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Ferromagnetism in an extended three-dimensional, diamond-like copper(II) network: a new copper(II)/1-hydroxybenzotriazolato complex exhibiting soft-magnet properties and two transitions at 6.4 and 4.4 K.

Inorganic chemistry

Tangoulis V, Raptopoulou CP, Psycharis V, Terzis A, Skorda K, Perlepes SP, Cador O, Kahn O, Bakalbassis EG.
PMID: 11197005
Inorg Chem. 2000 Jun 12;39(12):2522-9. doi: 10.1021/ic991149i.

The use of the substituted benzotriazole ligand btaOH (1-hydroxybenzotriazole) in copper(II) chemistry has yielded a structurally and magnetically very interesting complex. The [Cu2(O2CMe)4(H2O)2]/btaOH.H2O/aqueous NH3 (1:4:4, 1:3:3, 1:2:2) reaction system in MeOH gives dark brown-green [Cu(btaO)2(MeOH)]n (4) in approximately 80%...

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Tangoulis V, Raptopoulou CP, Psycharis V, et al. Ferromagnetism in an extended three-dimensional, diamond-like copper(II) network: a new copper(II)/1-hydroxybenzotriazolato complex exhibiting soft-magnet properties and two transitions at 6.4 and 4.4 K. Inorg Chem. 2000;39(12):2522-9doi: 10.1021/ic991149i.
Tangoulis, V., Raptopoulou, C. P., Psycharis, V., Terzis, A., Skorda, K., Perlepes, S. P., Cador, O., Kahn, O., & Bakalbassis, E. G. (2000). Ferromagnetism in an extended three-dimensional, diamond-like copper(II) network: a new copper(II)/1-hydroxybenzotriazolato complex exhibiting soft-magnet properties and two transitions at 6.4 and 4.4 K. Inorganic chemistry, 39(12), 2522-9. https://doi.org/10.1021/ic991149i
Tangoulis, V, et al. "Ferromagnetism in an extended three-dimensional, diamond-like copper(II) network: a new copper(II)/1-hydroxybenzotriazolato complex exhibiting soft-magnet properties and two transitions at 6.4 and 4.4 K." Inorganic chemistry vol. 39,12 (2000): 2522-9. doi: https://doi.org/10.1021/ic991149i
Tangoulis V, Raptopoulou CP, Psycharis V, Terzis A, Skorda K, Perlepes SP, Cador O, Kahn O, Bakalbassis EG. Ferromagnetism in an extended three-dimensional, diamond-like copper(II) network: a new copper(II)/1-hydroxybenzotriazolato complex exhibiting soft-magnet properties and two transitions at 6.4 and 4.4 K. Inorg Chem. 2000 Jun 12;39(12):2522-9. doi: 10.1021/ic991149i. PMID: 11197005.
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Syntheses and Characterization of gamma-[SiW(10)M(2)S(2)O(38)](6)(-) (M = Mo(V), W(V)). Two Keggin Oxothio Heteropolyanions with a Metal-Metal Bond.

Inorganic chemistry

Cadot E, Béreau V, Marg B, Halut S, Sécheresse F.
PMID: 11666504
Inorg Chem. 1996 May 22;35(11):3099-3106. doi: 10.1021/ic951054q.

The oxothio polyanions gamma-[SiW(10)M(2)S(2)O(38)](6)(-) (M = Mo(V), W(V)) were obtained through stereospecific addition of the dication [M(2)S(2)O(2)](2+) (M = Mo, W) to the divacant gamma-[SiW(10)O(36)](8)(-) anion in dimethylformamide. These compounds were isolated as crystals and are stable in usual...

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Cadot E, Béreau V, Marg B, et al. Syntheses and Characterization of gamma-[SiW(10)M(2)S(2)O(38)](6)(-) (M = Mo(V), W(V)). Two Keggin Oxothio Heteropolyanions with a Metal-Metal Bond. Inorg Chem. 1996;35(11):3099-3106doi: 10.1021/ic951054q.
Cadot, E., Béreau, V., Marg, B., Halut, S., & Sécheresse, F. (1996). Syntheses and Characterization of gamma-[SiW(10)M(2)S(2)O(38)](6)(-) (M = Mo(V), W(V)). Two Keggin Oxothio Heteropolyanions with a Metal-Metal Bond. Inorganic chemistry, 35(11), 3099-3106. https://doi.org/10.1021/ic951054q
Cadot, E., et al. "Syntheses and Characterization of gamma-[SiW(10)M(2)S(2)O(38)](6)(-) (M = Mo(V), W(V)). Two Keggin Oxothio Heteropolyanions with a Metal-Metal Bond." Inorganic chemistry vol. 35,11 (1996): 3099-3106. doi: https://doi.org/10.1021/ic951054q
Cadot E, Béreau V, Marg B, Halut S, Sécheresse F. Syntheses and Characterization of gamma-[SiW(10)M(2)S(2)O(38)](6)(-) (M = Mo(V), W(V)). Two Keggin Oxothio Heteropolyanions with a Metal-Metal Bond. Inorg Chem. 1996 May 22;35(11):3099-3106. doi: 10.1021/ic951054q. PMID: 11666504.
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New Metal Oxamates as Precursors of Low-Dimensional Heterobimetallics.

Inorganic chemistry

Fettouhi M, Ouahab L, Boukhari A, Cador O, Mathonière C, Kahn O.
PMID: 11666695
Inorg Chem. 1996 Aug 14;35(17):4932-4937. doi: 10.1021/ic960174a.

The goal of this work was to synthesize new molecular bricks which could be used as precursors of heterobimetallic low-dimensional compounds. Along this line, four compounds have been synthesized and structurally characterized, namely (NBu(4))(2)[Ni(Cl(2)opba)] (1), (NBu(4))(2)[Cu(Cl(2)opba)] (2), (NBu(4))(5)[Mn(Cl(2)opba)(DMSO)(2)](4) (3),...

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Fettouhi M, Ouahab L, Boukhari A, et al. New Metal Oxamates as Precursors of Low-Dimensional Heterobimetallics. Inorg Chem. 1996;35(17):4932-4937doi: 10.1021/ic960174a.
Fettouhi, M., Ouahab, L., Boukhari, A., Cador, O., Mathonière, C., & Kahn, O. (1996). New Metal Oxamates as Precursors of Low-Dimensional Heterobimetallics. Inorganic chemistry, 35(17), 4932-4937. https://doi.org/10.1021/ic960174a
Fettouhi, Mohammed, et al. "New Metal Oxamates as Precursors of Low-Dimensional Heterobimetallics." Inorganic chemistry vol. 35,17 (1996): 4932-4937. doi: https://doi.org/10.1021/ic960174a
Fettouhi M, Ouahab L, Boukhari A, Cador O, Mathonière C, Kahn O. New Metal Oxamates as Precursors of Low-Dimensional Heterobimetallics. Inorg Chem. 1996 Aug 14;35(17):4932-4937. doi: 10.1021/ic960174a. PMID: 11666695.
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Isotopic effects may induce cooperativity in valence tautomeric transition.

Chemical communications (Cambridge, England)

Cador O, Dei A, Sangregorio C.
PMID: 15010764
Chem Commun (Camb). 2004 Mar 21;(6):652-3. doi: 10.1039/b313049e. Epub 2004 Feb 10.

The replacing of CH(2)Cl(2) solvent molecules with their deuterated analogues in a Co complex undergoing valence-tautomeric interconversion drastically modifies its magnetic properties giving rise to a thermal hysteresis.

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Cador O, Dei A, Sangregorio C. Isotopic effects may induce cooperativity in valence tautomeric transition. Chem Commun (Camb). 2004;(6):652-3doi: 10.1039/b313049e.
Cador, O., Dei, A., & Sangregorio, C. (2004). Isotopic effects may induce cooperativity in valence tautomeric transition. Chemical communications (Cambridge, England), (6), 652-3. https://doi.org/10.1039/b313049e
Cador, Olivier, et al. "Isotopic effects may induce cooperativity in valence tautomeric transition." Chemical communications (Cambridge, England) vol. ,6 (2004): 652-3. doi: https://doi.org/10.1039/b313049e
Cador O, Dei A, Sangregorio C. Isotopic effects may induce cooperativity in valence tautomeric transition. Chem Commun (Camb). 2004 Mar 21;(6):652-3. doi: 10.1039/b313049e. Epub 2004 Feb 10. PMID: 15010764.
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[W].

Angewandte Chemie (International ed. in English)

Cadot E, Marrot J, Sécheresse F.
PMID: 11241620
Angew Chem Int Ed Engl. 2001 Feb 16;40(4):774-777. doi: 10.1002/1521-3773(20010216)40:4<774::aid-anie7740>3.0.co;2-l.

No abstract available.

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Cadot E, Marrot J, Sécheresse F. [W]. Angew Chem Int Ed Engl. 2001;40(4):774-777doi: 10.1002/1521-3773(20010216)40:4<774::aid-anie7740>3.0.co;2-l.
Cadot, E., Marrot, J., & Sécheresse, F. (2001). [W]. Angewandte Chemie (International ed. in English), 40(4), 774-777. https://doi.org/10.1002/1521-3773(20010216)40:4<774::aid-anie7740>3.0.co;2-l
Cadot, Emmanuel, et al. "[W]." Angewandte Chemie (International ed. in English) vol. 40,4 (2001): 774-777. doi: https://doi.org/10.1002/1521-3773(20010216)40:4<774::aid-anie7740>3.0.co;2-l
Cadot E, Marrot J, Sécheresse F. [W]. Angew Chem Int Ed Engl. 2001 Feb 16;40(4):774-777. doi: 10.1002/1521-3773(20010216)40:4<774::aid-anie7740>3.0.co;2-l. PMID: 11241620.
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Polyphosphate ions encapsulated in oxothiomolybdate rings: synthesis, structure, and behavior in solution.

Journal of the American Chemical Society

Cadot E, Pouet MJ, Robert-Labarre C, du Peloux C, Marrot J, Sécheresse F.
PMID: 15264848
J Am Chem Soc. 2004 Jul 28;126(29):9127-34. doi: 10.1021/ja048746a.

Cyclic oxothiomolybdates containing polyphosphate ions were prepared by simple reactions in aqueous medium of the corresponding polyphosphate ions and the cyclic precursor K(2)I(2)Mo(10)S(10)O(10)(OH)(10)(OH(2))(5).15H(2)O. K(5)[Cl(P(2)O(7)]Mo(12)S(12)O(12)(OH)(12)(H(2)O)(4)].22H(2)O (1) was isolated from concentrated chloride solution (2.5 mol.L(-1)). 1 reveals a remarkable complex containing...

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Cadot E, Pouet MJ, Robert-Labarre C, et al. Polyphosphate ions encapsulated in oxothiomolybdate rings: synthesis, structure, and behavior in solution. J Am Chem Soc. 2004;126(29):9127-34doi: 10.1021/ja048746a.
Cadot, E., Pouet, M. J., Robert-Labarre, C., du Peloux, C., Marrot, J., & Sécheresse, F. (2004). Polyphosphate ions encapsulated in oxothiomolybdate rings: synthesis, structure, and behavior in solution. Journal of the American Chemical Society, 126(29), 9127-34. https://doi.org/10.1021/ja048746a
Cadot, Emmanuel, et al. "Polyphosphate ions encapsulated in oxothiomolybdate rings: synthesis, structure, and behavior in solution." Journal of the American Chemical Society vol. 126,29 (2004): 9127-34. doi: https://doi.org/10.1021/ja048746a
Cadot E, Pouet MJ, Robert-Labarre C, du Peloux C, Marrot J, Sécheresse F. Polyphosphate ions encapsulated in oxothiomolybdate rings: synthesis, structure, and behavior in solution. J Am Chem Soc. 2004 Jul 28;126(29):9127-34. doi: 10.1021/ja048746a. PMID: 15264848.
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The magnetic möbius strip: synthesis, structure, and magnetic studies of odd-numbered antiferromagnetically coupled wheels.

Angewandte Chemie (International ed. in English)

Cador O, Gatteschi D, Sessoli R, Larsen FK, Overgaard J, Barra AL, Teat SJ, Timco GA, Winpenny RE.
PMID: 15455431
Angew Chem Int Ed Engl. 2004 Oct 04;43(39):5196-200. doi: 10.1002/anie.200460211.

No abstract available.

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Cador O, Gatteschi D, Sessoli R, et al. The magnetic möbius strip: synthesis, structure, and magnetic studies of odd-numbered antiferromagnetically coupled wheels. Angew Chem Int Ed Engl. 2004;43(39):5196-200doi: 10.1002/anie.200460211.
Cador, O., Gatteschi, D., Sessoli, R., Larsen, F. K., Overgaard, J., Barra, A. L., Teat, S. J., Timco, G. A., & Winpenny, R. E. (2004). The magnetic möbius strip: synthesis, structure, and magnetic studies of odd-numbered antiferromagnetically coupled wheels. Angewandte Chemie (International ed. in English), 43(39), 5196-200. https://doi.org/10.1002/anie.200460211
Cador, Olivier, et al. "The magnetic möbius strip: synthesis, structure, and magnetic studies of odd-numbered antiferromagnetically coupled wheels." Angewandte Chemie (International ed. in English) vol. 43,39 (2004): 5196-200. doi: https://doi.org/10.1002/anie.200460211
Cador O, Gatteschi D, Sessoli R, Larsen FK, Overgaard J, Barra AL, Teat SJ, Timco GA, Winpenny RE. The magnetic möbius strip: synthesis, structure, and magnetic studies of odd-numbered antiferromagnetically coupled wheels. Angew Chem Int Ed Engl. 2004 Oct 04;43(39):5196-200. doi: 10.1002/anie.200460211. PMID: 15455431.
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Redox-active organometallics: magnetic and electronic couplings through carbon-silicon hybrid molecular connectors.

Journal of the American Chemical Society

Hamon P, Justaud F, Cador O, Hapiot P, Rigaut S, Toupet L, Ouahab L, Stueger H, Hamon JR, Lapinte C.
PMID: 19053464
J Am Chem Soc. 2008 Dec 24;130(51):17372-83. doi: 10.1021/ja804608z.

Treatment of the triflate complex Cp*(dppe)FeOTf [12; Cp* = eta(5)-C(5)(CH(3))(5), dppe = 1,2-bis(diphenylphosphino)ethane, OTf = CF(3)SO(3)] with an excess of HC[triple bond]C-(Si(CH(3))(2))(x)-C[triple bond]CH (x = 2-4) in diethyl ether provides the binuclear bis(vinylidene) derivatives [Cp*(dppe)Fe=C=CH(Si(CH(3))(2))(x)CH=C=Fe(dppe)Cp*][OTf](2) (x = 2, 13;...

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Hamon P, Justaud F, Cador O, et al. Redox-active organometallics: magnetic and electronic couplings through carbon-silicon hybrid molecular connectors. J Am Chem Soc. 2008;130(51):17372-83doi: 10.1021/ja804608z.
Hamon, P., Justaud, F., Cador, O., Hapiot, P., Rigaut, S., Toupet, L., Ouahab, L., Stueger, H., Hamon, J. R., & Lapinte, C. (2008). Redox-active organometallics: magnetic and electronic couplings through carbon-silicon hybrid molecular connectors. Journal of the American Chemical Society, 130(51), 17372-83. https://doi.org/10.1021/ja804608z
Hamon, Paul, et al. "Redox-active organometallics: magnetic and electronic couplings through carbon-silicon hybrid molecular connectors." Journal of the American Chemical Society vol. 130,51 (2008): 17372-83. doi: https://doi.org/10.1021/ja804608z
Hamon P, Justaud F, Cador O, Hapiot P, Rigaut S, Toupet L, Ouahab L, Stueger H, Hamon JR, Lapinte C. Redox-active organometallics: magnetic and electronic couplings through carbon-silicon hybrid molecular connectors. J Am Chem Soc. 2008 Dec 24;130(51):17372-83. doi: 10.1021/ja804608z. PMID: 19053464.
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Changing the oxothiomolybdate ring from an anionic to a cationic receptor.

Inorganic chemistry

Lemonnier JF, Floquet S, Marrot J, Kachmar A, Bénard M, Rohmer MM, Haouas M, Taulelle F, Henry M, Cadot E.
PMID: 17929915
Inorg Chem. 2007 Nov 12;46(23):9516-8. doi: 10.1021/ic701432s. Epub 2007 Oct 12.

The ionic recognition properties of neutral oxothiomolybdenum wheels can be changed from anionic to cationic through ionization of the internal aquo ligands. In the solid state, [Mo8O8S8(OH)10(H2O)]2- (1) interacts with two Cs+ cations to give a close supramolecular host-guest...

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Lemonnier JF, Floquet S, Marrot J, et al. Changing the oxothiomolybdate ring from an anionic to a cationic receptor. Inorg Chem. 2007;46(23):9516-8doi: 10.1021/ic701432s.
Lemonnier, J. F., Floquet, S., Marrot, J., Kachmar, A., Bénard, M., Rohmer, M. M., Haouas, M., Taulelle, F., Henry, M., & Cadot, E. (2007). Changing the oxothiomolybdate ring from an anionic to a cationic receptor. Inorganic chemistry, 46(23), 9516-8. https://doi.org/10.1021/ic701432s
Lemonnier, Jean-François, et al. "Changing the oxothiomolybdate ring from an anionic to a cationic receptor." Inorganic chemistry vol. 46,23 (2007): 9516-8. doi: https://doi.org/10.1021/ic701432s
Lemonnier JF, Floquet S, Marrot J, Kachmar A, Bénard M, Rohmer MM, Haouas M, Taulelle F, Henry M, Cadot E. Changing the oxothiomolybdate ring from an anionic to a cationic receptor. Inorg Chem. 2007 Nov 12;46(23):9516-8. doi: 10.1021/ic701432s. Epub 2007 Oct 12. PMID: 17929915.
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Cyclic Ti9 keggin trimers with tetrahedral (PO4) or octahedral (TiO6) capping groups.

Inorganic chemistry

Al-Kadamany GA, Hussain F, Mal SS, Dickman MH, Leclerc-Laronze N, Marrot J, Cadot E, Kortz U.
PMID: 18781734
Inorg Chem. 2008 Oct 06;47(19):8574-6. doi: 10.1021/ic801114n. Epub 2008 Sep 10.

We have synthesized the cyclic Ti 9 Keggin trimers [(alpha-Ti 3PW 9O 38) 3(PO 4)] (18-) ( 1) and [(alpha-Ti 3SiW 9O 37OH) 3(TiO 3(OH 2) 3)] (17-) ( 2), which are both composed of three (Ti 3XW 9O...

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Al-Kadamany GA, Hussain F, Mal SS, et al. Cyclic Ti9 keggin trimers with tetrahedral (PO4) or octahedral (TiO6) capping groups. Inorg Chem. 2008;47(19):8574-6doi: 10.1021/ic801114n.
Al-Kadamany, G. A., Hussain, F., Mal, S. S., Dickman, M. H., Leclerc-Laronze, N., Marrot, J., Cadot, E., & Kortz, U. (2008). Cyclic Ti9 keggin trimers with tetrahedral (PO4) or octahedral (TiO6) capping groups. Inorganic chemistry, 47(19), 8574-6. https://doi.org/10.1021/ic801114n
Al-Kadamany, Ghada A, et al. "Cyclic Ti9 keggin trimers with tetrahedral (PO4) or octahedral (TiO6) capping groups." Inorganic chemistry vol. 47,19 (2008): 8574-6. doi: https://doi.org/10.1021/ic801114n
Al-Kadamany GA, Hussain F, Mal SS, Dickman MH, Leclerc-Laronze N, Marrot J, Cadot E, Kortz U. Cyclic Ti9 keggin trimers with tetrahedral (PO4) or octahedral (TiO6) capping groups. Inorg Chem. 2008 Oct 06;47(19):8574-6. doi: 10.1021/ic801114n. Epub 2008 Sep 10. PMID: 18781734.
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4-(2-Tetrathiafulvalenyl-ethenyl)pyridine (TTF-CH=CH-Py) radical cation salts containing poly(beta-diketonate) rare earth complexes: synthesis, crystal structure, photoluminescent and magnetic properties.

Inorganic chemistry

Pointillart F, Maury O, Le Gal Y, Golhen S, Cador O, Ouahab L.
PMID: 19572728
Inorg Chem. 2009 Aug 03;48(15):7421-9. doi: 10.1021/ic901052b.

The reactions between the redox-active 4-(2-tetrathiafulvalenyl-ethenyl)pyridine ligand (TTF-CH=CH-Py) and the tris(1,1,1,5,5,5-hexafluoroacetylacetonate)Ln(III) (Ln = La and Nd) lead to the formation of compounds with the formulas {[La(hfac)(5)][(TTF-CH=CH-Py(*+))](2)} (1), {[Nd(hfac)(4)(H(2)O)][(TTF-CH=CH-Py(*+))]}(2) (2), and {[Nd(hfac)(4)(H(2)O)][(TTF-CH=CH-Py(*+))]}(2)(H(2)O)(C(6)H(14))(0.5) (3) (hfac(-) = 1,1,1,5,5,5-hexafluoroacetylacetonate anion). These compounds have...

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Pointillart F, Maury O, Le Gal Y, et al. 4-(2-Tetrathiafulvalenyl-ethenyl)pyridine (TTF-CH=CH-Py) radical cation salts containing poly(beta-diketonate) rare earth complexes: synthesis, crystal structure, photoluminescent and magnetic properties. Inorg Chem. 2009;48(15):7421-9doi: 10.1021/ic901052b.
Pointillart, F., Maury, O., Le Gal, Y., Golhen, S., Cador, O., & Ouahab, L. (2009). 4-(2-Tetrathiafulvalenyl-ethenyl)pyridine (TTF-CH=CH-Py) radical cation salts containing poly(beta-diketonate) rare earth complexes: synthesis, crystal structure, photoluminescent and magnetic properties. Inorganic chemistry, 48(15), 7421-9. https://doi.org/10.1021/ic901052b
Pointillart, Fabrice, et al. "4-(2-Tetrathiafulvalenyl-ethenyl)pyridine (TTF-CH=CH-Py) radical cation salts containing poly(beta-diketonate) rare earth complexes: synthesis, crystal structure, photoluminescent and magnetic properties." Inorganic chemistry vol. 48,15 (2009): 7421-9. doi: https://doi.org/10.1021/ic901052b
Pointillart F, Maury O, Le Gal Y, Golhen S, Cador O, Ouahab L. 4-(2-Tetrathiafulvalenyl-ethenyl)pyridine (TTF-CH=CH-Py) radical cation salts containing poly(beta-diketonate) rare earth complexes: synthesis, crystal structure, photoluminescent and magnetic properties. Inorg Chem. 2009 Aug 03;48(15):7421-9. doi: 10.1021/ic901052b. PMID: 19572728.
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Current composite-feature classification methods do not outperform simple single-genes classifiers in breast cancer prognosis.

Frontiers in genetics

Staiger C, Cadot S, Györffy B, Wessels LF, Klau GW.
PMID: 24391662
Front Genet. 2013 Dec 23;4:289. doi: 10.3389/fgene.2013.00289. eCollection 2013.

Integrating gene expression data with secondary data such as pathway or protein-protein interaction data has been proposed as a promising approach for improved outcome prediction of cancer patients. Methods employing this approach usually aggregate the expression of genes into...

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Staiger C, Cadot S, Györffy B, et al. Current composite-feature classification methods do not outperform simple single-genes classifiers in breast cancer prognosis. Front Genet. 2013;4:289doi: 10.3389/fgene.2013.00289.
Staiger, C., Cadot, S., Györffy, B., Wessels, L. F., & Klau, G. W. (2013). Current composite-feature classification methods do not outperform simple single-genes classifiers in breast cancer prognosis. Frontiers in genetics, 4289. https://doi.org/10.3389/fgene.2013.00289
Staiger, Christine, et al. "Current composite-feature classification methods do not outperform simple single-genes classifiers in breast cancer prognosis." Frontiers in genetics vol. 4 (2013): 289. doi: https://doi.org/10.3389/fgene.2013.00289
Staiger C, Cadot S, Györffy B, Wessels LF, Klau GW. Current composite-feature classification methods do not outperform simple single-genes classifiers in breast cancer prognosis. Front Genet. 2013 Dec 23;4:289. doi: 10.3389/fgene.2013.00289. eCollection 2013. PMID: 24391662; PMCID: PMC3870302.
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