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Ammonia Borane Dehydrogenation Catalyzed by (κ.

Inorganic chemistry

Todisco S, Luconi L, Giambastiani G, Rossin A, Peruzzini M, Golub IE, Filippov OA, Belkova NV, Shubina ES.
PMID: 28345899
Inorg Chem. 2017 Apr 17;56(8):4296-4307. doi: 10.1021/acs.inorgchem.6b02673. Epub 2017 Mar 27.

Two Co(I) hydrides containing the tripodal polyphosphine ligand EP

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Todisco S, Luconi L, Giambastiani G, et al. Ammonia Borane Dehydrogenation Catalyzed by (κ. Inorg Chem. 2017;56(8):4296-4307doi: 10.1021/acs.inorgchem.6b02673.
Todisco, S., Luconi, L., Giambastiani, G., Rossin, A., Peruzzini, M., Golub, I. E., Filippov, O. A., Belkova, N. V., & Shubina, E. S. (2017). Ammonia Borane Dehydrogenation Catalyzed by (κ. Inorganic chemistry, 56(8), 4296-4307. https://doi.org/10.1021/acs.inorgchem.6b02673
Todisco, Stefano, et al. "Ammonia Borane Dehydrogenation Catalyzed by (κ." Inorganic chemistry vol. 56,8 (2017): 4296-4307. doi: https://doi.org/10.1021/acs.inorgchem.6b02673
Todisco S, Luconi L, Giambastiani G, Rossin A, Peruzzini M, Golub IE, Filippov OA, Belkova NV, Shubina ES. Ammonia Borane Dehydrogenation Catalyzed by (κ. Inorg Chem. 2017 Apr 17;56(8):4296-4307. doi: 10.1021/acs.inorgchem.6b02673. Epub 2017 Mar 27. PMID: 28345899.
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Synthesis, characterization and coordination chemistry of the new tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-bis(methanephosphonic acid monoethyl ester) dipotassium salt.

Organic & biomolecular chemistry

Bianchini C, Giambastiani G, Laschi F, Mariani P, Vacca A, Vizza F, Zanello P.
PMID: 12929374
Org Biomol Chem. 2003 Mar 07;1(5):879-86. doi: 10.1039/b210655h.

A new potentially hexadentate tetraazamacrocycle based on the cyclen skeleton has been synthesized and fully characterized. The macrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-bis(methanephosphonic acid monoethyl ester) dipotassium salt (Me2DO2PME) contains mutually trans monoethyl ester phosphonate acid substituents on two nitrogen atoms, and trans...

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Bianchini C, Giambastiani G, Laschi F, et al. Synthesis, characterization and coordination chemistry of the new tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-bis(methanephosphonic acid monoethyl ester) dipotassium salt. Org Biomol Chem. 2003;1(5):879-86doi: 10.1039/b210655h.
Bianchini, C., Giambastiani, G., Laschi, F., Mariani, P., Vacca, A., Vizza, F., & Zanello, P. (2003). Synthesis, characterization and coordination chemistry of the new tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-bis(methanephosphonic acid monoethyl ester) dipotassium salt. Organic & biomolecular chemistry, 1(5), 879-86. https://doi.org/10.1039/b210655h
Bianchini, Claudio, et al. "Synthesis, characterization and coordination chemistry of the new tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-bis(methanephosphonic acid monoethyl ester) dipotassium salt." Organic & biomolecular chemistry vol. 1,5 (2003): 879-86. doi: https://doi.org/10.1039/b210655h
Bianchini C, Giambastiani G, Laschi F, Mariani P, Vacca A, Vizza F, Zanello P. Synthesis, characterization and coordination chemistry of the new tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-bis(methanephosphonic acid monoethyl ester) dipotassium salt. Org Biomol Chem. 2003 Mar 07;1(5):879-86. doi: 10.1039/b210655h. PMID: 12929374.
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Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis.

Dalton transactions (Cambridge, England : 2003)

Luconi L, Klosin J, Smith AJ, Germain S, Schulz E, Hannedouche J, Giambastiani G.
PMID: 23945547
Dalton Trans. 2013 Dec 07;42(45):16056-65. doi: 10.1039/c3dt51620b. Epub 2013 Aug 14.

Neutral Zr(IV) and Hf(IV) dimethyl complexes stabilized by unsymmetrical dianionic {N,C,N'} pincer ligands have been prepared from their corresponding bis-amido complexes upon treatment with AlMe3. Their structure consists of a central σ-bonded aryl donor group (C) capable of forming...

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Luconi L, Klosin J, Smith AJ, et al. Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis. Dalton Trans. 2013;42(45):16056-65doi: 10.1039/c3dt51620b.
Luconi, L., Klosin, J., Smith, A. J., Germain, S., Schulz, E., Hannedouche, J., & Giambastiani, G. (2013). Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis. Dalton transactions (Cambridge, England : 2003), 42(45), 16056-65. https://doi.org/10.1039/c3dt51620b
Luconi, Lapo, et al. "Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis." Dalton transactions (Cambridge, England : 2003) vol. 42,45 (2013): 16056-65. doi: https://doi.org/10.1039/c3dt51620b
Luconi L, Klosin J, Smith AJ, Germain S, Schulz E, Hannedouche J, Giambastiani G. Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis. Dalton Trans. 2013 Dec 07;42(45):16056-65. doi: 10.1039/c3dt51620b. Epub 2013 Aug 14. PMID: 23945547.
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Steric control on the redox chemistry of (η5-C9H7)2Yb(II)(THF)2 by 6-aryl substituted iminopyridines.

Dalton transactions (Cambridge, England : 2003)

Trifonov AA, Shestakov BG, Gudilenkov ID, Fukin GK, Giambastiani G, Bianchini C, Rossin A, Luconi L, Filippi J, Sorace L.
PMID: 21566826
Dalton Trans. 2011 Oct 28;40(40):10568-75. doi: 10.1039/c1dt10135h. Epub 2011 May 13.

A steric control on the reductive capacity of ytterbocenes towards iminopyridine ligands is described. The reaction of (η(5)-C(9)H(7))(2)Yb(THF)(2) with a series of 6-organyl-2-(aldimino)pyridyl ligands (IPy) takes place with the replacement of two THF molecules by one IPy unit. In...

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Trifonov AA, Shestakov BG, Gudilenkov ID, et al. Steric control on the redox chemistry of (η5-C9H7)2Yb(II)(THF)2 by 6-aryl substituted iminopyridines. Dalton Trans. 2011;40(40):10568-75doi: 10.1039/c1dt10135h.
Trifonov, A. A., Shestakov, B. G., Gudilenkov, I. D., Fukin, G. K., Giambastiani, G., Bianchini, C., Rossin, A., Luconi, L., Filippi, J., & Sorace, L. (2011). Steric control on the redox chemistry of (η5-C9H7)2Yb(II)(THF)2 by 6-aryl substituted iminopyridines. Dalton transactions (Cambridge, England : 2003), 40(40), 10568-75. https://doi.org/10.1039/c1dt10135h
Trifonov, Alexander A, et al. "Steric control on the redox chemistry of (η5-C9H7)2Yb(II)(THF)2 by 6-aryl substituted iminopyridines." Dalton transactions (Cambridge, England : 2003) vol. 40,40 (2011): 10568-75. doi: https://doi.org/10.1039/c1dt10135h
Trifonov AA, Shestakov BG, Gudilenkov ID, Fukin GK, Giambastiani G, Bianchini C, Rossin A, Luconi L, Filippi J, Sorace L. Steric control on the redox chemistry of (η5-C9H7)2Yb(II)(THF)2 by 6-aryl substituted iminopyridines. Dalton Trans. 2011 Oct 28;40(40):10568-75. doi: 10.1039/c1dt10135h. Epub 2011 May 13. PMID: 21566826.
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Biomimetic graphene for enhanced interaction with the external membrane of astrocytes.

Journal of materials chemistry. B

Durso M, Borrachero-Conejo AI, Bettini C, Treossi E, Scidà A, Saracino E, Gazzano M, Christian M, Morandi V, Tuci G, Giambastiani G, Ottaviano L, Perrozzi F, Benfenati V, Melucci M, Palermo V.
PMID: 32254499
J Mater Chem B. 2018 Sep 07;6(33):5335-5342. doi: 10.1039/c8tb01410h. Epub 2018 Jul 25.

Graphene and graphene substrates display huge potential as material interfaces for devices and biomedical tools targeting the modulation or recovery of brain functionality. However, to be considered reliable neural interfaces, graphene-derived substrates should properly interact with astrocytes, favoring their...

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Durso M, Borrachero-Conejo AI, Bettini C, et al. Biomimetic graphene for enhanced interaction with the external membrane of astrocytes. J Mater Chem B. 2018;6(33):5335-5342doi: 10.1039/c8tb01410h.
Durso, M., Borrachero-Conejo, A. I., Bettini, C., Treossi, E., Scidà, A., Saracino, E., Gazzano, M., Christian, M., Morandi, V., Tuci, G., Giambastiani, G., Ottaviano, L., Perrozzi, F., Benfenati, V., Melucci, M., & Palermo, V. (2018). Biomimetic graphene for enhanced interaction with the external membrane of astrocytes. Journal of materials chemistry. B, 6(33), 5335-5342. https://doi.org/10.1039/c8tb01410h
Durso, M, et al. "Biomimetic graphene for enhanced interaction with the external membrane of astrocytes." Journal of materials chemistry. B vol. 6,33 (2018): 5335-5342. doi: https://doi.org/10.1039/c8tb01410h
Durso M, Borrachero-Conejo AI, Bettini C, Treossi E, Scidà A, Saracino E, Gazzano M, Christian M, Morandi V, Tuci G, Giambastiani G, Ottaviano L, Perrozzi F, Benfenati V, Melucci M, Palermo V. Biomimetic graphene for enhanced interaction with the external membrane of astrocytes. J Mater Chem B. 2018 Sep 07;6(33):5335-5342. doi: 10.1039/c8tb01410h. Epub 2018 Jul 25. PMID: 32254499.
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Light-responsive nanocomposite sponges for on demand chemical release with high spatial and dosage control.

Journal of materials chemistry. B

Matteini P, Martina MR, Giambastiani G, Tatini F, Cascella R, Ratto F, Cecchi C, Caminati G, Dei L, Pini R.
PMID: 32260832
J Mater Chem B. 2013 Feb 28;1(8):1096-1100. doi: 10.1039/c2tb00310d. Epub 2013 Jan 07.

We present a biocompatible device for on demand chemical release in the form of a light-activated sponge-like nanocomposite scaffold, which ensures excellent control over the principal parameters of chemical release and dosage in order to sustain effective therapeutic action....

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Matteini P, Martina MR, Giambastiani G, et al. Light-responsive nanocomposite sponges for on demand chemical release with high spatial and dosage control. J Mater Chem B. 2013;1(8):1096-1100doi: 10.1039/c2tb00310d.
Matteini, P., Martina, M. R., Giambastiani, G., Tatini, F., Cascella, R., Ratto, F., Cecchi, C., Caminati, G., Dei, L., & Pini, R. (2013). Light-responsive nanocomposite sponges for on demand chemical release with high spatial and dosage control. Journal of materials chemistry. B, 1(8), 1096-1100. https://doi.org/10.1039/c2tb00310d
Matteini, Paolo, et al. "Light-responsive nanocomposite sponges for on demand chemical release with high spatial and dosage control." Journal of materials chemistry. B vol. 1,8 (2013): 1096-1100. doi: https://doi.org/10.1039/c2tb00310d
Matteini P, Martina MR, Giambastiani G, Tatini F, Cascella R, Ratto F, Cecchi C, Caminati G, Dei L, Pini R. Light-responsive nanocomposite sponges for on demand chemical release with high spatial and dosage control. J Mater Chem B. 2013 Feb 28;1(8):1096-1100. doi: 10.1039/c2tb00310d. Epub 2013 Jan 07. PMID: 32260832.
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Porous Silicon Carbide (SiC): A Chance for Improving Catalysts or Just Another Active-Phase Carrier?.

Chemical reviews

Tuci G, Liu Y, Rossin A, Guo X, Pham C, Giambastiani G, Pham-Huu C.
PMID: 34255488
Chem Rev. 2021 Sep 08;121(17):10559-10665. doi: 10.1021/acs.chemrev.1c00269. Epub 2021 Jul 13.

There is an obvious gap between efforts dedicated to the control of chemicophysical and morphological properties of catalyst active phases and the attention paid to the search of new materials to be employed as functional carriers in the upgrading...

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Tuci G, Liu Y, Rossin A, et al. Porous Silicon Carbide (SiC): A Chance for Improving Catalysts or Just Another Active-Phase Carrier?. Chem Rev. 2021;121(17):10559-10665doi: 10.1021/acs.chemrev.1c00269.
Tuci, G., Liu, Y., Rossin, A., Guo, X., Pham, C., Giambastiani, G., & Pham-Huu, C. (2021). Porous Silicon Carbide (SiC): A Chance for Improving Catalysts or Just Another Active-Phase Carrier?. Chemical reviews, 121(17), 10559-10665. https://doi.org/10.1021/acs.chemrev.1c00269
Tuci, Giulia, et al. "Porous Silicon Carbide (SiC): A Chance for Improving Catalysts or Just Another Active-Phase Carrier?." Chemical reviews vol. 121,17 (2021): 10559-10665. doi: https://doi.org/10.1021/acs.chemrev.1c00269
Tuci G, Liu Y, Rossin A, Guo X, Pham C, Giambastiani G, Pham-Huu C. Porous Silicon Carbide (SiC): A Chance for Improving Catalysts or Just Another Active-Phase Carrier?. Chem Rev. 2021 Sep 08;121(17):10559-10665. doi: 10.1021/acs.chemrev.1c00269. Epub 2021 Jul 13. PMID: 34255488.
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Carbon Dioxide Capture and Utilization with Isomeric Forms of Bis(amino)-Tagged Zinc Bipyrazolate Metal-Organic Frameworks.

Chemistry (Weinheim an der Bergstrasse, Germany)

Mercuri G, Moroni M, Domasevitch KV, Di Nicola C, Campitelli P, Pettinari C, Giambastiani G, Galli S, Rossin A.
PMID: 33368713
Chemistry. 2021 Mar 08;27(14):4746-4754. doi: 10.1002/chem.202005216. Epub 2021 Feb 15.

Aiming at extending the tagged zinc bipyrazolate metal-organic frameworks (MOFs) family, the ligand 3,3'-diamino-4,4'-bipyrazole (3,3'-H

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Mercuri G, Moroni M, Domasevitch KV, et al. Carbon Dioxide Capture and Utilization with Isomeric Forms of Bis(amino)-Tagged Zinc Bipyrazolate Metal-Organic Frameworks. Chemistry. 2021;27(14):4746-4754doi: 10.1002/chem.202005216.
Mercuri, G., Moroni, M., Domasevitch, K. V., Di Nicola, C., Campitelli, P., Pettinari, C., Giambastiani, G., Galli, S., & Rossin, A. (2021). Carbon Dioxide Capture and Utilization with Isomeric Forms of Bis(amino)-Tagged Zinc Bipyrazolate Metal-Organic Frameworks. Chemistry (Weinheim an der Bergstrasse, Germany), 27(14), 4746-4754. https://doi.org/10.1002/chem.202005216
Mercuri, Giorgio, et al. "Carbon Dioxide Capture and Utilization with Isomeric Forms of Bis(amino)-Tagged Zinc Bipyrazolate Metal-Organic Frameworks." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 27,14 (2021): 4746-4754. doi: https://doi.org/10.1002/chem.202005216
Mercuri G, Moroni M, Domasevitch KV, Di Nicola C, Campitelli P, Pettinari C, Giambastiani G, Galli S, Rossin A. Carbon Dioxide Capture and Utilization with Isomeric Forms of Bis(amino)-Tagged Zinc Bipyrazolate Metal-Organic Frameworks. Chemistry. 2021 Mar 08;27(14):4746-4754. doi: 10.1002/chem.202005216. Epub 2021 Feb 15. PMID: 33368713.
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Temperature-Dependent Nitrous Oxide/Carbon Dioxide Preferential Adsorption in a Thiazolium-Functionalized NU-1000 Metal-Organic Framework.

ACS applied materials & interfaces

Mercuri G, Moroni M, Galli S, Tuci G, Giambastiani G, Yan T, Liu D, Rossin A.
PMID: 34854665
ACS Appl Mater Interfaces. 2021 Dec 15;13(49):58982-58993. doi: 10.1021/acsami.1c21437. Epub 2021 Dec 02.

Solvent-assisted ligand incorporation (SALI) of the ditopic linker 5-carboxy-3-(4-carboxybenzyl)thiazolium bromide [(

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Mercuri G, Moroni M, Galli S, et al. Temperature-Dependent Nitrous Oxide/Carbon Dioxide Preferential Adsorption in a Thiazolium-Functionalized NU-1000 Metal-Organic Framework. ACS Appl Mater Interfaces. 2021;13(49):58982-58993doi: 10.1021/acsami.1c21437.
Mercuri, G., Moroni, M., Galli, S., Tuci, G., Giambastiani, G., Yan, T., Liu, D., & Rossin, A. (2021). Temperature-Dependent Nitrous Oxide/Carbon Dioxide Preferential Adsorption in a Thiazolium-Functionalized NU-1000 Metal-Organic Framework. ACS applied materials & interfaces, 13(49), 58982-58993. https://doi.org/10.1021/acsami.1c21437
Mercuri, Giorgio, et al. "Temperature-Dependent Nitrous Oxide/Carbon Dioxide Preferential Adsorption in a Thiazolium-Functionalized NU-1000 Metal-Organic Framework." ACS applied materials & interfaces vol. 13,49 (2021): 58982-58993. doi: https://doi.org/10.1021/acsami.1c21437
Mercuri G, Moroni M, Galli S, Tuci G, Giambastiani G, Yan T, Liu D, Rossin A. Temperature-Dependent Nitrous Oxide/Carbon Dioxide Preferential Adsorption in a Thiazolium-Functionalized NU-1000 Metal-Organic Framework. ACS Appl Mater Interfaces. 2021 Dec 15;13(49):58982-58993. doi: 10.1021/acsami.1c21437. Epub 2021 Dec 02. PMID: 34854665.
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The first tridentate phosphine ligand combining planar, phosphorus and carbon chirality.

Chemical communications (Cambridge, England)

Barbaro P, Bianchini C, Giambastiani G, Togni A.
PMID: 12510292
Chem Commun (Camb). 2002 Nov 21;(22):2672-3. doi: 10.1039/b208384a.

Two new diastereomerically pure tridentate phosphine ligands combining planar, phosphorus and carbon chirality have been conveniently synthesized via resolution of their phosphineoxide-diborane adducts and structurally characterized by X-ray analyses.

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Barbaro P, Bianchini C, Giambastiani G, et al. The first tridentate phosphine ligand combining planar, phosphorus and carbon chirality. Chem Commun (Camb). 2002;(22):2672-3doi: 10.1039/b208384a.
Barbaro, P., Bianchini, C., Giambastiani, G., & Togni, A. (2002). The first tridentate phosphine ligand combining planar, phosphorus and carbon chirality. Chemical communications (Cambridge, England), (22), 2672-3. https://doi.org/10.1039/b208384a
Barbaro, Pierluigi, et al. "The first tridentate phosphine ligand combining planar, phosphorus and carbon chirality." Chemical communications (Cambridge, England) vol. ,22 (2002): 2672-3. doi: https://doi.org/10.1039/b208384a
Barbaro P, Bianchini C, Giambastiani G, Togni A. The first tridentate phosphine ligand combining planar, phosphorus and carbon chirality. Chem Commun (Camb). 2002 Nov 21;(22):2672-3. doi: 10.1039/b208384a. PMID: 12510292.
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Can nitrones functionalize carbon nanotubes?.

Chemical communications (Cambridge, England)

Ghini G, Luconi L, Rossin A, Bianchini C, Giambastiani G, Cicchi S, Lascialfari L, Brandi A, Giannasi A.
PMID: 20024342
Chem Commun (Camb). 2010 Jan 14;46(2):252-4. doi: 10.1039/b917016b. Epub 2009 Nov 16.

An unprecedented functionalization of multi-walled carbon nanotubes (MWCNTs) has been conveniently achieved by the 1,3-dipolar cycloaddition of a cyclic nitrone. This organic functionalization yields materials with a great solubility in DMF (close to 10 mg per mL of DMF)...

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Ghini G, Luconi L, Rossin A, et al. Can nitrones functionalize carbon nanotubes?. Chem Commun (Camb). 2009;46(2):252-4doi: 10.1039/b917016b.
Ghini, G., Luconi, L., Rossin, A., Bianchini, C., Giambastiani, G., Cicchi, S., Lascialfari, L., Brandi, A., & Giannasi, A. (2010). Can nitrones functionalize carbon nanotubes?. Chemical communications (Cambridge, England), 46(2), 252-4. https://doi.org/10.1039/b917016b
Ghini, Giacomo, et al. "Can nitrones functionalize carbon nanotubes?." Chemical communications (Cambridge, England) vol. 46,2 (2010): 252-4. doi: https://doi.org/10.1039/b917016b
Ghini G, Luconi L, Rossin A, Bianchini C, Giambastiani G, Cicchi S, Lascialfari L, Brandi A, Giannasi A. Can nitrones functionalize carbon nanotubes?. Chem Commun (Camb). 2010 Jan 14;46(2):252-4. doi: 10.1039/b917016b. Epub 2009 Nov 16. PMID: 20024342.
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Nitro-functionalized Bis(pyrazolate) Metal-Organic Frameworks as Carbon Dioxide Capture Materials under Ambient Conditions.

Chemistry (Weinheim an der Bergstrasse, Germany)

Mosca N, Vismara R, Fernandes JA, Tuci G, Di Nicola C, Domasevitch KV, Giacobbe C, Giambastiani G, Pettinari C, Aragones-Anglada M, Moghadam PZ, Fairen-Jimenez D, Rossin A, Galli S.
PMID: 30028544
Chemistry. 2018 Sep 06;24(50):13170-13180. doi: 10.1002/chem.201802240. Epub 2018 Aug 27.

The metal-organic frameworks (MOFs) M(BPZNO

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Mosca N, Vismara R, Fernandes JA, et al. Nitro-functionalized Bis(pyrazolate) Metal-Organic Frameworks as Carbon Dioxide Capture Materials under Ambient Conditions. Chemistry. 2018;24(50):13170-13180doi: 10.1002/chem.201802240.
Mosca, N., Vismara, R., Fernandes, J. A., Tuci, G., Di Nicola, C., Domasevitch, K. V., Giacobbe, C., Giambastiani, G., Pettinari, C., Aragones-Anglada, M., Moghadam, P. Z., Fairen-Jimenez, D., Rossin, A., & Galli, S. (2018). Nitro-functionalized Bis(pyrazolate) Metal-Organic Frameworks as Carbon Dioxide Capture Materials under Ambient Conditions. Chemistry (Weinheim an der Bergstrasse, Germany), 24(50), 13170-13180. https://doi.org/10.1002/chem.201802240
Mosca, Nello, et al. "Nitro-functionalized Bis(pyrazolate) Metal-Organic Frameworks as Carbon Dioxide Capture Materials under Ambient Conditions." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 24,50 (2018): 13170-13180. doi: https://doi.org/10.1002/chem.201802240
Mosca N, Vismara R, Fernandes JA, Tuci G, Di Nicola C, Domasevitch KV, Giacobbe C, Giambastiani G, Pettinari C, Aragones-Anglada M, Moghadam PZ, Fairen-Jimenez D, Rossin A, Galli S. Nitro-functionalized Bis(pyrazolate) Metal-Organic Frameworks as Carbon Dioxide Capture Materials under Ambient Conditions. Chemistry. 2018 Sep 06;24(50):13170-13180. doi: 10.1002/chem.201802240. Epub 2018 Aug 27. PMID: 30028544.
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