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Showing 13 to 24 of 309 entries
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A sea-floor spreading event captured by seismometers.

Science (New York, N.Y.)

Tolstoy M, Cowen JP, Baker ET, Fornari DJ, Rubin KH, Shank TM, Waldhauser F, Bohnenstiehl DR, Forsyth DW, Holmes RC, Love B, Perfit MR, Weekly RT, Soule SA, Glazer B.
PMID: 17124289
Science. 2006 Dec 22;314(5807):1920-2. doi: 10.1126/science.1133950. Epub 2006 Nov 23.

Two-thirds of Earth's surface is formed at mid-ocean ridges, yet sea-floor spreading events are poorly understood because they occur far beneath the ocean surface. At 9 degrees 50'N on the East Pacific Rise, ocean-bottom seismometers recently recorded the microearthquake...

Reactions of lanthanoid metals with 3,5-diphenylpyrazole at elevated temperatures: synthesis and structures of both homoleptic, [Ln3(Ph2pz)9] (Ln = La, Nd), [Ln2(Ph2pz)6] (Ln = Er, Lu), and heteroleptic, [Ln(Ph2pz)3(Ph2pzH)2] (Ln = La, Nd, Gd, Tb, Er or Yb), pyrazolate complexes.

Dalton transactions (Cambridge, England : 2003)

Deacon GB, Forsyth CM, Gitlits A, Skelton BW, White AH.
PMID: 15252667
Dalton Trans. 2004 Apr 21;(8):1239-47. doi: 10.1039/b400541d. Epub 2004 Mar 15.

The direct reaction of lanthanoid metals with 3,5-diphenylpyrazole (Ph2pzH) at 300 degrees C under vacuum in the presence of mercury gives the structurally characterized [Ln3(Ph2pz)9] (Ln = La or Nd), [Ln2(Ph2pz)6] (Ln = Er or Lu). Similar reactions provided...

Ambient temperature plastic crystal electrolyte for efficient, all-solid-state dye-sensitized solar cell.

Journal of the American Chemical Society

Wang P, Dai Q, Zakeeruddin SM, Forsyth M, Macfarlane DR, Grätzel M.
PMID: 15493896
J Am Chem Soc. 2004 Oct 27;126(42):13590-1. doi: 10.1021/ja045013h.

Doping the molecular plastic crystal of succinonitrile with solid N-methyl-N-butylpyrrolidinium iodide salt and iodine has produced a highly conductive solid iodide/triiodide conductor. Furthermore, it was employed for a highly efficient, all-solid-state dye-sensitized solar cell.

Broadband dielectric response of the ionic liquid N-methyl-N-ethylpyrrolidinium dicyanamide.

Chemical communications (Cambridge, England)

Schrödle S, Annat G, MacFarlane DR, Forsyth M, Buchner R, Hefter G.
PMID: 16609792
Chem Commun (Camb). 2006 Apr 28;(16):1748-50. doi: 10.1039/b602209j. Epub 2006 Mar 14.

Dielectric relaxation measurements as a function of temperature, and of concentration in a non-coordinating solvent, the first reported for an ionic liquid, indicate a crossover in the relaxation mechanism due to varying levels of ion aggregation and the interplay...

Determination of butyltin, methyltin and tetraalkyltin in marine food products with gas chromatography-atomic absorption spectrometry.

Talanta

Forsyth DS, Cleroux C.
PMID: 18965243
Talanta. 1991 Sep;38(9):951-7. doi: 10.1016/0039-9140(91)80308-m.

Extraction methods were developed for the determination of butyltin, methyltin and tetraalkyltin in marine food products. Alkyltins were complexed with either diphenylthiocarbazone (dithizone) or tropolone from enzymatically hydrolysed samples. Tetraalkyltins were extracted with hexane. Butyl or methyl derivatives of...

LONGEVITY IN THE SOUTHERN STATES.

Science (New York, N.Y.)

Forsyth CH.
PMID: 17773483
Science. 1923 Apr 27;57(1478):490-3. doi: 10.1126/science.57.1478.490.

No abstract available.

Proton transport in choline dihydrogen phosphate/H(3)PO(4) mixtures.

Physical chemistry chemical physics : PCCP

Rana UA, Bayley PM, Vijayaraghavan R, Howlett P, Macfarlane DR, Forsyth M.
PMID: 20680198
Phys Chem Chem Phys. 2010 Oct 07;12(37):11291-8. doi: 10.1039/c0cp00156b. Epub 2010 Aug 02.

Mixtures of the plastic crystal material choline dihydrogen phosphate [Choline][DHP] and phosphoric acid, from 4.5 mol% to 18 mol% H(3)PO(4), were investigated and shown to have significantly higher proton conductivity compared to the pure [Choline][DHP]. This was particularly evident...

Experimental reproduction of the runting-stunting syndrome of broiler chickens.

Avian pathology : journal of the W.V.P.A

Smart IJ, Barr DA, Reece RL, Forsyth WM, Ewing I.
PMID: 18766720
Avian Pathol. 1988;17(3):617-27. doi: 10.1080/03079458808436481.

A model for the reproduction of the runting-stunting syndrome (RSS) of broiler chickens is described. In this model, groups of at least 90 day-old broiler chickens were inoculated (per os) with various tissue homogenates or virus preparations. During the...

Reduction of carbodiimides by samarium(II) bis(trimethylsilyl)amides-formation of oxalamidinates and amidinates through C-C coupling or C-H activation.

Inorganic chemistry

Deacon GB, Forsyth CM, Junk PC, Wang J.
PMID: 17929807
Inorg Chem. 2007 Nov 12;46(23):10022-30. doi: 10.1021/ic701497c. Epub 2007 Oct 11.

The reaction of [Sm{N(SiMe3)2}2(THF)2] (THF=tetrahydrofuran) with carbodiimides RN=C=NR (R=Cy, C6H3-2,6-iPr2) led to the formation of dinuclear SmIII complexes via differing C-C coupling processes. For R=Cy, the product [{(Me3Si)2N}2Sm(micro-C2N4Cy4)Sm{N(SiMe3)2}2] (1) has an oxalamidinate [C2N4Cy4]2- ligand resulting from coupling at the...

Direct electro-deposition of graphene from aqueous suspensions.

Physical chemistry chemical physics : PCCP

Hilder M, Winther-Jensen B, Li D, Forsyth M, MacFarlane DR.
PMID: 21479302
Phys Chem Chem Phys. 2011 May 28;13(20):9187-93. doi: 10.1039/c1cp20173e. Epub 2011 Apr 08.

We describe the direct electro-chemical reduction of graphene oxide to graphene from aqueous suspension by applying reduction voltages exceeding -1.0 to -1.2 V. The conductivity of the deposition medium is of crucial importance and only values between 4-25 mS...

New insights into the fundamental chemical nature of ionic liquid film formation on magnesium alloy surfaces.

ACS applied materials & interfaces

Forsyth M, Neil WC, Howlett PC, Macfarlane DR, Hinton BR, Rocher N, Kemp TF, Smith ME.
PMID: 20355890
ACS Appl Mater Interfaces. 2009 May;1(5):1045-52. doi: 10.1021/am900023j.

Ionic liquids (ILs) based on trihexyltetradecylphosphonium coupled with either diphenylphosphate or bis(trifluoromethanesulfonyl)amide have been shown to react with magnesium alloy surfaces, leading to the formation a surface film that can improve the corrosion resistance of the alloy. The morphology...

Synthesis, structures and spin crossover properties of infinite 3D frameworks of iron(II) containing organodinitrile bridging ligands.

Dalton transactions (Cambridge, England : 2003)

Chainok K, Neville SM, Moubaraki B, Batten SR, Murray KS, Forsyth CM, Cashion JD, Haller KJ.
PMID: 20721391
Dalton Trans. 2010 Dec 07;39(45):10900-9. doi: 10.1039/c0dt00447b. Epub 2010 Aug 19.

Four new Fe(II) coordination polymers of formulation [Fe(L)(3)][MCl(4)](2), M = Fe(III), In(III) have been synthesized and structurally and magnetically characterized. They contain organodinitrile bridging ligands where L is 1,1'-azobiscyclopentanecarbonitrile (ACCN) or 2,2'-azobisisobutyronitrile (AIBN). The compounds are [Fe(AIBN)(3)][InCl(4)](2) (1), [Fe(AIBN)(3)][FeCl(4)](2)...

Showing 13 to 24 of 309 entries