, Liu J, Yang Z, et al. Rhodium(III)-catalyzed oxidative annulation of isoquinolones with allyl alcohols: synthesis of isoindolo[2,1-. Org Biomol Chem. 2022;20(2):339-344doi: 10.1039/d1ob02305e.
Jiang, J., Liu, J., Yang, Z., Zheng, J., Tian, X., Zheng, L., & Liu, Z. Q. (2022). Rhodium(III)-catalyzed oxidative annulation of isoquinolones with allyl alcohols: synthesis of isoindolo[2,1-. Organic & biomolecular chemistry, 20(2), 339-344. https://doi.org/10.1039/d1ob02305e
Jiang, Jinyuan, et al. "Rhodium(III)-catalyzed oxidative annulation of isoquinolones with allyl alcohols: synthesis of isoindolo[2,1-." Organic & biomolecular chemistry vol. 20,2 (2022): 339-344. doi: https://doi.org/10.1039/d1ob02305e
Jiang J, Liu J, Yang Z, Zheng J, Tian X, Zheng L, Liu ZQ. Rhodium(III)-catalyzed oxidative annulation of isoquinolones with allyl alcohols: synthesis of isoindolo[2,1-. Org Biomol Chem. 2022 Jan 05;20(2):339-344. doi: 10.1039/d1ob02305e. PMID: 34908095.
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Direct copolymerization of ethylene with protic comonomers enabled by multinuclear Ni catalysts.

Nature communications

Ji G, Chen Z, Wang XY, Ning XS, Xu CJ, Zhang XM, Tao WJ, Li JF, Gao Y, Shen Q, Sun XL, Wang HY, Zhao JB, Zhang B, Guo YL, Zhao Y, Sun J, Luo Y, Tang Y.
PMID: 34725330
Nat Commun. 2021 Nov 01;12(1):6283. doi: 10.1038/s41467-021-26470-x.

Ethylene/polar monomer coordination copolymerization offers an attractive way of making functionalized polyolefins. However, ethylene copolymerization with industrially relevant short chain length alkenoic acid remain a big challenge. Here we report the efficient direct copolymerization of ethylene with vinyl acetic...

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Ji G, Chen Z, Wang XY, et al. Direct copolymerization of ethylene with protic comonomers enabled by multinuclear Ni catalysts. Nat Commun. 2021;12(1):6283doi: 10.1038/s41467-021-26470-x.
Ji, G., Chen, Z., Wang, X. Y., Ning, X. S., Xu, C. J., Zhang, X. M., Tao, W. J., Li, J. F., Gao, Y., Shen, Q., Sun, X. L., Wang, H. Y., Zhao, J. B., Zhang, B., Guo, Y. L., Zhao, Y., Sun, J., Luo, Y., & Tang, Y. (2021). Direct copolymerization of ethylene with protic comonomers enabled by multinuclear Ni catalysts. Nature communications, 12(1), 6283. https://doi.org/10.1038/s41467-021-26470-x
Ji, Gang, et al. "Direct copolymerization of ethylene with protic comonomers enabled by multinuclear Ni catalysts." Nature communications vol. 12,1 (2021): 6283. doi: https://doi.org/10.1038/s41467-021-26470-x
Ji G, Chen Z, Wang XY, Ning XS, Xu CJ, Zhang XM, Tao WJ, Li JF, Gao Y, Shen Q, Sun XL, Wang HY, Zhao JB, Zhang B, Guo YL, Zhao Y, Sun J, Luo Y, Tang Y. Direct copolymerization of ethylene with protic comonomers enabled by multinuclear Ni catalysts. Nat Commun. 2021 Nov 01;12(1):6283. doi: 10.1038/s41467-021-26470-x. PMID: 34725330; PMCID: PMC8560877.
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Showing 253 to 257 of 257 entries