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Dihydrogen bonding in complex (PP3)RuH(η(1)-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies.

Inorganic chemistry

Belkova NV, Bakhmutova-Albert EV, Gutsul EI, Bakhmutov VI, Golub IE, Filippov OA, Epstein LM, Peruzzini M, Rossin A, Zanobini F, Shubina ES.
PMID: 24369730
Inorg Chem. 2014 Jan 21;53(2):1080-90. doi: 10.1021/ic4026206. Epub 2013 Dec 26.

Combining variable-temperature infrared and NMR spectroscopic studies with quantum-chemical calculations (density functional theory (DFT) and natural bond orbital) allowed us to address the problem of competition between MH (M = transition metal) and BH hydrogens as proton-accepting sites in...

A novel cadmium aminophosphonate: X-ray powder diffraction structure, solid-state IR and NMR spectroscopic determination of the fine structure of the organic moieties.

Inorganic chemistry

Bakhmutova-Albert EV, Bestaoui N, Bakhmutov VI, Clearfield A, Rodriguez AV, Llavona R.
PMID: 14966961
Inorg Chem. 2004 Feb 23;43(4):1264-72. doi: 10.1021/ic030320u.

A new divalent cadmium phosphonate, Cd2Cl2(H2O)4(H2L), has been synthesized from the ethylenediamine-N,N'-bis(methylenephosphonic acid) (H4L). The obtained microcrystalline compound has been characterized by solid-state IR spectra and 13C, 31P, and 113Cd CP MAS NMR. The static 13P NMR spectra have...

Showing 1 to 2 of 2 entries