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Showing 1 to 12 of 166 entries
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Pressure-Dependent Friction on Granular Slopes Close to Avalanche.

Physical review letters

Crassous J, Humeau A, Boury S, Casas J.
PMID: 28949714
Phys Rev Lett. 2017 Aug 04;119(5):058003. doi: 10.1103/PhysRevLett.119.058003. Epub 2017 Aug 03.

We investigate the sliding of objects on an inclined granular surface close to the avalanche threshold. Our experiments show that the stability is driven by the surface deformations. Heavy objects generate footprintlike deformations which stabilize the objects on the...

Two-Photon Absorption and Two-Photon Circular Dichroism of a Hexahelicene Derivative with a Terminal Donor-Phenyl-Acceptor Motif.

The journal of physical chemistry. A

Vesga Y, Diaz C, Crassous J, Hernandez FE.
PMID: 29543462
J Phys Chem A. 2018 Apr 05;122(13):3365-3373. doi: 10.1021/acs.jpca.8b00347. Epub 2018 Mar 23.

Herein, we report on the theoretical-experimental analysis of the two photon absorption and circular dichroism spectra of 1-(2-pyridyl)-4-methoxy-carbo[6]helicene derivative (P6). The primary outcomes of our investigation on this particular helicene derivative with a donor-acceptor motif on one end led...

Spatially resolved measurements of micro-deformations in granular materials using diffusing wave spectroscopy.

The Review of scientific instruments

Amon A, Mikhailovskaya A, Crassous J.
PMID: 28571455
Rev Sci Instrum. 2017 May;88(5):051804. doi: 10.1063/1.4983048.

This article is a tutorial on the practical implementation of a method of measurement of minute deformations based on multiple scattering. This technique has been recently developed and has proven to give new insights into the spatial repartition of...

Iron Alkynyl Helicenes: Redox-Triggered Chiroptical Tuning in the IR and Near-IR Spectral Regions and Suitable for Telecommunications Applications.

Angewandte Chemie (International ed. in English)

Shen C, Loas G, Srebro-Hooper M, Vanthuyne N, Toupet L, Cador O, Paul F, López Navarrete JT, Ramírez FJ, Nieto-Ortega B, Casado J, Autschbach J, Vallet M, Crassous J.
PMID: 27193483
Angew Chem Int Ed Engl. 2016 Jul 04;55(28):8062-6. doi: 10.1002/anie.201601633. Epub 2016 May 19.

The combination of a bis-alkynyl-helicene moiety with two iron centers leads to novel electroactive species displaying unprecedented redox-triggered chiroptical switching. Upon oxidation, strong changes of vibrational modes (either local or extended coupled modes) are detected by vibrational circular dichroism...

Diastereo- and enantioselective synthesis of organometallic bis(helicene)s by a combination of C-H activation and dynamic isomerization.

Chemistry (Weinheim an der Bergstrasse, Germany)

Shen C, Anger E, Srebro M, Vanthuyne N, Toupet L, Roussel C, Autschbach J, Réau R, Crassous J.
PMID: 24173674
Chemistry. 2013 Dec 02;19(49):16722-8. doi: 10.1002/chem.201302479. Epub 2013 Oct 31.

Homochiral and heterochiral cis-bis-cycloplatinated-[6]helicene derivatives 1b(1,2), as representative examples of platina[6]helicenes that share a common platinum center, have been prepared. A diastereo- and enantioselective synthesis, which combines CH activation and dynamic isomerization from heterochiral structure 1b(2) into homochiral structure...

Synthesis and Structural Properties of Aza[n]helicene Platinum Complexes: Control of Cis and Trans Stereochemistry.

Inorganic chemistry

Mendola D, Saleh N, Hellou N, Vanthuyne N, Roussel C, Toupet L, Castiglione F, Melone F, Caronna T, Fontana F, Martí-Rujas J, Parisini E, Malpezzi L, Mele A, Crassous J.
PMID: 26645835
Inorg Chem. 2016 Mar 07;55(5):2009-17. doi: 10.1021/acs.inorgchem.5b02276. Epub 2015 Dec 08.

The synthesis and structural characterization of azahelicene platinum complexes obtained from cis-PtCl2(NCEt)(PPh3) and from ligands that differ in terms of both the position of the nitrogen atom and the number of fused rings are reported. These square-planar complexes of...

Mechanical fluctuations suppress the threshold of soft-glassy solids: The secular drift scenario.

Physical review. E, Statistical, nonlinear, and soft matter physics

Pons A, Amon A, Darnige T, Crassous J, Clément E.
PMID: 26382329
Phys Rev E Stat Nonlin Soft Matter Phys. 2015 Aug;92(2):020201. doi: 10.1103/PhysRevE.92.020201. Epub 2015 Aug 20.

We propose a dynamical mechanism leading to the fluidization by external mechanical fluctuations of soft-glassy amorphous material driven below the yield stress. The model is based on the combination of memory effect and nonlinearity, leading to an accumulation of...

Enantioseparation on Riboflavin Derivatives Chemically Bonded to Silica Gel as Chiral Stationary Phases for HPLC.

Chirality

Kumano D, Iwahana S, Iida H, Shen C, Crassous J, Yashima E.
PMID: 25919938
Chirality. 2015 Aug;27(8):507-17. doi: 10.1002/chir.22452. Epub 2015 Apr 28.

Acetylated and/or 3,5-dimethylphenylcarbamated riboflavins were prepared and the resulting riboflavin derivatives as well as natural riboflavin were regioselectively immobilized on silica gel through chemical bonding at the 5'-O- or 3-N-position of the riboflavin to develop novel chiral stationary phases...

Search for resolution of chiral fluorohalogenomethanes and parity-violation effects at the molecular level.

Chemphyschem : a European journal of chemical physics and physical chemistry

Crassous J, Monier F, Dutasta JP, Ziskind M, Daussy C, Grain C, Chardonnet C.
PMID: 12836475
Chemphyschem. 2003 Jun 16;4(6):541-8. doi: 10.1002/cphc.200200536.

The first observation of a parity-violation effect in molecules induced by weak interactions is still a dream that requires the synthesis and, eventually, the resolution of the enantiomers of well-chosen simple chiral molecules together with an appropriate experimental set-up...

Chiral trialkanolamine-based hemicryptophanes: synthesis and oxovanadium complex.

Organic letters

Gautier A, Mulatier JC, Crassous J, Dutasta JP.
PMID: 15787468
Org Lett. 2005 Mar 31;7(7):1207-10. doi: 10.1021/ol047469+.

[reaction: see text] A novel class of chiral hemicryptophane hosts has been synthesized in diastereoisomerically pure form, namely, M-(R,R,R)-1a/P-(S,S,S)-1a and M-(S,S,S)-1b/P-(R,R,R)-1b. The C3-symmetrical precursor 9 was prepared, using either (R)- or (S)-glycidyl nosylate, repectively, as the chiral pool reactant...

Stereoselective coordination of ditopic phospholyl-azahelicenes: a novel approach towards structural diversity in chiral pi-conjugated assemblies.

Chemical communications (Cambridge, England)

Shen W, Graule S, Crassous J, Lescop C, Gornitzka H, Réau R.
PMID: 18253525
Chem Commun (Camb). 2008 Feb 21;(7):850-2. doi: 10.1039/b714340k. Epub 2007 Dec 18.

Phosphole-modified aza[4]helicenes act as heteroditopic chelates toward metal ions having different coordination geometries (Pd(II), Cu(I)).

Diffusive waves in a dilating scattering medium.

Physical review letters

Crassous J, Erpelding M, Amon A.
PMID: 19659149
Phys Rev Lett. 2009 Jul 03;103(1):013903. doi: 10.1103/PhysRevLett.103.013903. Epub 2009 Jul 02.

We consider the propagation of a diffusive wave in a scattering medium submitted to a homogeneous expansion. The light multiply scattered by a glass spheres sample is measured. We analyze the variations of the scattered light when the material...

Showing 1 to 12 of 166 entries