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Showing 1 to 12 of 226 entries
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Structure and osmotic pressure of ionic microgel dispersions.

The Journal of chemical physics

Hedrick MM, Chung JK, Denton AR.
PMID: 25612730
J Chem Phys. 2015 Jan 21;142(3):034904. doi: 10.1063/1.4905574.

We investigate structural and thermodynamic properties of aqueous dispersions of ionic microgels--soft colloidal gel particles that exhibit unusual phase behavior. Starting from a coarse-grained model of microgel macroions as charged spheres that are permeable to microions, we perform simulations...

Adult bacterial exposure increases behavioral variation and drives higher repeatability in field crickets.

Behavioral ecology and sociobiology

DiRienzo N, Niemelä PT, Hedrick AV, Kortet R.
PMID: 28584393
Behav Ecol Sociobiol. 2016 Nov;70(11):1941-1947. doi: 10.1007/s00265-016-2200-5. Epub 2016 Sep 09.

Among-individual differences in behavior are now a widely studied research-focus within the field of behavioral ecology. Furthermore, elements of an animal's internal state, such as energy or fat reserves, and infection status can have large impacts on behaviors. Despite...

Computational and experimental investigations of one-step conversion of poly(carbonate)s into value-added poly(aryl ether sulfone)s.

Proceedings of the National Academy of Sciences of the United States of America

Jones GO, Yuen A, Wojtecki RJ, Hedrick JL, García JM.
PMID: 27354514
Proc Natl Acad Sci U S A. 2016 Jul 12;113(28):7722-6. doi: 10.1073/pnas.1600924113. Epub 2016 Jun 27.

It is estimated that ∼2.7 million tons poly(carbonate)s (PCs) are produced annually worldwide. In 2008, retailers pulled products from store shelves after reports of bisphenol A (BPA) leaching from baby bottles, reusable drink bottles, and other retail products. Since...

Tagging alcohols with cyclic carbonate: a versatile equivalent of (meth)acrylate for ring-opening polymerization.

Chemical communications (Cambridge, England)

Pratt RC, Nederberg F, Waymouth RM, Hedrick JL.
PMID: 18399418
Chem Commun (Camb). 2008 Jan 07;(1):114-6. doi: 10.1039/b713925j.

Cyclic carbonate monomers based on a single biocompatible scaffold allow for incorporation of a wide range of functional groups into macromolecules via ring-opening polymerization.

Photoelectron spectroscopy of the [glycine x (H2O)(1,2)]- clusters: sequential hydration shifts and observation of isomers.

The Journal of chemical physics

Diken EG, Headrick JM, Johnson MA.
PMID: 15974678
J Chem Phys. 2005 Jun 08;122(22):224317. doi: 10.1063/1.1930833.

The electron binding energies of the small hydrated amino acid anions, [glycine x (H2O)(1,2)]-, are determined using photoelectron spectroscopy. The vertical electron detachment energies (VDEs) are found to increase by approximately 0.12 eV with each additional water molecule such...

TENDENCIES IN THE LOGIC OF MATHEMATICS.

Science (New York, N.Y.)

Hedrick ER.
PMID: 17794280
Science. 1933 Apr 07;77(1997):335-43. doi: 10.1126/science.77.1997.335.

No abstract available.

Starlike dendrimers in solutions: structural properties and internal dynamics.

The Journal of chemical physics

Rathgeber S, Monkenbusch M, Hedrick JL, Trollsås M, Gast AP.
PMID: 17144741
J Chem Phys. 2006 Nov 28;125(20):204908. doi: 10.1063/1.2364895.

We measured the shape and the internal dynamics of starlike dendrimers under good solvent conditions with small-angle neutron scattering and neutron spin-echo (NSE) spectroscopy, respectively. Architectural parameters such as the spacer length and generation were varied in a systematic...

Spectral signatures of hydrated proton vibrations in water clusters.

Science (New York, N.Y.)

Headrick JM, Diken EG, Walters RS, Hammer NI, Christie RA, Cui J, Myshakin EM, Duncan MA, Johnson MA, Jordan KD.
PMID: 15961665
Science. 2005 Jun 17;308(5729):1765-9. doi: 10.1126/science.1113094.

The ease with which the pH of water is measured obscures the fact that there is presently no clear molecular description for the hydrated proton. The mid-infrared spectrum of bulk aqueous acid, for example, is too diffuse to establish...

Nanoscale frictional dissipation into shear-stressed polymer relaxations.

Physical review letters

Jansen L, Schirmeisen A, Hedrick JL, Lantz MA, Knoll A, Cannara R, Gotsmann B.
PMID: 19658951
Phys Rev Lett. 2009 Jun 12;102(23):236101. doi: 10.1103/PhysRevLett.102.236101. Epub 2009 Jun 09.

Sliding friction between a silicon tip and a highly cross-linked polyaryletherketone film is studied using friction force microscopy. The friction force as a function of temperature between 150 and 500 K shows distinctive maxima corresponding to alpha and beta...

Nanoscale three-dimensional patterning of molecular resists by scanning probes.

Science (New York, N.Y.)

Pires D, Hedrick JL, De Silva A, Frommer J, Gotsmann B, Wolf H, Despont M, Duerig U, Knoll AW.
PMID: 20413457
Science. 2010 May 07;328(5979):732-5. doi: 10.1126/science.1187851. Epub 2010 Apr 22.

For patterning organic resists, optical and electron beam lithography are the most established methods; however, at resolutions below 30 nanometers, inherent problems result from unwanted exposure of the resist in nearby areas. We present a scanning probe lithography method...

Mechanisms of organocatalytic amidation and trans-esterification of aromatic esters as a model for the depolymerization of poly(ethylene) terephthalate.

The journal of physical chemistry. A

Horn HW, Jones GO, Wei DS, Fukushima K, Lecuyer JM, Coady DJ, Hedrick JL, Rice JE.
PMID: 23241219
J Phys Chem A. 2012 Dec 27;116(51):12389-98. doi: 10.1021/jp304212y. Epub 2012 Dec 14.

We describe investigations with B3LYP density functional theory to probe mechanisms for the organocatalyzed depolymerization of poly(ethylene) terephthalate (PET) into ester and amide products. These investigations utilize model systems involving the trans-esterification and amidation of methylbenzoate (MB) with ethylene...

Effects of jet-fuel microbial isolates on a polyurethane foam.

Applied microbiology

Hedrick HG, Crum MG.
PMID: 16349826
Appl Microbiol. 1968 Dec;16(12):1826-30. doi: 10.1128/am.16.12.1826-1830.1968.

Jet-fuel microbial isolates were studied for effects on a polyurethane foam material that has been proposed as a baffling material for use in aircraft fuel tanks. Evidence was found that a polyesterurethane foam gave increased cell counts and oxygen...

Showing 1 to 12 of 226 entries