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Showing 1 to 12 of 63 entries
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Photoisomerization pathways and Raman activity of 1,1'-difluorostilbene.

The Journal of chemical physics

Dobryakov AL, Quick M, Richter C, Knie C, Ioffe IN, Granovsky AA, Mahrwald R, Ernsting NP, Kovalenko SA.
PMID: 28147515
J Chem Phys. 2017 Jan 28;146(4):044501. doi: 10.1063/1.4974357.

The photoisomerization of 1,1'-difluorostilbene, following S

Photoisomerization dynamics and pathways of trans- and cis-azobenzene in solution from broadband femtosecond spectroscopies and calculations.

The journal of physical chemistry. B

Quick M, Dobryakov AL, Gerecke M, Richter C, Berndt F, Ioffe IN, Granovsky AA, Mahrwald R, Ernsting NP, Kovalenko SA.
PMID: 24983924
J Phys Chem B. 2014 Jul 24;118(29):8756-71. doi: 10.1021/jp504999f. Epub 2014 Jul 11.

The photoisomerization of azobenzene in solution was studied experimentally and by calculations. trans-to-cis and cis-to-trans dynamics are described through broadband transient absorption, fluorescence, and stimulated Raman spectroscopy. Transient absorption was extended to cover not only the nπ* band but...

Silicon single-crystal cryogenic optical resonator.

Optics letters

Wiens E, Chen QF, Ernsting I, Luckmann H, Rosowski U, Nevsky A, Schiller S.
PMID: 24876023
Opt Lett. 2014 Jun 01;39(11):3242-5. doi: 10.1364/OL.39.003242.

We report on the demonstration and characterization of a silicon optical resonator for laser frequency stabilization, operating in the deep cryogenic regime at temperatures as low as 1.5 K. Robust operation was achieved, with absolute frequency drift less than...

Perpendicular State of an Electronically Excited Stilbene: Observation by Femtosecond-Stimulated Raman Spectroscopy.

The journal of physical chemistry letters

Quick M, Dobryakov AL, Ioffe IN, Granovsky AA, Kovalenko SA, Ernsting NP.
PMID: 27685655
J Phys Chem Lett. 2016 Oct 20;7(20):4047-4052. doi: 10.1021/acs.jpclett.6b01923. Epub 2016 Sep 30.

In the photoisomerization path of stilbene, a perpendicular state P on the S

Conductivity and Solvation Dynamics in Ionic Liquids.

The journal of physical chemistry letters

Zhang XX, Liang M, Ernsting NP, Maroncelli M.
PMID: 26282043
J Phys Chem Lett. 2013 Apr 04;4(7):1205-10. doi: 10.1021/jz400359r. Epub 2013 Mar 26.

It was shown recently that a simple dielectric continuum model predicts the integral solvation time of a dipolar solute ⟨τsolv⟩ to be inversely proportional to the electrical conductivity σ0 of an ionic solvent or solution. In this Letter, we...

The invasion of the carnivorous carabid beetle Trechisibus antarcticus on South Georgia (sub-Antarctic) and its effect on the endemic herbivorous beetle Hydromedion spasutum.

Oecologia

Ernsting G, Block W, MacAlister H, Todd C.
PMID: 28306942
Oecologia. 1995 Jul;103(1):34-42. doi: 10.1007/BF00328422.

Recently two species of carabid beetle were accidentally introduced onto the sub-Antarctic island of South Georgia. Both species are carnivorous and flightless. One of the species, Trechisibus antarcticus, is locally very abundant and in the process of invading the...

Excited-state Raman spectroscopy with and without actinic excitation: S1 Raman spectra of trans-azobenzene.

The Journal of chemical physics

Dobryakov AL, Quick M, Ioffe IN, Granovsky AA, Ernsting NP, Kovalenko SA.
PMID: 24832273
J Chem Phys. 2014 May 14;140(18):184310. doi: 10.1063/1.4874854.

We show that femtosecond stimulated Raman spectroscopy can record excited-state spectra in the absence of actinic excitation, if the Raman pump is in resonance with an electronic transition. The approach is illustrated by recording S1 and S0 spectra of...

A preoperative smoking intervention decreased postoperative complications in elective knee or hip replacement.

Evidence-based nursing

Murray EW.
PMID: 12123268
Evid Based Nurs. 2002 Jul;5(3):84. doi: 10.1136/ebn.5.3.84.

No abstract available.

Ultrafast intramolecular charge transfer and internal conversion with tetrafluoro-aminobenzonitriles.

Chemphyschem : a European journal of chemical physics and physical chemistry

Galievsky VA, Druzhinin SI, Demeter A, Jiang YB, Kovalenko SA, Pérez Lustres L, Venugopal K, Ernsting NP, Allonas X, Noltemeyer M, Machinek R, Zachariasse KA.
PMID: 16273565
Chemphyschem. 2005 Nov 11;6(11):2307-23. doi: 10.1002/cphc.200500267.

The five 2,3,5,6-tetrafluoro-4-aminobenzonitriles XABN4F with a dimethyl-amino (DMABN4F), diethyl-amino (DEABN4F), azetidinyl (AZABN4F), methyl-amino (MABN4F) or amino (ABN4F) group undergo ultrafast intramolecular charge transfer (ICT) at room temperature, in the polar solvent acetonitrile (MeCN) as well as in the nonpolar...

2-Amino-7-nitro-fluorenes in neat and mixed solvents-optical band shapes and solvatochromism.

The journal of physical chemistry. A

Karunakaran V, Senyushkina T, Saroja G, Liebscher J, Ernsting NP.
PMID: 17929778
J Phys Chem A. 2007 Nov 01;111(43):10944-52. doi: 10.1021/jp073844e. Epub 2007 Oct 11.

Femtosecond transient absorption spectroscopy of amino-nitro-fluorenes in the UV-visible range shows that the dynamic Stokes shift of the emission band is sensitive to infrared-active modes of the solvent. Bandshapes for stationary absorption and emission are needed to quantify the...

Low-noise, tunable diode laser for ultra-high-resolution spectroscopy.

Optics letters

Döringshoff K, Ernsting I, Rinkleff RH, Schiller S, Wicht A.
PMID: 17909603
Opt Lett. 2007 Oct 01;32(19):2876-8. doi: 10.1364/ol.32.002876.

We demonstrate the excellent spectral properties of a diode laser setup that combines good tunability with superb short-term frequency stability and controllability. It is based on merging two concepts, the diode laser with resonant optical feedback and the grating...

An efficient setup for femtosecond stimulated Raman spectroscopy.

The Review of scientific instruments

Kovalenko SA, Dobryakov AL, Ernsting NP.
PMID: 21721669
Rev Sci Instrum. 2011 Jun;82(6):063102. doi: 10.1063/1.3596453.

We present an efficient and robust setup for femtosecond stimulated Raman (FSR) spectroscopy with 60 fs and 10 cm(-1) resolution. Raman pulses of 0.5-5 ps are tunable between 450-750 nm with energies 1-10 μJ. Experimental features of the setup,...

Showing 1 to 12 of 63 entries