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B-B bond activation and NHC ring-expansion reactions of diboron(4) compounds, and accurate molecular structures of B.

Dalton transactions (Cambridge, England : 2003)

Eck M, Würtemberger-Pietsch S, Eichhorn A, Berthel JH, Bertermann R, Paul US, Schneider H, Friedrich A, Kleeberg C, Radius U, Marder TB.
PMID: 28252145
Dalton Trans. 2017 Mar 14;46(11):3661-3680. doi: 10.1039/c7dt00334j.

In this detailed study we report on the structures of the widely employed diboron(4) compounds bis(pinacolato)diboron (B

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Eck M, Würtemberger-Pietsch S, Eichhorn A, et al. B-B bond activation and NHC ring-expansion reactions of diboron(4) compounds, and accurate molecular structures of B. Dalton Trans. 2017;46(11):3661-3680doi: 10.1039/c7dt00334j.
Eck, M., Würtemberger-Pietsch, S., Eichhorn, A., Berthel, J. H., Bertermann, R., Paul, U. S., Schneider, H., Friedrich, A., Kleeberg, C., Radius, U., & Marder, T. B. (2017). B-B bond activation and NHC ring-expansion reactions of diboron(4) compounds, and accurate molecular structures of B. Dalton transactions (Cambridge, England : 2003), 46(11), 3661-3680. https://doi.org/10.1039/c7dt00334j
Eck, Martin, et al. "B-B bond activation and NHC ring-expansion reactions of diboron(4) compounds, and accurate molecular structures of B." Dalton transactions (Cambridge, England : 2003) vol. 46,11 (2017): 3661-3680. doi: https://doi.org/10.1039/c7dt00334j
Eck M, Würtemberger-Pietsch S, Eichhorn A, Berthel JH, Bertermann R, Paul US, Schneider H, Friedrich A, Kleeberg C, Radius U, Marder TB. B-B bond activation and NHC ring-expansion reactions of diboron(4) compounds, and accurate molecular structures of B. Dalton Trans. 2017 Mar 14;46(11):3661-3680. doi: 10.1039/c7dt00334j. PMID: 28252145.
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Synthesis of Vinyl-, Allyl-, and 2-Boryl Allylboronates via a Highly Selective Copper-Catalyzed Borylation of Propargylic Alcohols.

Organic letters

Mao L, Bertermann R, Emmert K, Szabó KJ, Marder TB.
PMID: 29181971
Org Lett. 2017 Dec 15;19(24):6586-6589. doi: 10.1021/acs.orglett.7b03294. Epub 2017 Nov 28.

An efficient methodology for the synthesis of vinyl-, allyl-, and (E)-2-boryl allylboronates from propargylic alcohols via Cu-catalyzed borylation under mild conditions is reported. In the presence of commercially available Cu(OAc)

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Mao L, Bertermann R, Emmert K, et al. Synthesis of Vinyl-, Allyl-, and 2-Boryl Allylboronates via a Highly Selective Copper-Catalyzed Borylation of Propargylic Alcohols. Org Lett. 2017;19(24):6586-6589doi: 10.1021/acs.orglett.7b03294.
Mao, L., Bertermann, R., Emmert, K., Szabó, K. J., & Marder, T. B. (2017). Synthesis of Vinyl-, Allyl-, and 2-Boryl Allylboronates via a Highly Selective Copper-Catalyzed Borylation of Propargylic Alcohols. Organic letters, 19(24), 6586-6589. https://doi.org/10.1021/acs.orglett.7b03294
Mao, Lujia, et al. "Synthesis of Vinyl-, Allyl-, and 2-Boryl Allylboronates via a Highly Selective Copper-Catalyzed Borylation of Propargylic Alcohols." Organic letters vol. 19,24 (2017): 6586-6589. doi: https://doi.org/10.1021/acs.orglett.7b03294
Mao L, Bertermann R, Emmert K, Szabó KJ, Marder TB. Synthesis of Vinyl-, Allyl-, and 2-Boryl Allylboronates via a Highly Selective Copper-Catalyzed Borylation of Propargylic Alcohols. Org Lett. 2017 Dec 15;19(24):6586-6589. doi: 10.1021/acs.orglett.7b03294. Epub 2017 Nov 28. PMID: 29181971.
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Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-Viscosity Ionic Liquids.

Chemistry (Weinheim an der Bergstrasse, Germany)

Landmann J, Sprenger JAP, Hennig PT, Bertermann R, Grüne M, Würthner F, Ignat'ev NV, Finze M.
PMID: 28884848
Chemistry. 2018 Jan 12;24(3):608-623. doi: 10.1002/chem.201703685. Epub 2017 Nov 15.

The potassium perfluoroalkyltricyanoborates K[C

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Landmann J, Sprenger JAP, Hennig PT, et al. Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-Viscosity Ionic Liquids. Chemistry. 2017;24(3):608-623doi: 10.1002/chem.201703685.
Landmann, J., Sprenger, J. A. P., Hennig, P. T., Bertermann, R., Grüne, M., Würthner, F., Ignat'ev, N. V., & Finze, M. (2018). Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-Viscosity Ionic Liquids. Chemistry (Weinheim an der Bergstrasse, Germany), 24(3), 608-623. https://doi.org/10.1002/chem.201703685
Landmann, Johannes, et al. "Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-Viscosity Ionic Liquids." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 24,3 (2018): 608-623. doi: https://doi.org/10.1002/chem.201703685
Landmann J, Sprenger JAP, Hennig PT, Bertermann R, Grüne M, Würthner F, Ignat'ev NV, Finze M. Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-Viscosity Ionic Liquids. Chemistry. 2018 Jan 12;24(3):608-623. doi: 10.1002/chem.201703685. Epub 2017 Nov 15. PMID: 28884848.
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Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle.

Chemical communications (Cambridge, England)

Bergemann N, Pistidda C, Milanese C, Emmler T, Karimi F, Chaudhary AL, Chierotti MR, Klassen T, Dornheim M.
PMID: 26971390
Chem Commun (Camb). 2016 Apr 04;52(26):4836-9. doi: 10.1039/c5cc09991a. Epub 2016 Mar 14.

The Ca(BH4)2-Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and...

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Bergemann N, Pistidda C, Milanese C, et al. Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle. Chem Commun (Camb). 2016;52(26):4836-9doi: 10.1039/c5cc09991a.
Bergemann, N., Pistidda, C., Milanese, C., Emmler, T., Karimi, F., Chaudhary, A. L., Chierotti, M. R., Klassen, T., & Dornheim, M. (2016). Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle. Chemical communications (Cambridge, England), 52(26), 4836-9. https://doi.org/10.1039/c5cc09991a
Bergemann, N, et al. "Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle." Chemical communications (Cambridge, England) vol. 52,26 (2016): 4836-9. doi: https://doi.org/10.1039/c5cc09991a
Bergemann N, Pistidda C, Milanese C, Emmler T, Karimi F, Chaudhary AL, Chierotti MR, Klassen T, Dornheim M. Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle. Chem Commun (Camb). 2016 Apr 04;52(26):4836-9. doi: 10.1039/c5cc09991a. Epub 2016 Mar 14. PMID: 26971390.
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Stable Four-Coordinate Guanidinatosilicon(IV) Complexes with SiN3El Skeletons (El = S, Se, Te) and Si=El Double Bonds.

Chemistry (Weinheim an der Bergstrasse, Germany)

Mück FM, Kloß D, Baus JA, Burschka C, Bertermann R, Poater J, Fonseca Guerra C, Bickelhaupt FM, Tacke R.
PMID: 26284318
Chemistry. 2015 Sep 28;21(40):14011-21. doi: 10.1002/chem.201501789. Epub 2015 Aug 18.

To get information about the reactivity profile of the donor-stabilized guanidinatosilicon(II) complexes 2 and 3, a series of oxidative addition reactions was studied. Treatment of 2 and 3 with S8, Se, or Te afforded the respective four-coordinate silicon(IV) complexes...

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Mück FM, Kloß D, Baus JA, et al. Stable Four-Coordinate Guanidinatosilicon(IV) Complexes with SiN3El Skeletons (El = S, Se, Te) and Si=El Double Bonds. Chemistry. 2015;21(40):14011-21doi: 10.1002/chem.201501789.
Mück, F. M., Kloß, D., Baus, J. A., Burschka, C., Bertermann, R., Poater, J., Fonseca Guerra, C., Bickelhaupt, F. M., & Tacke, R. (2015). Stable Four-Coordinate Guanidinatosilicon(IV) Complexes with SiN3El Skeletons (El = S, Se, Te) and Si=El Double Bonds. Chemistry (Weinheim an der Bergstrasse, Germany), 21(40), 14011-21. https://doi.org/10.1002/chem.201501789
Mück, Felix M, et al. "Stable Four-Coordinate Guanidinatosilicon(IV) Complexes with SiN3El Skeletons (El = S, Se, Te) and Si=El Double Bonds." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 21,40 (2015): 14011-21. doi: https://doi.org/10.1002/chem.201501789
Mück FM, Kloß D, Baus JA, Burschka C, Bertermann R, Poater J, Fonseca Guerra C, Bickelhaupt FM, Tacke R. Stable Four-Coordinate Guanidinatosilicon(IV) Complexes with SiN3El Skeletons (El = S, Se, Te) and Si=El Double Bonds. Chemistry. 2015 Sep 28;21(40):14011-21. doi: 10.1002/chem.201501789. Epub 2015 Aug 18. PMID: 26284318.
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Microsatellite markers for the grapevine pathogen, Eutypa lata.

Molecular ecology resources

Baumgartner K, Bergemann SE, Fujiyoshi P, Rolshausen PE, Gubler WD.
PMID: 21564609
Mol Ecol Resour. 2009 Jan;9(1):222-4. doi: 10.1111/j.1755-0998.2008.02405.x. Epub 2008 Oct 21.

We isolated and characterized nine polymorphic microsatellite markers for Eutypa lata, a fungal pathogen responsible for Eutypa dieback of grapevine, in populations from two California vineyards (24 isolates per vineyard). Allele frequency ranged from two to 11 alleles per...

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Baumgartner K, Bergemann SE, Fujiyoshi P, et al. Microsatellite markers for the grapevine pathogen, Eutypa lata. Mol Ecol Resour. 2008;9(1):222-4doi: 10.1111/j.1755-0998.2008.02405.x.
Baumgartner, K., Bergemann, S. E., Fujiyoshi, P., Rolshausen, P. E., & Gubler, W. D. (2009). Microsatellite markers for the grapevine pathogen, Eutypa lata. Molecular ecology resources, 9(1), 222-4. https://doi.org/10.1111/j.1755-0998.2008.02405.x
Baumgartner, K, et al. "Microsatellite markers for the grapevine pathogen, Eutypa lata." Molecular ecology resources vol. 9,1 (2009): 222-4. doi: https://doi.org/10.1111/j.1755-0998.2008.02405.x
Baumgartner K, Bergemann SE, Fujiyoshi P, Rolshausen PE, Gubler WD. Microsatellite markers for the grapevine pathogen, Eutypa lata. Mol Ecol Resour. 2009 Jan;9(1):222-4. doi: 10.1111/j.1755-0998.2008.02405.x. Epub 2008 Oct 21. PMID: 21564609.
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Reduction of speckle noise in multiwavelength contouring.

Applied optics

Falldorf C, Huferath-von Luepke S, von Kopylow C, Bergmann RB.
PMID: 23207393
Appl Opt. 2012 Dec 01;51(34):8211-5. doi: 10.1364/AO.51.008211.

We report on a method that can be used to improve the result of multiwavelength contouring in the case of objects with rough surface. It is based on the combined evaluation of multiple measurements with varying direction of illumination....

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Falldorf C, Huferath-von Luepke S, von Kopylow C, et al. Reduction of speckle noise in multiwavelength contouring. Appl Opt. 2012;51(34):8211-5doi: 10.1364/AO.51.008211.
Falldorf, C., Huferath-von Luepke, S., von Kopylow, C., & Bergmann, R. B. (2012). Reduction of speckle noise in multiwavelength contouring. Applied optics, 51(34), 8211-5. https://doi.org/10.1364/AO.51.008211
Falldorf, Claas, et al. "Reduction of speckle noise in multiwavelength contouring." Applied optics vol. 51,34 (2012): 8211-5. doi: https://doi.org/10.1364/AO.51.008211
Falldorf C, Huferath-von Luepke S, von Kopylow C, Bergmann RB. Reduction of speckle noise in multiwavelength contouring. Appl Opt. 2012 Dec 01;51(34):8211-5. doi: 10.1364/AO.51.008211. PMID: 23207393.
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Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds.

Angewandte Chemie (International ed. in English)

Dömling M, Arrowsmith M, Schmidt U, Werner L, Castro AC, Jiménez-Halla JOC, Bertermann R, Müssig J, Prieschl D, Braunschweig H.
PMID: 31062910
Angew Chem Int Ed Engl. 2019 Jul 15;58(29):9782-9786. doi: 10.1002/anie.201902656. Epub 2019 Jun 06.

The transfer hydrogenation of N-heterocyclic carbene (NHC)-supported diborenes with dimethylamine borane proceeds with high selectivity for the trans-1,2-dihydrodiboranes. DFT calculations, supported by kinetic studies and deuteration experiments, suggest a stepwise proton-first-hydride-second reaction mechanism via an intermediate μ-hydrodiboronium dimethylaminoborate ion...

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Dömling M, Arrowsmith M, Schmidt U, et al. Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds. Angew Chem Int Ed Engl. 2019;58(29):9782-9786doi: 10.1002/anie.201902656.
Dömling, M., Arrowsmith, M., Schmidt, U., Werner, L., Castro, A. C., Jiménez-Halla, J. O. C., Bertermann, R., Müssig, J., Prieschl, D., & Braunschweig, H. (2019). Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds. Angewandte Chemie (International ed. in English), 58(29), 9782-9786. https://doi.org/10.1002/anie.201902656
Dömling, Michael, et al. "Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds." Angewandte Chemie (International ed. in English) vol. 58,29 (2019): 9782-9786. doi: https://doi.org/10.1002/anie.201902656
Dömling M, Arrowsmith M, Schmidt U, Werner L, Castro AC, Jiménez-Halla JOC, Bertermann R, Müssig J, Prieschl D, Braunschweig H. Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds. Angew Chem Int Ed Engl. 2019 Jul 15;58(29):9782-9786. doi: 10.1002/anie.201902656. Epub 2019 Jun 06. PMID: 31062910.
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The reductive coupling of dinitrogen.

Science (New York, N.Y.)

Légaré MA, Rang M, Bélanger-Chabot G, Schweizer JI, Krummenacher I, Bertermann R, Arrowsmith M, Holthausen MC, Braunschweig H.
PMID: 30898929
Science. 2019 Mar 22;363(6433):1329-1332. doi: 10.1126/science.aav9593. Epub 2019 Mar 21.

The coupling of two or more molecules of dinitrogen (N

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Légaré MA, Rang M, Bélanger-Chabot G, et al. The reductive coupling of dinitrogen. Science. 2019;363(6433):1329-1332doi: 10.1126/science.aav9593.
Légaré, M. A., Rang, M., Bélanger-Chabot, G., Schweizer, J. I., Krummenacher, I., Bertermann, R., Arrowsmith, M., Holthausen, M. C., & Braunschweig, H. (2019). The reductive coupling of dinitrogen. Science (New York, N.Y.), 363(6433), 1329-1332. https://doi.org/10.1126/science.aav9593
Légaré, Marc-André, et al. "The reductive coupling of dinitrogen." Science (New York, N.Y.) vol. 363,6433 (2019): 1329-1332. doi: https://doi.org/10.1126/science.aav9593
Légaré MA, Rang M, Bélanger-Chabot G, Schweizer JI, Krummenacher I, Bertermann R, Arrowsmith M, Holthausen MC, Braunschweig H. The reductive coupling of dinitrogen. Science. 2019 Mar 22;363(6433):1329-1332. doi: 10.1126/science.aav9593. Epub 2019 Mar 21. PMID: 30898929.
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Plant and Microbial Responses to Repeated Cu(OH).

Frontiers in microbiology

Simonin M, Colman BP, Tang W, Judy JD, Anderson SM, Bergemann CM, Rocca JD, Unrine JM, Cassar N, Bernhardt ES.
PMID: 30108580
Front Microbiol. 2018 Jul 31;9:1769. doi: 10.3389/fmicb.2018.01769. eCollection 2018.

The environmental fate and potential impacts of nanopesticides on agroecosystems under realistic agricultural conditions are poorly understood. As a result, the benefits and risks of these novel formulations compared to the conventional products are currently unclear. Here, we examined...

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Simonin M, Colman BP, Tang W, et al. Plant and Microbial Responses to Repeated Cu(OH). Front Microbiol. 2018;9:1769doi: 10.3389/fmicb.2018.01769.
Simonin, M., Colman, B. P., Tang, W., Judy, J. D., Anderson, S. M., Bergemann, C. M., Rocca, J. D., Unrine, J. M., Cassar, N., & Bernhardt, E. S. (2018). Plant and Microbial Responses to Repeated Cu(OH). Frontiers in microbiology, 91769. https://doi.org/10.3389/fmicb.2018.01769
Simonin, Marie, et al. "Plant and Microbial Responses to Repeated Cu(OH)." Frontiers in microbiology vol. 9 (2018): 1769. doi: https://doi.org/10.3389/fmicb.2018.01769
Simonin M, Colman BP, Tang W, Judy JD, Anderson SM, Bergemann CM, Rocca JD, Unrine JM, Cassar N, Bernhardt ES. Plant and Microbial Responses to Repeated Cu(OH). Front Microbiol. 2018 Jul 31;9:1769. doi: 10.3389/fmicb.2018.01769. eCollection 2018. PMID: 30108580; PMCID: PMC6079317.
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AGNP Consensus Guidelines for Therapeutic Drug Monitoring in Psychiatry: Update 2011.

Pharmacopsychiatry

Hiemke C, Baumann P, Bergemann N, Conca A, Dietmaier O, Egberts K, Fric M, Gerlach M, Greiner C, Gründer G, Haen E, Havemann-Reinecke U, Jaquenoud Sirot E, Kirchherr H, Laux G, Lutz UC, Messer T, Müller MJ, Pfuhlmann B, Rambeck B, Riederer P, Schoppek B, Stingl J, Uhr M, Ulrich S, Waschgler R, Zernig G.
PMID: 21969060
Pharmacopsychiatry. 2011 Sep;44(6):195-235. doi: 10.1055/s-0031-1286287. Epub 2011 Sep 27.

Therapeutic drug monitoring (TDM), i. e., the quantification of serum or plasma concentrations of medications for dose optimization, has proven a valuable tool for the patient-matched psychopharmacotherapy. Uncertain drug adherence, suboptimal tolerability, non-response at therapeutic doses, or pharmacokinetic drug-drug...

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Hiemke C, Baumann P, Bergemann N, et al. AGNP Consensus Guidelines for Therapeutic Drug Monitoring in Psychiatry: Update 2011. Pharmacopsychiatry. 2011;44(6):195-235doi: 10.1055/s-0031-1286287.
Hiemke, C., Baumann, P., Bergemann, N., Conca, A., Dietmaier, O., Egberts, K., Fric, M., Gerlach, M., Greiner, C., Gründer, G., Haen, E., Havemann-Reinecke, U., Jaquenoud Sirot, E., Kirchherr, H., Laux, G., Lutz, U. C., Messer, T., Müller, M. J., Pfuhlmann, B., Rambeck, B., Riederer, P., Schoppek, B., Stingl, J., Uhr, M., Ulrich, S., Waschgler, R., & Zernig, G. (2011). AGNP Consensus Guidelines for Therapeutic Drug Monitoring in Psychiatry: Update 2011. Pharmacopsychiatry, 44(6), 195-235. https://doi.org/10.1055/s-0031-1286287
Hiemke, C, et al. "AGNP Consensus Guidelines for Therapeutic Drug Monitoring in Psychiatry: Update 2011." Pharmacopsychiatry vol. 44,6 (2011): 195-235. doi: https://doi.org/10.1055/s-0031-1286287
Hiemke C, Baumann P, Bergemann N, Conca A, Dietmaier O, Egberts K, Fric M, Gerlach M, Greiner C, Gründer G, Haen E, Havemann-Reinecke U, Jaquenoud Sirot E, Kirchherr H, Laux G, Lutz UC, Messer T, Müller MJ, Pfuhlmann B, Rambeck B, Riederer P, Schoppek B, Stingl J, Uhr M, Ulrich S, Waschgler R, Zernig G. AGNP Consensus Guidelines for Therapeutic Drug Monitoring in Psychiatry: Update 2011. Pharmacopsychiatry. 2011 Sep;44(6):195-235. doi: 10.1055/s-0031-1286287. Epub 2011 Sep 27. PMID: 21969060.
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[No title available]

Bio-protocol

Matt K, Bergemann J.
PMID: 33654832
Bio Protoc. 2019 Aug 05;9(15):e3325. doi: 10.21769/BioProtoc.3325. eCollection 2019 Aug 05.

The ability of humans to repair DNA damages decreases with increasing age. In order to be able to repair daily occurring DNA damages, it becomes more and more important to preserve repair capability of cells with aging. The preservation...

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Matt K, Bergemann J. . Bio Protoc. 2019;9(15):e3325doi: 10.21769/BioProtoc.3325.
Matt, K., & Bergemann, J. (2019). . Bio-protocol, 9(15), e3325. https://doi.org/10.21769/BioProtoc.3325
Matt, Katja, and Bergemann, Jörg. "." Bio-protocol vol. 9,15 (2019): e3325. doi: https://doi.org/10.21769/BioProtoc.3325
Matt K, Bergemann J. . Bio Protoc. 2019 Aug 05;9(15):e3325. doi: 10.21769/BioProtoc.3325. eCollection 2019 Aug 05. PMID: 33654832; PMCID: PMC7854085.
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