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Showing 1 to 12 of 90 entries
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Prolonged Response and Restoration of Functional Independence with Bevacizumab plus Vinorelbine as Third-Line Treatment for Breast Cancer-Related Leptomeningeal Metastases.

Case reports in oncology

Le Rhun E, Taillibert S, Boulanger T, Zairi F, Bonneterre J, Chamberlain MC.
PMID: 25848355
Case Rep Oncol. 2015 Feb 12;8(1):72-7. doi: 10.1159/000375293. eCollection 2015.

BACKGROUND: Survival of patients with leptomeningeal metastases (LM) and impaired functional status is limited to several months, and rarely does neurological function improve with treatment.CASE REPORT: A 34-year-old female with hormone-negative and HER2-positive metastatic breast cancer was diagnosed with...

The future of high-grade glioma: Where we are and where are we going.

Surgical neurology international

Le Rhun E, Rhun EL, Taillibert S, Chamberlain MC.
PMID: 25722939
Surg Neurol Int. 2015 Feb 13;6:S9-S44. doi: 10.4103/2152-7806.151331. eCollection 2015.

High-grade glioma (HGG) are optimally treated with maximum safe surgery, followed by radiotherapy (RT) and/or systemic chemotherapy (CT). Recently, the treatment of newly diagnosed anaplastic glioma (AG) has changed, particularly in patients with 1p19q codeleted tumors. Results of trials...

Mono-phosphacyclopentadienyl bis(tetramethylaluminate) lanthanide complexes.

Dalton transactions (Cambridge, England : 2003)

Le Roux E, Nief F, Jaroschik F, Törnroos KW, Anwander R.
PMID: 17955139
Dalton Trans. 2007 Nov 14;(42):4866-70. doi: 10.1039/b709633j. Epub 2007 Aug 29.

Homoleptic complexes Ln(AlMe(4))(3) (Ln = La, Nd) can be straightforwardly utilized in salt metathetic exchange reactions with potassium 2,3,4,5-tetramethylphospholide (KTmp) or 3,4-dimethyl-2,5-bis(trimethylsilyl)phospholide (KDsp) affording monophosphacyclopentadienyl hydrocarbyl complexes (eta(5)-PC(4)Me(4))Ln(AlMe(4))(2) and [eta(5)-PC(4)Me(2)(SiMe(3))(2)]Ln(AlMe(4))(2) (Ln = La, Nd). The solid-state structures reveal distinct...

Elusive trimethyllanthanum: snapshots of extensive methyl group degradation in la--Al heterobimetallic complexes.

Chemistry (Weinheim an der Bergstrasse, Germany)

Gerber LC, Le Roux E, Törnroos KW, Anwander R.
PMID: 18785663
Chemistry. 2008;14(31):9555-64. doi: 10.1002/chem.200801174.

Reactions of [La(AlMe4)3] and [Y(AlMe4)3] with PMe3 show that the phosphine can cleave Ln--CH3--Al linkages, separating Me3Al(PMe3). PMe3 (3 mol equiv) reacts with [Y(AlMe4)3] to give [(YMe3)n] contaminated with by-products containing phosphorus and aluminum. The La-based analog, [(LaMe3)n], is...

Intramolecular hydroamination/cyclization of aminoalkenes catalyzed by Ln[N(SiMe(3))(2)](3) grafted onto periodic mesoporous silicas.

Journal of the American Chemical Society

Le Roux E, Liang Y, Storz MP, Anwander R.
PMID: 21028823
J Am Chem Soc. 2010 Nov 24;132(46):16368-71. doi: 10.1021/ja107963u. Epub 2010 Oct 28.

Homoleptic rare-earth metal silylamide complexes Ln[N(SiMe(3))(2)](3) (Ln = Y, La, Nd) were grafted onto a series of partially dehydroxylated periodic mesoporous silica (PMS) supports, SBA-15(-500) (d(p) = 7.9 nm), SBA-15LP(-500) (d(p) = 16.6 nm), and MCM-41(-500) (d(p) = 4.1...

Grafting of peralkylated Ln(II)Al(III) heterobimetallic complexes onto periodic mesoporous silica KIT-6.

Dalton transactions (Cambridge, England : 2003)

Le Roux E, Michel O, Sommerfeldt HM, Liang Y, Maichle-Mössmer C, Törnroos KW, Anwander R.
PMID: 20683527
Dalton Trans. 2010 Sep 28;39(36):8552-9. doi: 10.1039/c002734k. Epub 2010 Aug 04.

Tetraethylaluminates of the divalent lanthanides ytterbium and samarium were grafted onto large-pore cubic periodic mesoporous silica (PMS) KIT-6, which had been dehydroxylated at 500 degrees C (specific surface area a(s): 500 m(2)g(-1); mesopore volume V(p): 1.06 cm(3)g(-1); main pore...

[(≡SiO)Ta(V)Cl2Me2]: a well-defined silica-supported tantalum(V) surface complex as catalyst precursor for the selective cocatalyst-free trimerization of ethylene.

Angewandte Chemie (International ed. in English)

Chen Y, Callens E, Abou-Hamad E, Merle N, White AJ, Taoufik M, Copéret C, Le Roux E, Basset JM.
PMID: 23090868
Angew Chem Int Ed Engl. 2012 Nov 19;51(47):11886-9. doi: 10.1002/anie.201206272. Epub 2012 Oct 22.

No abstract available.

Adsorbate Screening of Surface Charge of Microscopic Ferroelectric Domains in Sol-Gel PbZr.

ACS applied materials & interfaces

Copie O, Chevalier N, Le Rhun G, Rountree CL, Martinotti D, Gonzalez S, Mathieu C, Renault O, Barrett N.
PMID: 28776367
ACS Appl Mater Interfaces. 2017 Aug 30;9(34):29311-29317. doi: 10.1021/acsami.7b08925. Epub 2017 Aug 16.

We present a study of adsorbate screening of surface charge in microscopic ferroelectric domains in a sol-gel grown PbZr

Coordination behavior of bis-phenolate saturated and unsaturated N-heterocyclic carbene ligands to zirconium: reactivity and activity in the copolymerization of cyclohexene oxide with CO.

Dalton transactions (Cambridge, England : 2003)

Lalrempuia R, Breivik F, Törnroos KW, Le Roux E.
PMID: 28604887
Dalton Trans. 2017 Jun 27;46(25):8065-8076. doi: 10.1039/c7dt01117b.

Tetravalent zirconium complexes supported by tridentate bis-phenolate imidazolidin-2-ylidene (L1), imidazol-2-ylidene (L2) and benzimidazol-2-ylidene (L3) NHC ligands were synthesized and evaluated as precursors for the copolymerization of cyclohexene oxide (CHO) with CO

Feeding disorders in children with oesophageal atresia: a cross-sectional study.

Archives of disease in childhood

Pham A, Ecochard-Dugelay E, Bonnard A, Le Roux E, Gelas T, Rousseau V, Thomassin N, Cabon-Boudard I, Nicolas A, Guinot A, Rebeuh J, Le Mandat A, Djeddi DD, Fouquet V, Boucharny A, Irtan S, Lemale J, Comte A, Bridoux-Henno L, Dupont-Lucas C, Dimitrov G, Turquet A, Borderon C, Pelatan C, Chaillou Legault E, Jung C, Willot S, Montalva L, Mitanchez D, Gottrand F, Bellaiche M.
PMID: 33863700
Arch Dis Child. 2022 Jan;107(1):52-58. doi: 10.1136/archdischild-2020-320609. Epub 2021 Apr 16.

INTRODUCTION: With advances in surgical and neonatal care, the survival of patients with oesophageal atresia (OA) has improved over time. Whereas a number of OA-related conditions (delayed primary anastomosis, anastomotic stricture and oesophageal dysmotility) may have an impact on...

Feeding disorders in children with oesophageal atresia: a cross-sectional study.

Archives of disease in childhood

Pham A, Ecochard-Dugelay E, Bonnard A, Le Roux E, Gelas T, Rousseau V, Thomassin N, Cabon-Boudard I, Nicolas A, Guinot A, Rebeuh J, Le Mandat A, Djeddi DD, Fouquet V, Boucharny A, Irtan S, Lemale J, Comte A, Bridoux-Henno L, Dupont-Lucas C, Dimitrov G, Turquet A, Borderon C, Pelatan C, Chaillou Legault E, Jung C, Willot S, Montalva L, Mitanchez D, Gottrand F, Bellaiche M.
PMID: 33863700
Arch Dis Child. 2022 Jan;107(1):52-58. doi: 10.1136/archdischild-2020-320609. Epub 2021 Apr 16.

INTRODUCTION: With advances in surgical and neonatal care, the survival of patients with oesophageal atresia (OA) has improved over time. Whereas a number of OA-related conditions (delayed primary anastomosis, anastomotic stricture and oesophageal dysmotility) may have an impact on...

Neuropathic Pain in Children with Sickle Cell Disease: The Hidden Side of the Vaso-Occlusive Crisis.

Children (Basel, Switzerland)

Sigalla J, Duparc Alegria N, Le Roux E, Toumazi A, Thiollier AF, Holvoet L, Benkerrou M, Dugue S, Koehl B.
PMID: 33530318
Children (Basel). 2021 Jan 26;8(2). doi: 10.3390/children8020084.

The majority of hospitalizations of patients with sickle cell disease (SCD) are related to painful vaso-occlusive crises (VOCs). Although the pain of VOC is classically nociceptive, neuropathic pain (NP) has also been demonstrated in SCD patients. The aim of...

Showing 1 to 12 of 90 entries