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Efficient Triplet Exciton Fusion in Molecularly Doped Polymer Light-Emitting Diodes.

Advanced materials (Deerfield Beach, Fla.)

Di D, Yang L, Richter JM, Meraldi L, Altamimi RM, Alyamani AY, Credgington D, Musselman KP, MacManus-Driscoll JL, Friend RH.
PMID: 28145598
Adv Mater. 2017 Apr;29(13). doi: 10.1002/adma.201605987. Epub 2017 Feb 01.

Solution-processed polymer organic light-emitting diodes (OLEDs) doped with triplet-triplet annihilation (TTA)-upconversion molecules, including 9,10-diphenylanthracene, perylene, rubrene and TIPS-pentacene, are reported. The fraction of triplet-generated electroluminescence approaches the theoretical limit. Record-high efficiencies in solution-processed OLEDs based on these materials are...

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Di D, Yang L, Richter JM, et al. Efficient Triplet Exciton Fusion in Molecularly Doped Polymer Light-Emitting Diodes. Adv Mater. 2017;29(13)doi: 10.1002/adma.201605987.
Di, D., Yang, L., Richter, J. M., Meraldi, L., Altamimi, R. M., Alyamani, A. Y., Credgington, D., Musselman, K. P., MacManus-Driscoll, J. L., & Friend, R. H. (2017). Efficient Triplet Exciton Fusion in Molecularly Doped Polymer Light-Emitting Diodes. Advanced materials (Deerfield Beach, Fla.), 29(13), . https://doi.org/10.1002/adma.201605987
Di, Dawei, et al. "Efficient Triplet Exciton Fusion in Molecularly Doped Polymer Light-Emitting Diodes." Advanced materials (Deerfield Beach, Fla.) vol. 29,13 (2017). doi: https://doi.org/10.1002/adma.201605987
Di D, Yang L, Richter JM, Meraldi L, Altamimi RM, Alyamani AY, Credgington D, Musselman KP, MacManus-Driscoll JL, Friend RH. Efficient Triplet Exciton Fusion in Molecularly Doped Polymer Light-Emitting Diodes. Adv Mater. 2017 Apr;29(13). doi: 10.1002/adma.201605987. Epub 2017 Feb 01. PMID: 28145598.
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Competition between the heavy atom effect and vibronic coupling in donor-bridge-acceptor organometallics.

Physical chemistry chemical physics : PCCP

Eng J, Thompson S, Goodwin H, Credgington D, Penfold TJ.
PMID: 32055809
Phys Chem Chem Phys. 2020 Feb 26;22(8):4659-4667. doi: 10.1039/c9cp06999b.

The excited state properties and intersystem crossing dynamics of a series of donor-bridge-acceptor carbene metal-amides based upon the coinage metals Cu, Ag, Au, are investigated using quantum dynamics simulations and supported by photophysical characterisation. The simulated intersystem rates are...

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Eng J, Thompson S, Goodwin H, et al. Competition between the heavy atom effect and vibronic coupling in donor-bridge-acceptor organometallics. Phys Chem Chem Phys. 2020;22(8):4659-4667doi: 10.1039/c9cp06999b.
Eng, J., Thompson, S., Goodwin, H., Credgington, D., & Penfold, T. J. (2020). Competition between the heavy atom effect and vibronic coupling in donor-bridge-acceptor organometallics. Physical chemistry chemical physics : PCCP, 22(8), 4659-4667. https://doi.org/10.1039/c9cp06999b
Eng, Julien, et al. "Competition between the heavy atom effect and vibronic coupling in donor-bridge-acceptor organometallics." Physical chemistry chemical physics : PCCP vol. 22,8 (2020): 4659-4667. doi: https://doi.org/10.1039/c9cp06999b
Eng J, Thompson S, Goodwin H, Credgington D, Penfold TJ. Competition between the heavy atom effect and vibronic coupling in donor-bridge-acceptor organometallics. Phys Chem Chem Phys. 2020 Feb 26;22(8):4659-4667. doi: 10.1039/c9cp06999b. PMID: 32055809.
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Correction: Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence.

Chemical communications (Cambridge, England)

Romanov AS, Di D, Yang L, Fernandez-Cestau J, Becker CR, James CE, Zhu B, Linnolahti M, Credgington D, Bochmann M.
PMID: 29589616
Chem Commun (Camb). 2018 Apr 05;54(29):3672. doi: 10.1039/c8cc90135j.

Correction for 'Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence' by Alexander S. Romanov et al., Chem. Commun., 2016, 52, 6379-6382.

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Romanov AS, Di D, Yang L, et al. Correction: Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence. Chem Commun (Camb). 2018;54(29):3672doi: 10.1039/c8cc90135j.
Romanov, A. S., Di, D., Yang, L., Fernandez-Cestau, J., Becker, C. R., James, C. E., Zhu, B., Linnolahti, M., Credgington, D., & Bochmann, M. (2018). Correction: Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence. Chemical communications (Cambridge, England), 54(29), 3672. https://doi.org/10.1039/c8cc90135j
Romanov, Alexander S, et al. "Correction: Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence." Chemical communications (Cambridge, England) vol. 54,29 (2018): 3672. doi: https://doi.org/10.1039/c8cc90135j
Romanov AS, Di D, Yang L, Fernandez-Cestau J, Becker CR, James CE, Zhu B, Linnolahti M, Credgington D, Bochmann M. Correction: Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence. Chem Commun (Camb). 2018 Apr 05;54(29):3672. doi: 10.1039/c8cc90135j. PMID: 29589616.
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Mapping epilepsy-specific patient-reported outcome measures for children to a proposed core outcome set for childhood epilepsy.

Epilepsy & behavior : E&B

Crudgington H, Collingwood A, Bray L, Lyle S, Martin R, Gringras P, Pal DK, Morris C.
PMID: 32906016
Epilepsy Behav. 2020 Nov;112:107372. doi: 10.1016/j.yebeh.2020.107372. Epub 2020 Sep 06.

OBJECTIVE: The objectives of the study were to (1) map questions in epilepsy-specific patient-reported outcome measures (PROMs) of children's health-related quality of life (HRQoL) to a proposed core outcome set (COS) for childhood epilepsy research and (2) gain insight...

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Crudgington H, Collingwood A, Bray L, et al. Mapping epilepsy-specific patient-reported outcome measures for children to a proposed core outcome set for childhood epilepsy. Epilepsy Behav. 2020;112:107372doi: 10.1016/j.yebeh.2020.107372.
Crudgington, H., Collingwood, A., Bray, L., Lyle, S., Martin, R., Gringras, P., Pal, D. K., & Morris, C. (2020). Mapping epilepsy-specific patient-reported outcome measures for children to a proposed core outcome set for childhood epilepsy. Epilepsy & behavior : E&B, 112107372. https://doi.org/10.1016/j.yebeh.2020.107372
Crudgington, Holly, et al. "Mapping epilepsy-specific patient-reported outcome measures for children to a proposed core outcome set for childhood epilepsy." Epilepsy & behavior : E&B vol. 112 (2020): 107372. doi: https://doi.org/10.1016/j.yebeh.2020.107372
Crudgington H, Collingwood A, Bray L, Lyle S, Martin R, Gringras P, Pal DK, Morris C. Mapping epilepsy-specific patient-reported outcome measures for children to a proposed core outcome set for childhood epilepsy. Epilepsy Behav. 2020 Nov;112:107372. doi: 10.1016/j.yebeh.2020.107372. Epub 2020 Sep 06. PMID: 32906016; PMCID: PMC7689576.
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Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED.

Chemical science

Romanov AS, Jones STE, Gu Q, Conaghan PJ, Drummond BH, Feng J, Chotard F, Buizza L, Foley M, Linnolahti M, Credgington D, Bochmann M.
PMID: 32190264
Chem Sci. 2019 Nov 13;11(2):435-446. doi: 10.1039/c9sc04589a. eCollection 2020 Jan 14.

Conformationally flexible "Carbene-Metal-Amide" (CMA) complexes of copper and gold have been developed based on a combination of sterically hindered cyclic (alkyl)(amino)carbene (CAAC) and 6- and 7-ring heterocyclic amide ligands. These complexes show photoemissions across the visible spectrum with PL...

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Romanov AS, Jones STE, Gu Q, et al. Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED. Chem Sci. 2019;11(2):435-446doi: 10.1039/c9sc04589a.
Romanov, A. S., Jones, S. T. E., Gu, Q., Conaghan, P. J., Drummond, B. H., Feng, J., Chotard, F., Buizza, L., Foley, M., Linnolahti, M., Credgington, D., & Bochmann, M. (2020). Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED. Chemical science, 11(2), 435-446. https://doi.org/10.1039/c9sc04589a
Romanov, Alexander S, et al. "Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED." Chemical science vol. 11,2 (2020): 435-446. doi: https://doi.org/10.1039/c9sc04589a
Romanov AS, Jones STE, Gu Q, Conaghan PJ, Drummond BH, Feng J, Chotard F, Buizza L, Foley M, Linnolahti M, Credgington D, Bochmann M. Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED. Chem Sci. 2019 Nov 13;11(2):435-446. doi: 10.1039/c9sc04589a. eCollection 2020 Jan 14. PMID: 32190264; PMCID: PMC7067249.
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Efficient and Stable Deep-Blue Fluorescent Organic Light-Emitting Diodes Employing a Sensitizer with Fast Triplet Upconversion.

Advanced materials (Deerfield Beach, Fla.)

Zhang D, Song X, Gillett AJ, Drummond BH, Jones STE, Li G, He H, Cai M, Credgington D, Duan L.
PMID: 32249984
Adv Mater. 2020 May;32(19):e1908355. doi: 10.1002/adma.201908355. Epub 2020 Apr 06.

Multiple donor-acceptor-type carbazole-benzonitrile derivatives that exhibit thermally activated delayed fluorescence (TADF) are the state of the art in efficiency and stability in sky-blue organic light-emitting diodes. However, such a motif still suffers from low reverse intersystem crossing rates (k

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Zhang D, Song X, Gillett AJ, et al. Efficient and Stable Deep-Blue Fluorescent Organic Light-Emitting Diodes Employing a Sensitizer with Fast Triplet Upconversion. Adv Mater. 2020;32(19):e1908355doi: 10.1002/adma.201908355.
Zhang, D., Song, X., Gillett, A. J., Drummond, B. H., Jones, S. T. E., Li, G., He, H., Cai, M., Credgington, D., & Duan, L. (2020). Efficient and Stable Deep-Blue Fluorescent Organic Light-Emitting Diodes Employing a Sensitizer with Fast Triplet Upconversion. Advanced materials (Deerfield Beach, Fla.), 32(19), e1908355. https://doi.org/10.1002/adma.201908355
Zhang, Dongdong, et al. "Efficient and Stable Deep-Blue Fluorescent Organic Light-Emitting Diodes Employing a Sensitizer with Fast Triplet Upconversion." Advanced materials (Deerfield Beach, Fla.) vol. 32,19 (2020): e1908355. doi: https://doi.org/10.1002/adma.201908355
Zhang D, Song X, Gillett AJ, Drummond BH, Jones STE, Li G, He H, Cai M, Credgington D, Duan L. Efficient and Stable Deep-Blue Fluorescent Organic Light-Emitting Diodes Employing a Sensitizer with Fast Triplet Upconversion. Adv Mater. 2020 May;32(19):e1908355. doi: 10.1002/adma.201908355. Epub 2020 Apr 06. PMID: 32249984.
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Ultrafast perturbation maps as a quantitative tool for testing of multi-port photonic devices.

Nature communications

Vynck K, Dinsdale NJ, Chen B, Bruck R, Khokhar AZ, Reynolds SA, Crudgington L, Thomson DJ, Reed GT, Lalanne P, Muskens OL.
PMID: 29884878
Nat Commun. 2018 Jun 08;9(1):2246. doi: 10.1038/s41467-018-04662-2.

Advanced photonic probing techniques are of great importance for the development of non-contact wafer-scale testing of photonic chips. Ultrafast photomodulation has been identified as a powerful new tool capable of remotely mapping photonic devices through a scanning perturbation. Here,...

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Vynck K, Dinsdale NJ, Chen B, et al. Ultrafast perturbation maps as a quantitative tool for testing of multi-port photonic devices. Nat Commun. 2018;9(1):2246doi: 10.1038/s41467-018-04662-2.
Vynck, K., Dinsdale, N. J., Chen, B., Bruck, R., Khokhar, A. Z., Reynolds, S. A., Crudgington, L., Thomson, D. J., Reed, G. T., Lalanne, P., & Muskens, O. L. (2018). Ultrafast perturbation maps as a quantitative tool for testing of multi-port photonic devices. Nature communications, 9(1), 2246. https://doi.org/10.1038/s41467-018-04662-2
Vynck, Kevin, et al. "Ultrafast perturbation maps as a quantitative tool for testing of multi-port photonic devices." Nature communications vol. 9,1 (2018): 2246. doi: https://doi.org/10.1038/s41467-018-04662-2
Vynck K, Dinsdale NJ, Chen B, Bruck R, Khokhar AZ, Reynolds SA, Crudgington L, Thomson DJ, Reed GT, Lalanne P, Muskens OL. Ultrafast perturbation maps as a quantitative tool for testing of multi-port photonic devices. Nat Commun. 2018 Jun 08;9(1):2246. doi: 10.1038/s41467-018-04662-2. PMID: 29884878; PMCID: PMC5993788.
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Solution-processed perovskite light emitting diodes with efficiency exceeding 15% through additive-controlled nanostructure tailoring.

Nature communications

Ban M, Zou Y, Rivett JPH, Yang Y, Thomas TH, Tan Y, Song T, Gao X, Credgington D, Deschler F, Sirringhaus H, Sun B.
PMID: 30250032
Nat Commun. 2018 Sep 24;9(1):3892. doi: 10.1038/s41467-018-06425-5.

Organometal halide perovskites (OHP) are promising materials for low-cost, high-efficiency light-emitting diodes. In films with a distribution of two-dimensional OHP nanosheets and small three-dimensional nanocrystals, an energy funnel can be realized that concentrates the excitations in highly efficient radiative...

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Ban M, Zou Y, Rivett JPH, et al. Solution-processed perovskite light emitting diodes with efficiency exceeding 15% through additive-controlled nanostructure tailoring. Nat Commun. 2018;9(1):3892doi: 10.1038/s41467-018-06425-5.
Ban, M., Zou, Y., Rivett, J. P. H., Yang, Y., Thomas, T. H., Tan, Y., Song, T., Gao, X., Credgington, D., Deschler, F., Sirringhaus, H., & Sun, B. (2018). Solution-processed perovskite light emitting diodes with efficiency exceeding 15% through additive-controlled nanostructure tailoring. Nature communications, 9(1), 3892. https://doi.org/10.1038/s41467-018-06425-5
Ban, Muyang, et al. "Solution-processed perovskite light emitting diodes with efficiency exceeding 15% through additive-controlled nanostructure tailoring." Nature communications vol. 9,1 (2018): 3892. doi: https://doi.org/10.1038/s41467-018-06425-5
Ban M, Zou Y, Rivett JPH, Yang Y, Thomas TH, Tan Y, Song T, Gao X, Credgington D, Deschler F, Sirringhaus H, Sun B. Solution-processed perovskite light emitting diodes with efficiency exceeding 15% through additive-controlled nanostructure tailoring. Nat Commun. 2018 Sep 24;9(1):3892. doi: 10.1038/s41467-018-06425-5. PMID: 30250032; PMCID: PMC6155305.
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Insights from Transient Optoelectronic Analyses on the Open-Circuit Voltage of Organic Solar Cells.

The journal of physical chemistry letters

Credgington D, Durrant JR.
PMID: 26285623
J Phys Chem Lett. 2012 Jun 07;3(11):1465-78. doi: 10.1021/jz300293q. Epub 2012 May 16.

In this Perspective, we review recent progress on the use of transient optoelectronic techniques to quantify the processes determining the open-circuit voltage (VOC) of organic solar cells. Most theoretical treatments of VOC include the effects of both material energetics...

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Credgington D, Durrant JR. Insights from Transient Optoelectronic Analyses on the Open-Circuit Voltage of Organic Solar Cells. J Phys Chem Lett. 2012;3(11):1465-78doi: 10.1021/jz300293q.
Credgington, D., & Durrant, J. R. (2012). Insights from Transient Optoelectronic Analyses on the Open-Circuit Voltage of Organic Solar Cells. The journal of physical chemistry letters, 3(11), 1465-78. https://doi.org/10.1021/jz300293q
Credgington, Dan, and Durrant, James R. "Insights from Transient Optoelectronic Analyses on the Open-Circuit Voltage of Organic Solar Cells." The journal of physical chemistry letters vol. 3,11 (2012): 1465-78. doi: https://doi.org/10.1021/jz300293q
Credgington D, Durrant JR. Insights from Transient Optoelectronic Analyses on the Open-Circuit Voltage of Organic Solar Cells. J Phys Chem Lett. 2012 Jun 07;3(11):1465-78. doi: 10.1021/jz300293q. Epub 2012 May 16. PMID: 26285623.
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Short hydrogen bonds enhance nonaromatic protein-related fluorescence.

Proceedings of the National Academy of Sciences of the United States of America

Stephens AD, Qaisrani MN, Ruggiero MT, Díaz Mirón G, Morzan UN, González Lebrero MC, Jones STE, Poli E, Bond AD, Woodhams PJ, Kleist EM, Grisanti L, Gebauer R, Zeitler JA, Credgington D, Hassanali A, Kaminski Schierle GS.
PMID: 34001606
Proc Natl Acad Sci U S A. 2021 May 25;118(21). doi: 10.1073/pnas.2020389118.

Fluorescence in biological systems is usually associated with the presence of aromatic groups. Here, by employing a combined experimental and computational approach, we show that specific hydrogen bond networks can significantly affect fluorescence. In particular, we reveal that the...

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Stephens AD, Qaisrani MN, Ruggiero MT, et al. Short hydrogen bonds enhance nonaromatic protein-related fluorescence. Proc Natl Acad Sci U S A. 2021;118(21)doi: 10.1073/pnas.2020389118.
Stephens, A. D., Qaisrani, M. N., Ruggiero, M. T., Díaz Mirón, G., Morzan, U. N., González Lebrero, M. C., Jones, S. T. E., Poli, E., Bond, A. D., Woodhams, P. J., Kleist, E. M., Grisanti, L., Gebauer, R., Zeitler, J. A., Credgington, D., Hassanali, A., & Kaminski Schierle, G. S. (2021). Short hydrogen bonds enhance nonaromatic protein-related fluorescence. Proceedings of the National Academy of Sciences of the United States of America, 118(21), . https://doi.org/10.1073/pnas.2020389118
Stephens, Amberley D, et al. "Short hydrogen bonds enhance nonaromatic protein-related fluorescence." Proceedings of the National Academy of Sciences of the United States of America vol. 118,21 (2021). doi: https://doi.org/10.1073/pnas.2020389118
Stephens AD, Qaisrani MN, Ruggiero MT, Díaz Mirón G, Morzan UN, González Lebrero MC, Jones STE, Poli E, Bond AD, Woodhams PJ, Kleist EM, Grisanti L, Gebauer R, Zeitler JA, Credgington D, Hassanali A, Kaminski Schierle GS. Short hydrogen bonds enhance nonaromatic protein-related fluorescence. Proc Natl Acad Sci U S A. 2021 May 25;118(21). doi: 10.1073/pnas.2020389118. PMID: 34001606; PMCID: PMC8166056.
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Electron spin resonance resolves intermediate triplet states in delayed fluorescence.

Nature communications

Drummond BH, Aizawa N, Zhang Y, Myers WK, Xiong Y, Cooper MW, Barlow S, Gu Q, Weiss LR, Gillett AJ, Credgington D, Pu YJ, Marder SR, Evans EW.
PMID: 34312394
Nat Commun. 2021 Jul 26;12(1):4532. doi: 10.1038/s41467-021-24612-9.

Molecular organic fluorophores are currently used in organic light-emitting diodes, though non-emissive triplet excitons generated in devices incorporating conventional fluorophores limit the efficiency. This limit can be overcome in materials that have intramolecular charge-transfer excitonic states and associated small...

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Drummond BH, Aizawa N, Zhang Y, et al. Electron spin resonance resolves intermediate triplet states in delayed fluorescence. Nat Commun. 2021;12(1):4532doi: 10.1038/s41467-021-24612-9.
Drummond, B. H., Aizawa, N., Zhang, Y., Myers, W. K., Xiong, Y., Cooper, M. W., Barlow, S., Gu, Q., Weiss, L. R., Gillett, A. J., Credgington, D., Pu, Y. J., Marder, S. R., & Evans, E. W. (2021). Electron spin resonance resolves intermediate triplet states in delayed fluorescence. Nature communications, 12(1), 4532. https://doi.org/10.1038/s41467-021-24612-9
Drummond, Bluebell H, et al. "Electron spin resonance resolves intermediate triplet states in delayed fluorescence." Nature communications vol. 12,1 (2021): 4532. doi: https://doi.org/10.1038/s41467-021-24612-9
Drummond BH, Aizawa N, Zhang Y, Myers WK, Xiong Y, Cooper MW, Barlow S, Gu Q, Weiss LR, Gillett AJ, Credgington D, Pu YJ, Marder SR, Evans EW. Electron spin resonance resolves intermediate triplet states in delayed fluorescence. Nat Commun. 2021 Jul 26;12(1):4532. doi: 10.1038/s41467-021-24612-9. PMID: 34312394; PMCID: PMC8313702.
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Kinetic equation of linear fractional stable motion and applications to modeling the scaling of intermittent bursts.

Physical review. E, Statistical, nonlinear, and soft matter physics

Watkins NW, Credgington D, Sanchez R, Rosenberg SJ, Chapman SC.
PMID: 19518190
Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Apr;79(4):041124. doi: 10.1103/PhysRevE.79.041124. Epub 2009 Apr 16.

Lévy flights and fractional Brownian motion have become exemplars of the heavy-tailed jumps and long-ranged memory widely seen in physics. Natural time series frequently combine both effects, and linear fractional stable motion (lfsm) is a model process of this...

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Watkins NW, Credgington D, Sanchez R, et al. Kinetic equation of linear fractional stable motion and applications to modeling the scaling of intermittent bursts. Phys Rev E Stat Nonlin Soft Matter Phys. 2009;79(4):041124doi: 10.1103/PhysRevE.79.041124.
Watkins, N. W., Credgington, D., Sanchez, R., Rosenberg, S. J., & Chapman, S. C. (2009). Kinetic equation of linear fractional stable motion and applications to modeling the scaling of intermittent bursts. Physical review. E, Statistical, nonlinear, and soft matter physics, 79(4), 041124. https://doi.org/10.1103/PhysRevE.79.041124
Watkins, N W, et al. "Kinetic equation of linear fractional stable motion and applications to modeling the scaling of intermittent bursts." Physical review. E, Statistical, nonlinear, and soft matter physics vol. 79,4 (2009): 041124. doi: https://doi.org/10.1103/PhysRevE.79.041124
Watkins NW, Credgington D, Sanchez R, Rosenberg SJ, Chapman SC. Kinetic equation of linear fractional stable motion and applications to modeling the scaling of intermittent bursts. Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Apr;79(4):041124. doi: 10.1103/PhysRevE.79.041124. Epub 2009 Apr 16. PMID: 19518190.
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