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The Nuclearity of the Active Site for Methane to Methanol Conversion in Cu-Mordenite: A Quantitative Assessment.

Journal of the American Chemical Society

Pappas DK, Martini A, Dyballa M, Kvande K, Teketel S, Lomachenko KA, Baran R, Glatzel P, Arstad B, Berlier G, Lamberti C, Bordiga S, Olsbye U, Svelle S, Beato P, Borfecchia E.
PMID: 30346154
J Am Chem Soc. 2018 Nov 14;140(45):15270-15278. doi: 10.1021/jacs.8b08071. Epub 2018 Nov 02.

The direct conversion of methane to methanol (MTM) is a reaction that has the potential to disrupt a great part of the synthesis gas-derived chemical industry. However, despite many decades of research, active enough catalysts and suitable processes for...

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Pappas DK, Martini A, Dyballa M, et al. The Nuclearity of the Active Site for Methane to Methanol Conversion in Cu-Mordenite: A Quantitative Assessment. J Am Chem Soc. 2018;140(45):15270-15278doi: 10.1021/jacs.8b08071.
Pappas, D. K., Martini, A., Dyballa, M., Kvande, K., Teketel, S., Lomachenko, K. A., Baran, R., Glatzel, P., Arstad, B., Berlier, G., Lamberti, C., Bordiga, S., Olsbye, U., Svelle, S., Beato, P., & Borfecchia, E. (2018). The Nuclearity of the Active Site for Methane to Methanol Conversion in Cu-Mordenite: A Quantitative Assessment. Journal of the American Chemical Society, 140(45), 15270-15278. https://doi.org/10.1021/jacs.8b08071
Pappas, Dimitrios K, et al. "The Nuclearity of the Active Site for Methane to Methanol Conversion in Cu-Mordenite: A Quantitative Assessment." Journal of the American Chemical Society vol. 140,45 (2018): 15270-15278. doi: https://doi.org/10.1021/jacs.8b08071
Pappas DK, Martini A, Dyballa M, Kvande K, Teketel S, Lomachenko KA, Baran R, Glatzel P, Arstad B, Berlier G, Lamberti C, Bordiga S, Olsbye U, Svelle S, Beato P, Borfecchia E. The Nuclearity of the Active Site for Methane to Methanol Conversion in Cu-Mordenite: A Quantitative Assessment. J Am Chem Soc. 2018 Nov 14;140(45):15270-15278. doi: 10.1021/jacs.8b08071. Epub 2018 Nov 02. PMID: 30346154.
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Reversible Capture and Release of Cl.

Journal of the American Chemical Society

Tulchinsky Y, Hendon CH, Lomachenko KA, Borfecchia E, Melot BC, Hudson MR, Tarver JD, Korzyński MD, Stubbs AW, Kagan JJ, Lamberti C, Brown CM, Dincă M.
PMID: 28347141
J Am Chem Soc. 2017 Apr 26;139(16):5992-5997. doi: 10.1021/jacs.7b02161. Epub 2017 Apr 14.

Extreme toxicity, corrosiveness, and volatility pose serious challenges for the safe storage and transportation of elemental chlorine and bromine, which play critical roles in the chemical industry. Solid materials capable of forming stable nonvolatile compounds upon reaction with elemental...

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Tulchinsky Y, Hendon CH, Lomachenko KA, et al. Reversible Capture and Release of Cl. J Am Chem Soc. 2017;139(16):5992-5997doi: 10.1021/jacs.7b02161.
Tulchinsky, Y., Hendon, C. H., Lomachenko, K. A., Borfecchia, E., Melot, B. C., Hudson, M. R., Tarver, J. D., Korzyński, M. D., Stubbs, A. W., Kagan, J. J., Lamberti, C., Brown, C. M., & Dincă, M. (2017). Reversible Capture and Release of Cl. Journal of the American Chemical Society, 139(16), 5992-5997. https://doi.org/10.1021/jacs.7b02161
Tulchinsky, Yuri, et al. "Reversible Capture and Release of Cl." Journal of the American Chemical Society vol. 139,16 (2017): 5992-5997. doi: https://doi.org/10.1021/jacs.7b02161
Tulchinsky Y, Hendon CH, Lomachenko KA, Borfecchia E, Melot BC, Hudson MR, Tarver JD, Korzyński MD, Stubbs AW, Kagan JJ, Lamberti C, Brown CM, Dincă M. Reversible Capture and Release of Cl. J Am Chem Soc. 2017 Apr 26;139(16):5992-5997. doi: 10.1021/jacs.7b02161. Epub 2017 Apr 14. PMID: 28347141.
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Exact Stoichiometry of Ce .

Journal of the American Chemical Society

Lomachenko KA, Jacobsen J, Bugaev AL, Atzori C, Bonino F, Bordiga S, Stock N, Lamberti C.
PMID: 30497258
J Am Chem Soc. 2018 Dec 19;140(50):17379-17383. doi: 10.1021/jacs.8b10343. Epub 2018 Dec 07.

Bimetallic Ce/Zr-UiO-66 metal-organic frameworks (MOFs) proved to be promising materials for various catalytic redox applications, representing, together with other bimetallic MOFs, a new generation of porous structures. However, no direct proof for the presence of both metals in a...

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Lomachenko KA, Jacobsen J, Bugaev AL, et al. Exact Stoichiometry of Ce . J Am Chem Soc. 2018;140(50):17379-17383doi: 10.1021/jacs.8b10343.
Lomachenko, K. A., Jacobsen, J., Bugaev, A. L., Atzori, C., Bonino, F., Bordiga, S., Stock, N., & Lamberti, C. (2018). Exact Stoichiometry of Ce . Journal of the American Chemical Society, 140(50), 17379-17383. https://doi.org/10.1021/jacs.8b10343
Lomachenko, Kirill A, et al. "Exact Stoichiometry of Ce ." Journal of the American Chemical Society vol. 140,50 (2018): 17379-17383. doi: https://doi.org/10.1021/jacs.8b10343
Lomachenko KA, Jacobsen J, Bugaev AL, Atzori C, Bonino F, Bordiga S, Stock N, Lamberti C. Exact Stoichiometry of Ce . J Am Chem Soc. 2018 Dec 19;140(50):17379-17383. doi: 10.1021/jacs.8b10343. Epub 2018 Dec 07. PMID: 30497258.
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A Titanium(IV)-Based Metal-Organic Framework Featuring Defect-Rich Ti-O Sheets as an Oxidative Desulfurization Catalyst.

Angewandte Chemie (International ed. in English)

Smolders S, Willhammar T, Krajnc A, Sentosun K, Wharmby MT, Lomachenko KA, Bals S, Mali G, Roeffaers MBJ, De Vos DE, Bueken B.
PMID: 31059170
Angew Chem Int Ed Engl. 2019 Jul 01;58(27):9160-9165. doi: 10.1002/anie.201904347. Epub 2019 May 27.

While titanium-based metal-organic frameworks (MOFs) have been widely studied for their (photo)catalytic potential, only a few Ti

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Smolders S, Willhammar T, Krajnc A, et al. A Titanium(IV)-Based Metal-Organic Framework Featuring Defect-Rich Ti-O Sheets as an Oxidative Desulfurization Catalyst. Angew Chem Int Ed Engl. 2019;58(27):9160-9165doi: 10.1002/anie.201904347.
Smolders, S., Willhammar, T., Krajnc, A., Sentosun, K., Wharmby, M. T., Lomachenko, K. A., Bals, S., Mali, G., Roeffaers, M. B. J., De Vos, D. E., & Bueken, B. (2019). A Titanium(IV)-Based Metal-Organic Framework Featuring Defect-Rich Ti-O Sheets as an Oxidative Desulfurization Catalyst. Angewandte Chemie (International ed. in English), 58(27), 9160-9165. https://doi.org/10.1002/anie.201904347
Smolders, Simon, et al. "A Titanium(IV)-Based Metal-Organic Framework Featuring Defect-Rich Ti-O Sheets as an Oxidative Desulfurization Catalyst." Angewandte Chemie (International ed. in English) vol. 58,27 (2019): 9160-9165. doi: https://doi.org/10.1002/anie.201904347
Smolders S, Willhammar T, Krajnc A, Sentosun K, Wharmby MT, Lomachenko KA, Bals S, Mali G, Roeffaers MBJ, De Vos DE, Bueken B. A Titanium(IV)-Based Metal-Organic Framework Featuring Defect-Rich Ti-O Sheets as an Oxidative Desulfurization Catalyst. Angew Chem Int Ed Engl. 2019 Jul 01;58(27):9160-9165. doi: 10.1002/anie.201904347. Epub 2019 May 27. PMID: 31059170.
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Bimetallic hexanuclear clusters in Ce/Zr-UiO-66 MOFs: in situ FTIR spectroscopy and modelling insights.

Dalton transactions (Cambridge, England : 2003)

Atzori C, Lomachenko KA, Jacobsen J, Stock N, Damin A, Bonino F, Bordiga S.
PMID: 32315376
Dalton Trans. 2020 May 14;49(18):5794-5797. doi: 10.1039/d0dt01023e. Epub 2020 Apr 21.

In situ FTIR spectroscopy in combination with results from DFT calculations was used to determine the composition of mixed-metal clusters {Ce

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Atzori C, Lomachenko KA, Jacobsen J, et al. Bimetallic hexanuclear clusters in Ce/Zr-UiO-66 MOFs: in situ FTIR spectroscopy and modelling insights. Dalton Trans. 2020;49(18):5794-5797doi: 10.1039/d0dt01023e.
Atzori, C., Lomachenko, K. A., Jacobsen, J., Stock, N., Damin, A., Bonino, F., & Bordiga, S. (2020). Bimetallic hexanuclear clusters in Ce/Zr-UiO-66 MOFs: in situ FTIR spectroscopy and modelling insights. Dalton transactions (Cambridge, England : 2003), 49(18), 5794-5797. https://doi.org/10.1039/d0dt01023e
Atzori, Cesare, et al. "Bimetallic hexanuclear clusters in Ce/Zr-UiO-66 MOFs: in situ FTIR spectroscopy and modelling insights." Dalton transactions (Cambridge, England : 2003) vol. 49,18 (2020): 5794-5797. doi: https://doi.org/10.1039/d0dt01023e
Atzori C, Lomachenko KA, Jacobsen J, Stock N, Damin A, Bonino F, Bordiga S. Bimetallic hexanuclear clusters in Ce/Zr-UiO-66 MOFs: in situ FTIR spectroscopy and modelling insights. Dalton Trans. 2020 May 14;49(18):5794-5797. doi: 10.1039/d0dt01023e. Epub 2020 Apr 21. PMID: 32315376.
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High energy resolution core-level X-ray spectroscopy for electronic and structural characterization of osmium compounds.

Physical chemistry chemical physics : PCCP

Lomachenko KA, Garino C, Gallo E, Gianolio D, Gobetto R, Glatzel P, Smolentsev N, Smolentsev G, Soldatov AV, Lamberti C, Salassa L.
PMID: 23986116
Phys Chem Chem Phys. 2013 Oct 14;15(38):16152-9. doi: 10.1039/c3cp51880a. Epub 2013 Aug 29.

A comprehensive study of the bulk solid OsCl3 and the molecular ion [Os(bpy)2(CO)Cl](+) is presented illustrating the application of RIXS and HERFD XANES spectroscopies to the investigation of both bulk materials and molecular complexes. In order to analyze the...

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Lomachenko KA, Garino C, Gallo E, et al. High energy resolution core-level X-ray spectroscopy for electronic and structural characterization of osmium compounds. Phys Chem Chem Phys. 2013;15(38):16152-9doi: 10.1039/c3cp51880a.
Lomachenko, K. A., Garino, C., Gallo, E., Gianolio, D., Gobetto, R., Glatzel, P., Smolentsev, N., Smolentsev, G., Soldatov, A. V., Lamberti, C., & Salassa, L. (2013). High energy resolution core-level X-ray spectroscopy for electronic and structural characterization of osmium compounds. Physical chemistry chemical physics : PCCP, 15(38), 16152-9. https://doi.org/10.1039/c3cp51880a
Lomachenko, Kirill A, et al. "High energy resolution core-level X-ray spectroscopy for electronic and structural characterization of osmium compounds." Physical chemistry chemical physics : PCCP vol. 15,38 (2013): 16152-9. doi: https://doi.org/10.1039/c3cp51880a
Lomachenko KA, Garino C, Gallo E, Gianolio D, Gobetto R, Glatzel P, Smolentsev N, Smolentsev G, Soldatov AV, Lamberti C, Salassa L. High energy resolution core-level X-ray spectroscopy for electronic and structural characterization of osmium compounds. Phys Chem Chem Phys. 2013 Oct 14;15(38):16152-9. doi: 10.1039/c3cp51880a. Epub 2013 Aug 29. PMID: 23986116.
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Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction.

Chemical science

Borfecchia E, Lomachenko KA, Giordanino F, Falsig H, Beato P, Soldatov AV, Bordiga S, Lamberti C.
PMID: 28936309
Chem Sci. 2015 Jan 01;6(1):548-563. doi: 10.1039/c4sc02907k. Epub 2014 Oct 13.

Cu-SSZ-13 is a highly active NH

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Borfecchia E, Lomachenko KA, Giordanino F, et al. Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction. Chem Sci. 2014;6(1):548-563doi: 10.1039/c4sc02907k.
Borfecchia, E., Lomachenko, K. A., Giordanino, F., Falsig, H., Beato, P., Soldatov, A. V., Bordiga, S., & Lamberti, C. (2015). Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction. Chemical science, 6(1), 548-563. https://doi.org/10.1039/c4sc02907k
Borfecchia, E, et al. "Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction." Chemical science vol. 6,1 (2015): 548-563. doi: https://doi.org/10.1039/c4sc02907k
Borfecchia E, Lomachenko KA, Giordanino F, Falsig H, Beato P, Soldatov AV, Bordiga S, Lamberti C. Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction. Chem Sci. 2015 Jan 01;6(1):548-563. doi: 10.1039/c4sc02907k. Epub 2014 Oct 13. PMID: 28936309; PMCID: PMC5588737.
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Photoactivated Osmium Arene Anticancer Complexes.

Inorganic chemistry

Xue X, Fu Y, He L, Salassa L, He LF, Hao YY, Koh MJ, Soulié C, Needham RJ, Habtemariam A, Garino C, Lomachenko KA, Su Z, Qian Y, Paterson MJ, Mao ZW, Liu HK, Sadler PJ.
PMID: 34503331
Inorg Chem. 2021 Dec 06;60(23):17450-17461. doi: 10.1021/acs.inorgchem.1c00241. Epub 2021 Sep 09.

Half-sandwich Os-arene complexes exhibit promising anticancer activity, but their photochemistry has hardly been explored. To exploit the photocytotoxicity and photochemistry of Os-arenes,

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Xue X, Fu Y, He L, et al. Photoactivated Osmium Arene Anticancer Complexes. Inorg Chem. 2021;60(23):17450-17461doi: 10.1021/acs.inorgchem.1c00241.
Xue, X., Fu, Y., He, L., Salassa, L., He, L. F., Hao, Y. Y., Koh, M. J., Soulié, C., Needham, R. J., Habtemariam, A., Garino, C., Lomachenko, K. A., Su, Z., Qian, Y., Paterson, M. J., Mao, Z. W., Liu, H. K., & Sadler, P. J. (2021). Photoactivated Osmium Arene Anticancer Complexes. Inorganic chemistry, 60(23), 17450-17461. https://doi.org/10.1021/acs.inorgchem.1c00241
Xue, Xuling, et al. "Photoactivated Osmium Arene Anticancer Complexes." Inorganic chemistry vol. 60,23 (2021): 17450-17461. doi: https://doi.org/10.1021/acs.inorgchem.1c00241
Xue X, Fu Y, He L, Salassa L, He LF, Hao YY, Koh MJ, Soulié C, Needham RJ, Habtemariam A, Garino C, Lomachenko KA, Su Z, Qian Y, Paterson MJ, Mao ZW, Liu HK, Sadler PJ. Photoactivated Osmium Arene Anticancer Complexes. Inorg Chem. 2021 Dec 06;60(23):17450-17461. doi: 10.1021/acs.inorgchem.1c00241. Epub 2021 Sep 09. PMID: 34503331.
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Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts.

Physical chemistry chemical physics : PCCP

Negri C, Martini A, Deplano G, Lomachenko KA, Janssens TVW, Borfecchia E, Berlier G, Bordiga S.
PMID: 34612374
Phys Chem Chem Phys. 2021 Sep 14;23(34):18322-18337. doi: 10.1039/d1cp01754c. Epub 2021 Aug 17.

The speciation of framework-interacting Cu

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Negri C, Martini A, Deplano G, et al. Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts. Phys Chem Chem Phys. 2021;23(34):18322-18337doi: 10.1039/d1cp01754c.
Negri, C., Martini, A., Deplano, G., Lomachenko, K. A., Janssens, T. V. W., Borfecchia, E., Berlier, G., & Bordiga, S. (2021). Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts. Physical chemistry chemical physics : PCCP, 23(34), 18322-18337. https://doi.org/10.1039/d1cp01754c
Negri, Chiara, et al. "Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts." Physical chemistry chemical physics : PCCP vol. 23,34 (2021): 18322-18337. doi: https://doi.org/10.1039/d1cp01754c
Negri C, Martini A, Deplano G, Lomachenko KA, Janssens TVW, Borfecchia E, Berlier G, Bordiga S. Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts. Phys Chem Chem Phys. 2021 Sep 14;23(34):18322-18337. doi: 10.1039/d1cp01754c. Epub 2021 Aug 17. PMID: 34612374; PMCID: PMC8409503.
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Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH.

Journal of the American Chemical Society

Negri C, Selleri T, Borfecchia E, Martini A, Lomachenko KA, Janssens TVW, Cutini M, Bordiga S, Berlier G.
PMID: 32830975
J Am Chem Soc. 2020 Sep 16;142(37):15884-15896. doi: 10.1021/jacs.0c06270. Epub 2020 Sep 03.

The NH

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Negri C, Selleri T, Borfecchia E, et al. Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH. J Am Chem Soc. 2020;142(37):15884-15896doi: 10.1021/jacs.0c06270.
Negri, C., Selleri, T., Borfecchia, E., Martini, A., Lomachenko, K. A., Janssens, T. V. W., Cutini, M., Bordiga, S., & Berlier, G. (2020). Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH. Journal of the American Chemical Society, 142(37), 15884-15896. https://doi.org/10.1021/jacs.0c06270
Negri, Chiara, et al. "Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH." Journal of the American Chemical Society vol. 142,37 (2020): 15884-15896. doi: https://doi.org/10.1021/jacs.0c06270
Negri C, Selleri T, Borfecchia E, Martini A, Lomachenko KA, Janssens TVW, Cutini M, Bordiga S, Berlier G. Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH. J Am Chem Soc. 2020 Sep 16;142(37):15884-15896. doi: 10.1021/jacs.0c06270. Epub 2020 Sep 03. PMID: 32830975; PMCID: PMC8011910.
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Interaction of NH3 with Cu-SSZ-13 Catalyst: A Complementary FTIR, XANES, and XES Study.

The journal of physical chemistry letters

Giordanino F, Borfecchia E, Lomachenko KA, Lazzarini A, Agostini G, Gallo E, Soldatov AV, Beato P, Bordiga S, Lamberti C.
PMID: 26270095
J Phys Chem Lett. 2014 May 01;5(9):1552-9. doi: 10.1021/jz500241m. Epub 2014 Apr 15.

In the typical NH3-SCR temperature range (100-500 °C), ammonia is one of the main adsorbed species on acidic sites of Cu-SSZ-13 catalyst. Therefore, the study of adsorbed ammonia at high temperature is a key step for the understanding of...

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Giordanino F, Borfecchia E, Lomachenko KA, et al. Interaction of NH3 with Cu-SSZ-13 Catalyst: A Complementary FTIR, XANES, and XES Study. J Phys Chem Lett. 2014;5(9):1552-9doi: 10.1021/jz500241m.
Giordanino, F., Borfecchia, E., Lomachenko, K. A., Lazzarini, A., Agostini, G., Gallo, E., Soldatov, A. V., Beato, P., Bordiga, S., & Lamberti, C. (2014). Interaction of NH3 with Cu-SSZ-13 Catalyst: A Complementary FTIR, XANES, and XES Study. The journal of physical chemistry letters, 5(9), 1552-9. https://doi.org/10.1021/jz500241m
Giordanino, Filippo, et al. "Interaction of NH3 with Cu-SSZ-13 Catalyst: A Complementary FTIR, XANES, and XES Study." The journal of physical chemistry letters vol. 5,9 (2014): 1552-9. doi: https://doi.org/10.1021/jz500241m
Giordanino F, Borfecchia E, Lomachenko KA, Lazzarini A, Agostini G, Gallo E, Soldatov AV, Beato P, Bordiga S, Lamberti C. Interaction of NH3 with Cu-SSZ-13 Catalyst: A Complementary FTIR, XANES, and XES Study. J Phys Chem Lett. 2014 May 01;5(9):1552-9. doi: 10.1021/jz500241m. Epub 2014 Apr 15. PMID: 26270095.
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Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity.

Chemical communications (Cambridge, England)

Lammert M, Wharmby MT, Smolders S, Bueken B, Lieb A, Lomachenko KA, Vos DD, Stock N.
PMID: 26154160
Chem Commun (Camb). 2015 Aug 14;51(63):12578-81. doi: 10.1039/c5cc02606g.

A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO...

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Lammert M, Wharmby MT, Smolders S, et al. Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity. Chem Commun (Camb). 2015;51(63):12578-81doi: 10.1039/c5cc02606g.
Lammert, M., Wharmby, M. T., Smolders, S., Bueken, B., Lieb, A., Lomachenko, K. A., Vos, D. D., & Stock, N. (2015). Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity. Chemical communications (Cambridge, England), 51(63), 12578-81. https://doi.org/10.1039/c5cc02606g
Lammert, Martin, et al. "Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity." Chemical communications (Cambridge, England) vol. 51,63 (2015): 12578-81. doi: https://doi.org/10.1039/c5cc02606g
Lammert M, Wharmby MT, Smolders S, Bueken B, Lieb A, Lomachenko KA, Vos DD, Stock N. Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity. Chem Commun (Camb). 2015 Aug 14;51(63):12578-81. doi: 10.1039/c5cc02606g. PMID: 26154160.
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Showing 1 to 12 of 27 entries