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Showing 1 to 6 of 6 entries
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Thermochromic Uranyl Isothiocyanates: Influencing Charge Transfer Bands with Supramolecular Structure.

Inorganic chemistry

Surbella RG, Ducati LC, Autschbach J, Deifel NP, Cahill CL.
PMID: 29436836
Inorg Chem. 2018 Mar 05;57(5):2455-2471. doi: 10.1021/acs.inorgchem.7b02702. Epub 2018 Feb 13.

The synthesis and structural characterization of seven new [UO

Differential expression of kunitz and bowman-birk soybean proteinase inhibitors in plant and callus tissue.

Plant physiology

Tan-Wilson AL, Hartl PM, Delfel NE, Wilson KA.
PMID: 16664236
Plant Physiol. 1985 Jun;78(2):310-4. doi: 10.1104/pp.78.2.310.

Bowman-Birk soybean trypsin inhibitor (BBSTI) but not Kunitz soybean trypsin inhibitor (KSTI) was found in samples of undifferentiated and partially differentiated Amsoy 71 tissue culture callus. This suggests the differential metabolism of these two classes of proteinase inhibitors, whether...

PF6(-) hydrolysis as a route to unique uranium phosphate materials.

Chemical communications (Cambridge, England)

Deifel NP, Holman KT, Cahill CL.
PMID: 19030578
Chem Commun (Camb). 2008 Dec 07;(45):6037-8. doi: 10.1039/b813819b. Epub 2008 Oct 23.

An uranium phosphate fluoride with a unique pentameric secondary building unit is prepared under hydrothermal conditions with UO2(NO3)2 x 6H(2)O, PF6(-) and 4,4'-bipyridine; the single-crystal structure is determined.

Combining coordination and supramolecular chemistry for the formation of uranyl-organic hybrid materials.

Chemical communications (Cambridge, England)

Deifel NP, Cahill CL.
PMID: 21487584
Chem Commun (Camb). 2011 Jun 07;47(21):6114-6. doi: 10.1039/c1cc11116g. Epub 2011 Apr 12.

Three hybrid compounds have been synthesized through hydrothermal reactions of UO(2)(NO(3))(2)·6H(2)O with 4-halobenzoic acid (X = Cl, Br, I). The formation of these compounds utilizes a composite synthesis methodology that explicitly employs aspects of both coordination chemistry and supramolecular...

1-Methyl-4H-3,1-benzoxazine-2,4(1H)dione.

Acta crystallographica. Section E, Structure reports online

Deifel NP, Cherney E, Hunt DA, Chan BC.
PMID: 21580413
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 20;66:o665. doi: 10.1107/S1600536810006094.

In its crystal structure, the title compound, C(9)H(7)NO(3), forms π-stacked dimers, with a centroid-centroid distance of 3.475 (5) Å between the benzenoid and the 2,4 dicarbonyl oxazine rings. These dimers then form staircase-like linear chains through further π-stacking between...

Charge transfer vibronic transitions in uranyl tetrachloride compounds.

The journal of physical chemistry. A

Liu G, Deifel NP, Cahill CL, Zhurov VV, Pinkerton AA.
PMID: 22148434
J Phys Chem A. 2012 Jan 19;116(2):855-64. doi: 10.1021/jp210046j. Epub 2012 Jan 09.

The electronic and vibronic interactions of uranyl (UO(2))(2+) in three tetrachloride crystals have been investigated with spectroscopic experiments and theoretical modeling. Analysis and simulation of the absorption and photoluminescence spectra have resulted in a quantitative understanding of the charge...

Showing 1 to 6 of 6 entries