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Bioinspired carbide-derived carbons with hierarchical pore structure for the adsorptive removal of mercury from aqueous solution.

Chemical communications (Cambridge, England)

Fischer C, Oschatz M, Nickel W, Leistenschneider D, Kaskel S, Brunner E.
PMID: 28421211
Chem Commun (Camb). 2017 Apr 27;53(35):4845-4848. doi: 10.1039/c6cc08041c.

Biosilica of the diatom species Thalassiosira pseudonana is used as hard template for the synthesis of silicon carbide-derived carbons. The typical species-specific macroporous structure is retained during the nanocasting-chlorine treatment process and the resulting materials exhibit very high specific...

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Fischer C, Oschatz M, Nickel W, et al. Bioinspired carbide-derived carbons with hierarchical pore structure for the adsorptive removal of mercury from aqueous solution. Chem Commun (Camb). 2017;53(35):4845-4848doi: 10.1039/c6cc08041c.
Fischer, C., Oschatz, M., Nickel, W., Leistenschneider, D., Kaskel, S., & Brunner, E. (2017). Bioinspired carbide-derived carbons with hierarchical pore structure for the adsorptive removal of mercury from aqueous solution. Chemical communications (Cambridge, England), 53(35), 4845-4848. https://doi.org/10.1039/c6cc08041c
Fischer, C, et al. "Bioinspired carbide-derived carbons with hierarchical pore structure for the adsorptive removal of mercury from aqueous solution." Chemical communications (Cambridge, England) vol. 53,35 (2017): 4845-4848. doi: https://doi.org/10.1039/c6cc08041c
Fischer C, Oschatz M, Nickel W, Leistenschneider D, Kaskel S, Brunner E. Bioinspired carbide-derived carbons with hierarchical pore structure for the adsorptive removal of mercury from aqueous solution. Chem Commun (Camb). 2017 Apr 27;53(35):4845-4848. doi: 10.1039/c6cc08041c. PMID: 28421211.
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Hyperhoneycomb Iridate β-Li2IrO3 as a platform for Kitaev magnetism.

Physical review letters

Takayama T, Kato A, Dinnebier R, Nuss J, Kono H, Veiga LS, Fabbris G, Haskel D, Takagi H.
PMID: 25763972
Phys Rev Lett. 2015 Feb 20;114(7):077202. doi: 10.1103/PhysRevLett.114.077202. Epub 2015 Feb 19.

A complex iridium oxide β-Li(2)IrO(3) crystallizes in a hyperhoneycomb structure, a three-dimensional analogue of honeycomb lattice, and is found to be a spin-orbital Mott insulator with J(eff)=1/2 moment. Ir ions are connected to the three neighboring Ir ions via...

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Takayama T, Kato A, Dinnebier R, et al. Hyperhoneycomb Iridate β-Li2IrO3 as a platform for Kitaev magnetism. Phys Rev Lett. 2015;114(7):077202doi: 10.1103/PhysRevLett.114.077202.
Takayama, T., Kato, A., Dinnebier, R., Nuss, J., Kono, H., Veiga, L. S., Fabbris, G., Haskel, D., & Takagi, H. (2015). Hyperhoneycomb Iridate β-Li2IrO3 as a platform for Kitaev magnetism. Physical review letters, 114(7), 077202. https://doi.org/10.1103/PhysRevLett.114.077202
Takayama, T, et al. "Hyperhoneycomb Iridate β-Li2IrO3 as a platform for Kitaev magnetism." Physical review letters vol. 114,7 (2015): 077202. doi: https://doi.org/10.1103/PhysRevLett.114.077202
Takayama T, Kato A, Dinnebier R, Nuss J, Kono H, Veiga LS, Fabbris G, Haskel D, Takagi H. Hyperhoneycomb Iridate β-Li2IrO3 as a platform for Kitaev magnetism. Phys Rev Lett. 2015 Feb 20;114(7):077202. doi: 10.1103/PhysRevLett.114.077202. Epub 2015 Feb 19. PMID: 25763972.
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A Stimuli-Responsive Zirconium Metal-Organic Framework Based on Supermolecular Design.

Angewandte Chemie (International ed. in English)

Krause S, Bon V, Stoeck U, Senkovska I, Többens DM, Wallacher D, Kaskel S.
PMID: 28670873
Angew Chem Int Ed Engl. 2017 Aug 28;56(36):10676-10680. doi: 10.1002/anie.201702357. Epub 2017 Jul 24.

A flexible, yet very stable metal-organic framework (DUT-98, Zr

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Krause S, Bon V, Stoeck U, et al. A Stimuli-Responsive Zirconium Metal-Organic Framework Based on Supermolecular Design. Angew Chem Int Ed Engl. 2017;56(36):10676-10680doi: 10.1002/anie.201702357.
Krause, S., Bon, V., Stoeck, U., Senkovska, I., Többens, D. M., Wallacher, D., & Kaskel, S. (2017). A Stimuli-Responsive Zirconium Metal-Organic Framework Based on Supermolecular Design. Angewandte Chemie (International ed. in English), 56(36), 10676-10680. https://doi.org/10.1002/anie.201702357
Krause, Simon, et al. "A Stimuli-Responsive Zirconium Metal-Organic Framework Based on Supermolecular Design." Angewandte Chemie (International ed. in English) vol. 56,36 (2017): 10676-10680. doi: https://doi.org/10.1002/anie.201702357
Krause S, Bon V, Stoeck U, Senkovska I, Többens DM, Wallacher D, Kaskel S. A Stimuli-Responsive Zirconium Metal-Organic Framework Based on Supermolecular Design. Angew Chem Int Ed Engl. 2017 Aug 28;56(36):10676-10680. doi: 10.1002/anie.201702357. Epub 2017 Jul 24. PMID: 28670873.
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A pressure-amplifying framework material with negative gas adsorption transitions.

Nature

Krause S, Bon V, Senkovska I, Stoeck U, Wallacher D, Többens DM, Zander S, Pillai RS, Maurin G, Coudert FX, Kaskel S.
PMID: 27049950
Nature. 2016 Apr 21;532(7599):348-52. doi: 10.1038/nature17430. Epub 2016 Apr 06.

Adsorption-based phenomena are important in gas separations, such as the treatment of greenhouse-gas and toxic-gas pollutants, and in water-adsorption-based heat pumps for solar cooling systems. The ability to tune the pore size, shape and functionality of crystalline porous coordination...

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Krause S, Bon V, Senkovska I, et al. A pressure-amplifying framework material with negative gas adsorption transitions. Nature. 2016;532(7599):348-52doi: 10.1038/nature17430.
Krause, S., Bon, V., Senkovska, I., Stoeck, U., Wallacher, D., Többens, D. M., Zander, S., Pillai, R. S., Maurin, G., Coudert, F. X., & Kaskel, S. (2016). A pressure-amplifying framework material with negative gas adsorption transitions. Nature, 532(7599), 348-52. https://doi.org/10.1038/nature17430
Krause, Simon, et al. "A pressure-amplifying framework material with negative gas adsorption transitions." Nature vol. 532,7599 (2016): 348-52. doi: https://doi.org/10.1038/nature17430
Krause S, Bon V, Senkovska I, Stoeck U, Wallacher D, Többens DM, Zander S, Pillai RS, Maurin G, Coudert FX, Kaskel S. A pressure-amplifying framework material with negative gas adsorption transitions. Nature. 2016 Apr 21;532(7599):348-52. doi: 10.1038/nature17430. Epub 2016 Apr 06. PMID: 27049950.
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Unusual ultra-hydrophilic, porous carbon cuboids for atmospheric-water capture.

Angewandte Chemie (International ed. in English)

Hao GP, Mondin G, Zheng Z, Biemelt T, Klosz S, Schubel R, Eychmüller A, Kaskel S.
PMID: 25522081
Angew Chem Int Ed Engl. 2015 Feb 02;54(6):1941-5. doi: 10.1002/anie.201409439. Epub 2014 Dec 17.

There is significant interest in high-performance materials that can directly and efficiently capture water vapor, particularly from air. Herein, we report a class of novel porous carbon cuboids with unusual ultra-hydrophilic properties, over which the synergistic effects between surface...

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Hao GP, Mondin G, Zheng Z, et al. Unusual ultra-hydrophilic, porous carbon cuboids for atmospheric-water capture. Angew Chem Int Ed Engl. 2014;54(6):1941-5doi: 10.1002/anie.201409439.
Hao, G. P., Mondin, G., Zheng, Z., Biemelt, T., Klosz, S., Schubel, R., Eychmüller, A., & Kaskel, S. (2015). Unusual ultra-hydrophilic, porous carbon cuboids for atmospheric-water capture. Angewandte Chemie (International ed. in English), 54(6), 1941-5. https://doi.org/10.1002/anie.201409439
Hao, Guang-Ping, et al. "Unusual ultra-hydrophilic, porous carbon cuboids for atmospheric-water capture." Angewandte Chemie (International ed. in English) vol. 54,6 (2015): 1941-5. doi: https://doi.org/10.1002/anie.201409439
Hao GP, Mondin G, Zheng Z, Biemelt T, Klosz S, Schubel R, Eychmüller A, Kaskel S. Unusual ultra-hydrophilic, porous carbon cuboids for atmospheric-water capture. Angew Chem Int Ed Engl. 2015 Feb 02;54(6):1941-5. doi: 10.1002/anie.201409439. Epub 2014 Dec 17. PMID: 25522081.
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Mild serotonin syndrome: A report of 12 cases.

Annals of Indian Academy of Neurology

Prakash S, Patel V, Kakked S, Patel I, Yadav R.
PMID: 26019424
Ann Indian Acad Neurol. 2015 Apr-Jun;18(2):226-30. doi: 10.4103/0972-2327.150612.

Serotonin syndrome (SS) is an under diagnosed and under reported condition. Mild SS is easily overlooked by physicians. Every patient with mild SS is a potential candidate for developing life-threatening severe SS because of inadvertent overdose or the addition...

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Prakash S, Patel V, Kakked S, et al. Mild serotonin syndrome: A report of 12 cases. Ann Indian Acad Neurol. 2015;18(2):226-30doi: 10.4103/0972-2327.150612.
Prakash, S., Patel, V., Kakked, S., Patel, I., & Yadav, R. (2015). Mild serotonin syndrome: A report of 12 cases. Annals of Indian Academy of Neurology, 18(2), 226-30. https://doi.org/10.4103/0972-2327.150612
Prakash, Sanjay, et al. "Mild serotonin syndrome: A report of 12 cases." Annals of Indian Academy of Neurology vol. 18,2 (2015): 226-30. doi: https://doi.org/10.4103/0972-2327.150612
Prakash S, Patel V, Kakked S, Patel I, Yadav R. Mild serotonin syndrome: A report of 12 cases. Ann Indian Acad Neurol. 2015 Apr-Jun;18(2):226-30. doi: 10.4103/0972-2327.150612. PMID: 26019424; PMCID: PMC4445202.
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Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex.

Angewandte Chemie (International ed. in English)

Braunschweig H, Celik MA, Dewhurst RD, Kachel S, Wennemann B.
PMID: 26990148
Angew Chem Int Ed Engl. 2016 Apr 11;55(16):5076-80. doi: 10.1002/anie.201600307. Epub 2016 Mar 15.

The complete scission of the carbon-oxygen bond of carbon monoxide, while frequently observed on bulk metals and with bimetallic and cluster transition metal complexes, is unknown with monometallic systems. Reaction of a zerovalent iron bis(borylene) complex with a cyclic...

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Braunschweig H, Celik MA, Dewhurst RD, et al. Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex. Angew Chem Int Ed Engl. 2016;55(16):5076-80doi: 10.1002/anie.201600307.
Braunschweig, H., Celik, M. A., Dewhurst, R. D., Kachel, S., & Wennemann, B. (2016). Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex. Angewandte Chemie (International ed. in English), 55(16), 5076-80. https://doi.org/10.1002/anie.201600307
Braunschweig, Holger, et al. "Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex." Angewandte Chemie (International ed. in English) vol. 55,16 (2016): 5076-80. doi: https://doi.org/10.1002/anie.201600307
Braunschweig H, Celik MA, Dewhurst RD, Kachel S, Wennemann B. Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex. Angew Chem Int Ed Engl. 2016 Apr 11;55(16):5076-80. doi: 10.1002/anie.201600307. Epub 2016 Mar 15. PMID: 26990148.
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Tailoring adsorption induced phase transitions in the pillared-layer type metal-organic framework DUT-8(Ni).

Dalton transactions (Cambridge, England : 2003)

Kavoosi N, Bon V, Senkovska I, Krause S, Atzori C, Bonino F, Pallmann J, Paasch S, Brunner E, Kaskel S.
PMID: 28332683
Dalton Trans. 2017 Apr 05;46(14):4685-4695. doi: 10.1039/c7dt00015d.

Tailoring the characteristics of gating transitions in the porous network, Ni

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Kavoosi N, Bon V, Senkovska I, et al. Tailoring adsorption induced phase transitions in the pillared-layer type metal-organic framework DUT-8(Ni). Dalton Trans. 2017;46(14):4685-4695doi: 10.1039/c7dt00015d.
Kavoosi, N., Bon, V., Senkovska, I., Krause, S., Atzori, C., Bonino, F., Pallmann, J., Paasch, S., Brunner, E., & Kaskel, S. (2017). Tailoring adsorption induced phase transitions in the pillared-layer type metal-organic framework DUT-8(Ni). Dalton transactions (Cambridge, England : 2003), 46(14), 4685-4695. https://doi.org/10.1039/c7dt00015d
Kavoosi, Negar, et al. "Tailoring adsorption induced phase transitions in the pillared-layer type metal-organic framework DUT-8(Ni)." Dalton transactions (Cambridge, England : 2003) vol. 46,14 (2017): 4685-4695. doi: https://doi.org/10.1039/c7dt00015d
Kavoosi N, Bon V, Senkovska I, Krause S, Atzori C, Bonino F, Pallmann J, Paasch S, Brunner E, Kaskel S. Tailoring adsorption induced phase transitions in the pillared-layer type metal-organic framework DUT-8(Ni). Dalton Trans. 2017 Apr 05;46(14):4685-4695. doi: 10.1039/c7dt00015d. PMID: 28332683.
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Postsynthetic Inner-Surface Functionalization of the Highly Stable Zirconium-Based Metal-Organic Framework DUT-67.

Inorganic chemistry

Drache F, Bon V, Senkovska I, Marschelke C, Synytska A, Kaskel S.
PMID: 27378209
Inorg Chem. 2016 Aug 01;55(15):7206-13. doi: 10.1021/acs.inorgchem.6b00829. Epub 2016 Jul 05.

A postsynthetic functionalization approach was used to tailor the hydrophobicity of DUT-67, a metal-organic framework (MOF) consisting of 8-connected Zr6O6(OH)2 clusters and 2,5-thiophenedicarboxylate as the ligand, using postsynthetic exchange of the modulator by fluorinated monocarboxylates. Water adsorption isotherms demonstrated...

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Drache F, Bon V, Senkovska I, et al. Postsynthetic Inner-Surface Functionalization of the Highly Stable Zirconium-Based Metal-Organic Framework DUT-67. Inorg Chem. 2016;55(15):7206-13doi: 10.1021/acs.inorgchem.6b00829.
Drache, F., Bon, V., Senkovska, I., Marschelke, C., Synytska, A., & Kaskel, S. (2016). Postsynthetic Inner-Surface Functionalization of the Highly Stable Zirconium-Based Metal-Organic Framework DUT-67. Inorganic chemistry, 55(15), 7206-13. https://doi.org/10.1021/acs.inorgchem.6b00829
Drache, Franziska, et al. "Postsynthetic Inner-Surface Functionalization of the Highly Stable Zirconium-Based Metal-Organic Framework DUT-67." Inorganic chemistry vol. 55,15 (2016): 7206-13. doi: https://doi.org/10.1021/acs.inorgchem.6b00829
Drache F, Bon V, Senkovska I, Marschelke C, Synytska A, Kaskel S. Postsynthetic Inner-Surface Functionalization of the Highly Stable Zirconium-Based Metal-Organic Framework DUT-67. Inorg Chem. 2016 Aug 01;55(15):7206-13. doi: 10.1021/acs.inorgchem.6b00829. Epub 2016 Jul 05. PMID: 27378209.
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Nickel cobalt oxide hollow nanosponges as advanced electrocatalysts for the oxygen evolution reaction.

Chemical communications (Cambridge, England)

Zhu C, Wen D, Leubner S, Oschatz M, Liu W, Holzschuh M, Simon F, Kaskel S, Eychmüller A.
PMID: 25855058
Chem Commun (Camb). 2015 May 07;51(37):7851-4. doi: 10.1039/c5cc01558h.

A class of novel nickel cobalt oxide hollow nanosponges were synthesized through a sodium borohydride reduction strategy. Due to their porous and hollow nanostructures, and synergetic effects between their components, the optimized nickel cobalt oxide nanosponges exhibited excellent catalytic...

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Zhu C, Wen D, Leubner S, et al. Nickel cobalt oxide hollow nanosponges as advanced electrocatalysts for the oxygen evolution reaction. Chem Commun (Camb). 2015;51(37):7851-4doi: 10.1039/c5cc01558h.
Zhu, C., Wen, D., Leubner, S., Oschatz, M., Liu, W., Holzschuh, M., Simon, F., Kaskel, S., & Eychmüller, A. (2015). Nickel cobalt oxide hollow nanosponges as advanced electrocatalysts for the oxygen evolution reaction. Chemical communications (Cambridge, England), 51(37), 7851-4. https://doi.org/10.1039/c5cc01558h
Zhu, Chengzhou, et al. "Nickel cobalt oxide hollow nanosponges as advanced electrocatalysts for the oxygen evolution reaction." Chemical communications (Cambridge, England) vol. 51,37 (2015): 7851-4. doi: https://doi.org/10.1039/c5cc01558h
Zhu C, Wen D, Leubner S, Oschatz M, Liu W, Holzschuh M, Simon F, Kaskel S, Eychmüller A. Nickel cobalt oxide hollow nanosponges as advanced electrocatalysts for the oxygen evolution reaction. Chem Commun (Camb). 2015 May 07;51(37):7851-4. doi: 10.1039/c5cc01558h. PMID: 25855058.
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Polyatomic clusters of the triel elements. Palladium-centered clusters of thallium in A(8)Tl(11)Pd, A = Cs, Rb, K.

Inorganic chemistry

Kaskel S, Klem MT, Corbett JD.
PMID: 12079464
Inorg Chem. 2002 Jul 01;41(13):3457-62. doi: 10.1021/ic020078b.

Reactions of the elements within welded Ta containers at approximately 600 degrees C followed by slow cooling give new A(8)Tl(11)Pd(x) products from an apparently continuous encapsulation of Pd atoms into the pentacapped trigonal prismatic anions in the isotypic rhombohedral...

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Kaskel S, Klem MT, Corbett JD. Polyatomic clusters of the triel elements. Palladium-centered clusters of thallium in A(8)Tl(11)Pd, A = Cs, Rb, K. Inorg Chem. 2002;41(13):3457-62doi: 10.1021/ic020078b.
Kaskel, S., Klem, M. T., & Corbett, J. D. (2002). Polyatomic clusters of the triel elements. Palladium-centered clusters of thallium in A(8)Tl(11)Pd, A = Cs, Rb, K. Inorganic chemistry, 41(13), 3457-62. https://doi.org/10.1021/ic020078b
Kaskel, Stefan, et al. "Polyatomic clusters of the triel elements. Palladium-centered clusters of thallium in A(8)Tl(11)Pd, A = Cs, Rb, K." Inorganic chemistry vol. 41,13 (2002): 3457-62. doi: https://doi.org/10.1021/ic020078b
Kaskel S, Klem MT, Corbett JD. Polyatomic clusters of the triel elements. Palladium-centered clusters of thallium in A(8)Tl(11)Pd, A = Cs, Rb, K. Inorg Chem. 2002 Jul 01;41(13):3457-62. doi: 10.1021/ic020078b. PMID: 12079464.
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New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands.

Inorganic chemistry

Hevia E, Pérez J, Riera V, Miguel D, Kassel S, Rheingold A.
PMID: 12206690
Inorg Chem. 2002 Sep 09;41(18):4673-9. doi: 10.1021/ic020174c.

Triflate abstraction from the complex [Re(OTf)(CO)(3)(bipy)] (1) using the salt NaBAr'(4) (Ar' = 3,5-bis(trifluoromethyl)phenyl) in dichloromethane solution in the presence of L = PPh(3), NCMe, NCPh, imines, ketones, Et(2)O, THF, MeOH, and MeI affords cationic complexes [Re(L)(CO)(3)(bipy)](+) as their...

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Hevia E, Pérez J, Riera V, et al. New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands. Inorg Chem. 2002;41(18):4673-9doi: 10.1021/ic020174c.
Hevia, E., Pérez, J., Riera, V., Miguel, D., Kassel, S., & Rheingold, A. (2002). New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands. Inorganic chemistry, 41(18), 4673-9. https://doi.org/10.1021/ic020174c
Hevia, Eva, et al. "New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands." Inorganic chemistry vol. 41,18 (2002): 4673-9. doi: https://doi.org/10.1021/ic020174c
Hevia E, Pérez J, Riera V, Miguel D, Kassel S, Rheingold A. New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands. Inorg Chem. 2002 Sep 09;41(18):4673-9. doi: 10.1021/ic020174c. PMID: 12206690.
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