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Relationship between Platelet PPARs, cAMP Levels, and P-Selectin Expression: Antiplatelet Activity of Natural Products.

Evidence-based complementary and alternative medicine : eCAM

Fuentes E, Palomo I.
PMID: 24324520
Evid Based Complement Alternat Med. 2013;2013:861786. doi: 10.1155/2013/861786. Epub 2013 Nov 13.

Platelets are no longer considered simply as cells participating in thrombosis. In atherosclerosis, platelets are regulators of multiple processes, with the recruitment of inflammatory cells towards the lesion sites, inflammatory mediators release, and regulation of endothelial function. The antiplatelet...

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Fuentes E, Palomo I. Relationship between Platelet PPARs, cAMP Levels, and P-Selectin Expression: Antiplatelet Activity of Natural Products. Evid Based Complement Alternat Med. 2013;2013:861786doi: 10.1155/2013/861786.
Fuentes, E., & Palomo, I. (2013). Relationship between Platelet PPARs, cAMP Levels, and P-Selectin Expression: Antiplatelet Activity of Natural Products. Evidence-based complementary and alternative medicine : eCAM, 2013861786. https://doi.org/10.1155/2013/861786
Fuentes, Eduardo, and Palomo, Iván. "Relationship between Platelet PPARs, cAMP Levels, and P-Selectin Expression: Antiplatelet Activity of Natural Products." Evidence-based complementary and alternative medicine : eCAM vol. 2013 (2013): 861786. doi: https://doi.org/10.1155/2013/861786
Fuentes E, Palomo I. Relationship between Platelet PPARs, cAMP Levels, and P-Selectin Expression: Antiplatelet Activity of Natural Products. Evid Based Complement Alternat Med. 2013;2013:861786. doi: 10.1155/2013/861786. Epub 2013 Nov 13. PMID: 24324520; PMCID: PMC3845334.
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A comparison of screening batteries in the detection of neurocognitive impairment in HIV-infected Spanish speakers.

Neurobehavioral HIV medicine

Levine AJ, Palomo M, Hinkin CH, Valdes-Sueiras M, Lopez E, Mathisen G, Donovan S, Singer EJ.
PMID: 26448691
Neurobehav HIV Med. 2011;3:79-86. doi: 10.2147/NBHIV.S22553.

BACKGROUND: A substantial number of Spanish-speaking individuals from Mexico and Central America are now living in the United States. These individuals are at heightened risk for HIV infection and, due to late diagnosis and limited resources, for HIV-associated neurocognitive...

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Levine AJ, Palomo M, Hinkin CH, et al. A comparison of screening batteries in the detection of neurocognitive impairment in HIV-infected Spanish speakers. Neurobehav HIV Med. 2011;3:79-86doi: 10.2147/NBHIV.S22553.
Levine, A. J., Palomo, M., Hinkin, C. H., Valdes-Sueiras, M., Lopez, E., Mathisen, G., Donovan, S., & Singer, E. J. (2011). A comparison of screening batteries in the detection of neurocognitive impairment in HIV-infected Spanish speakers. Neurobehavioral HIV medicine, 379-86. https://doi.org/10.2147/NBHIV.S22553
Levine, Andrew J, et al. "A comparison of screening batteries in the detection of neurocognitive impairment in HIV-infected Spanish speakers." Neurobehavioral HIV medicine vol. 3 (2011): 79-86. doi: https://doi.org/10.2147/NBHIV.S22553
Levine AJ, Palomo M, Hinkin CH, Valdes-Sueiras M, Lopez E, Mathisen G, Donovan S, Singer EJ. A comparison of screening batteries in the detection of neurocognitive impairment in HIV-infected Spanish speakers. Neurobehav HIV Med. 2011;3:79-86. doi: 10.2147/NBHIV.S22553. PMID: 26448691; PMCID: PMC4593057.
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Bifunctional Brønsted Base Catalyzes Direct Asymmetric Aldol Reaction of α-Keto Amides.

Angewandte Chemie (International ed. in English)

Echave H, López R, Palomo C.
PMID: 26835655
Angew Chem Int Ed Engl. 2016 Mar 01;55(10):3364-8. doi: 10.1002/anie.201510482. Epub 2016 Feb 02.

The first enantioselective direct cross-aldol reaction of α-keto amides with aldehydes, mediated by a bifunctional ureidopeptide-based Brønsted base catalyst, is described. The appropriate combination of a tertiary amine base and an aminal, and urea hydrogen-bond donor groups in the...

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Echave H, López R, Palomo C. Bifunctional Brønsted Base Catalyzes Direct Asymmetric Aldol Reaction of α-Keto Amides. Angew Chem Int Ed Engl. 2016;55(10):3364-8doi: 10.1002/anie.201510482.
Echave, H., López, R., & Palomo, C. (2016). Bifunctional Brønsted Base Catalyzes Direct Asymmetric Aldol Reaction of α-Keto Amides. Angewandte Chemie (International ed. in English), 55(10), 3364-8. https://doi.org/10.1002/anie.201510482
Echave, Haizea, et al. "Bifunctional Brønsted Base Catalyzes Direct Asymmetric Aldol Reaction of α-Keto Amides." Angewandte Chemie (International ed. in English) vol. 55,10 (2016): 3364-8. doi: https://doi.org/10.1002/anie.201510482
Echave H, López R, Palomo C. Bifunctional Brønsted Base Catalyzes Direct Asymmetric Aldol Reaction of α-Keto Amides. Angew Chem Int Ed Engl. 2016 Mar 01;55(10):3364-8. doi: 10.1002/anie.201510482. Epub 2016 Feb 02. PMID: 26835655.
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Generation of Threonine- and Azathreonine N-Carboxy Anhydrides from alpha-Hydroxy beta-Lactams Promoted by 2,2,6,6-Tetramethylpiperidinyl-1-oxyl (TEMPO) in Combination with Sodium Hypochlorite.

The Journal of organic chemistry

Palomo C, Aizpurua JM, Cuevas C, Urchegui R, Linden A.
PMID: 11667344
J Org Chem. 1996 Jun 26;61(13):4400-4404. doi: 10.1021/jo952178n.

A versatile one-pot oxidation-Baeyer-Villiger reaction sequence applied to alpha-hydroxy beta-lactams and promoted by 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) leads to alpha-amino acid N-carboxy anhydrides. The examples reported constitute the first application of TEMPO in a Baeyer-Villiger reaction and provide a way for...

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Palomo C, Aizpurua JM, Cuevas C, et al. Generation of Threonine- and Azathreonine N-Carboxy Anhydrides from alpha-Hydroxy beta-Lactams Promoted by 2,2,6,6-Tetramethylpiperidinyl-1-oxyl (TEMPO) in Combination with Sodium Hypochlorite. J Org Chem. 1996;61(13):4400-4404doi: 10.1021/jo952178n.
Palomo, C., Aizpurua, J. M., Cuevas, C., Urchegui, R., & Linden, A. (1996). Generation of Threonine- and Azathreonine N-Carboxy Anhydrides from alpha-Hydroxy beta-Lactams Promoted by 2,2,6,6-Tetramethylpiperidinyl-1-oxyl (TEMPO) in Combination with Sodium Hypochlorite. The Journal of organic chemistry, 61(13), 4400-4404. https://doi.org/10.1021/jo952178n
Palomo, Claudio, et al. "Generation of Threonine- and Azathreonine N-Carboxy Anhydrides from alpha-Hydroxy beta-Lactams Promoted by 2,2,6,6-Tetramethylpiperidinyl-1-oxyl (TEMPO) in Combination with Sodium Hypochlorite." The Journal of organic chemistry vol. 61,13 (1996): 4400-4404. doi: https://doi.org/10.1021/jo952178n
Palomo C, Aizpurua JM, Cuevas C, Urchegui R, Linden A. Generation of Threonine- and Azathreonine N-Carboxy Anhydrides from alpha-Hydroxy beta-Lactams Promoted by 2,2,6,6-Tetramethylpiperidinyl-1-oxyl (TEMPO) in Combination with Sodium Hypochlorite. J Org Chem. 1996 Jun 26;61(13):4400-4404. doi: 10.1021/jo952178n. PMID: 11667344.
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A chiral acrylate equivalent for metal-free Diels-Alder reactions: endo-2-acryloylisoborneol.

Journal of the American Chemical Society

Palomo C, Oiarbide M, García JM, González A, Lecumberri A, Linden A.
PMID: 12197725
J Am Chem Soc. 2002 Sep 04;124(35):10288-9. doi: 10.1021/ja025906e.

The principle of metal-free activation of enones toward the Diels-Alder reaction with dienes is demonstrated by exploiting the capability of Brønsted acids to activate alpha'-hydroxyenones through hydrogen bonding. The diastereoselective application of such a principle is nicely realized by...

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Palomo C, Oiarbide M, García JM, et al. A chiral acrylate equivalent for metal-free Diels-Alder reactions: endo-2-acryloylisoborneol. J Am Chem Soc. 2002;124(35):10288-9doi: 10.1021/ja025906e.
Palomo, C., Oiarbide, M., García, J. M., González, A., Lecumberri, A., & Linden, A. (2002). A chiral acrylate equivalent for metal-free Diels-Alder reactions: endo-2-acryloylisoborneol. Journal of the American Chemical Society, 124(35), 10288-9. https://doi.org/10.1021/ja025906e
Palomo, Claudio, et al. "A chiral acrylate equivalent for metal-free Diels-Alder reactions: endo-2-acryloylisoborneol." Journal of the American Chemical Society vol. 124,35 (2002): 10288-9. doi: https://doi.org/10.1021/ja025906e
Palomo C, Oiarbide M, García JM, González A, Lecumberri A, Linden A. A chiral acrylate equivalent for metal-free Diels-Alder reactions: endo-2-acryloylisoborneol. J Am Chem Soc. 2002 Sep 04;124(35):10288-9. doi: 10.1021/ja025906e. PMID: 12197725.
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Practical Synthesis of alpha-Amino Acid N-Carboxy Anhydrides of Polyhydroxylated alpha-Amino Acids from beta-Lactam Frameworks. Model Studies toward the Synthesis of Directly Linked Peptidyl Nucleoside Antibiotics.

The Journal of organic chemistry

Palomo C, Oiarbide M, Esnal A, Landa A, Miranda JI, Linden A.
PMID: 11672185
J Org Chem. 1998 Aug 21;63(17):5838-5846. doi: 10.1021/jo980354x.

A straightforward method for the synthesis of polyhydroxylated alpha-amino acid N-carboxy anhydrides (NCAs) is described as the means by which short peptide segments comprised of a polyhydroxylated chain are easily affordable. The entire sequence lies in the preparation of...

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Palomo C, Oiarbide M, Esnal A, et al. Practical Synthesis of alpha-Amino Acid N-Carboxy Anhydrides of Polyhydroxylated alpha-Amino Acids from beta-Lactam Frameworks. Model Studies toward the Synthesis of Directly Linked Peptidyl Nucleoside Antibiotics. J Org Chem. 1998;63(17):5838-5846doi: 10.1021/jo980354x.
Palomo, C., Oiarbide, M., Esnal, A., Landa, A., Miranda, J. I., & Linden, A. (1998). Practical Synthesis of alpha-Amino Acid N-Carboxy Anhydrides of Polyhydroxylated alpha-Amino Acids from beta-Lactam Frameworks. Model Studies toward the Synthesis of Directly Linked Peptidyl Nucleoside Antibiotics. The Journal of organic chemistry, 63(17), 5838-5846. https://doi.org/10.1021/jo980354x
Palomo, Claudio, et al. "Practical Synthesis of alpha-Amino Acid N-Carboxy Anhydrides of Polyhydroxylated alpha-Amino Acids from beta-Lactam Frameworks. Model Studies toward the Synthesis of Directly Linked Peptidyl Nucleoside Antibiotics." The Journal of organic chemistry vol. 63,17 (1998): 5838-5846. doi: https://doi.org/10.1021/jo980354x
Palomo C, Oiarbide M, Esnal A, Landa A, Miranda JI, Linden A. Practical Synthesis of alpha-Amino Acid N-Carboxy Anhydrides of Polyhydroxylated alpha-Amino Acids from beta-Lactam Frameworks. Model Studies toward the Synthesis of Directly Linked Peptidyl Nucleoside Antibiotics. J Org Chem. 1998 Aug 21;63(17):5838-5846. doi: 10.1021/jo980354x. PMID: 11672185.
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Alkylation of chiral alpha-hydroxy ketones derived from (1R)-(+)-camphor. An asymmetric variant of the classical acetylene route to carbonyl compounds.

Organic letters

Palomo C, Oiarbide M, Mielgo A, González A, García JM, Landa C, Lecumberri A, Linden A.
PMID: 11594806
Org Lett. 2001 Oct 18;3(21):3249-52. doi: 10.1021/ol0163530.

[reaction: see text]. The asymmetric version of the traditional route for transforming acetylene into alpha-branched carbonyl compounds is now feasible for the first time. The method involves the temporary attachment of camphor to acetylene and gives a remarkably high...

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Palomo C, Oiarbide M, Mielgo A, et al. Alkylation of chiral alpha-hydroxy ketones derived from (1R)-(+)-camphor. An asymmetric variant of the classical acetylene route to carbonyl compounds. Org Lett. 2001;3(21):3249-52doi: 10.1021/ol0163530.
Palomo, C., Oiarbide, M., Mielgo, A., González, A., García, J. M., Landa, C., Lecumberri, A., & Linden, A. (2001). Alkylation of chiral alpha-hydroxy ketones derived from (1R)-(+)-camphor. An asymmetric variant of the classical acetylene route to carbonyl compounds. Organic letters, 3(21), 3249-52. https://doi.org/10.1021/ol0163530
Palomo, C, et al. "Alkylation of chiral alpha-hydroxy ketones derived from (1R)-(+)-camphor. An asymmetric variant of the classical acetylene route to carbonyl compounds." Organic letters vol. 3,21 (2001): 3249-52. doi: https://doi.org/10.1021/ol0163530
Palomo C, Oiarbide M, Mielgo A, González A, García JM, Landa C, Lecumberri A, Linden A. Alkylation of chiral alpha-hydroxy ketones derived from (1R)-(+)-camphor. An asymmetric variant of the classical acetylene route to carbonyl compounds. Org Lett. 2001 Oct 18;3(21):3249-52. doi: 10.1021/ol0163530. PMID: 11594806.
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The aldol addition reaction: an old transformation at constant rebirth.

Chemistry (Weinheim an der Bergstrasse, Germany)

Palomo C, Oiarbide M, García JM.
PMID: 11822463
Chemistry. 2002 Jan 04;8(1):36-44. doi: 10.1002/1521-3765(20020104)8:1<36::aid-chem36>3.0.co;2-l.

The main recent conceptual advances in asymmetric aldol reactions are presented. Methods ranging from stoichiometric chiral auxiliary-mediated to direct, catalytic reactions are covered, including the Mukaiyama aldol reactions which use stoichiometric base and silylating reagents, but catalytic (substoichiometric) amounts...

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Palomo C, Oiarbide M, García JM. The aldol addition reaction: an old transformation at constant rebirth. Chemistry. 2002;8(1):36-44doi: 10.1002/1521-3765(20020104)8:1<36::aid-chem36>3.0.co;2-l.
Palomo, C., Oiarbide, M., & García, J. M. (2002). The aldol addition reaction: an old transformation at constant rebirth. Chemistry (Weinheim an der Bergstrasse, Germany), 8(1), 36-44. https://doi.org/10.1002/1521-3765(20020104)8:1<36::aid-chem36>3.0.co;2-l
Palomo, Claudio, et al. "The aldol addition reaction: an old transformation at constant rebirth." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 8,1 (2002): 36-44. doi: https://doi.org/10.1002/1521-3765(20020104)8:1<36::aid-chem36>3.0.co;2-l
Palomo C, Oiarbide M, García JM. The aldol addition reaction: an old transformation at constant rebirth. Chemistry. 2002 Jan 04;8(1):36-44. doi: 10.1002/1521-3765(20020104)8:1<36::aid-chem36>3.0.co;2-l. PMID: 11822463.
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Developmental capacity of in vitro matured and fertilized oocytes from prepubertal and adult goats.

Theriogenology

Mogas T, Palomo MJ, Izquierdo MD, Paramio MT.
PMID: 16728068
Theriogenology. 1997 Apr 15;47(6):1189-203. doi: 10.1016/s0093-691x(97)00099-x.

The developmental competence of oocytes from prepubertal and adult goats was studied through in vitro maturation, fertilization and embryo culture up to the blastocyst stage. Oocytes were recovered from antral follicles of prepubertal and adult goat ovaries, with or...

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Mogas T, Palomo MJ, Izquierdo MD, et al. Developmental capacity of in vitro matured and fertilized oocytes from prepubertal and adult goats. Theriogenology. 1997;47(6):1189-203doi: 10.1016/s0093-691x(97)00099-x.
Mogas, T., Palomo, M. J., Izquierdo, M. D., & Paramio, M. T. (1997). Developmental capacity of in vitro matured and fertilized oocytes from prepubertal and adult goats. Theriogenology, 47(6), 1189-203. https://doi.org/10.1016/s0093-691x(97)00099-x
Mogas, T, et al. "Developmental capacity of in vitro matured and fertilized oocytes from prepubertal and adult goats." Theriogenology vol. 47,6 (1997): 1189-203. doi: https://doi.org/10.1016/s0093-691x(97)00099-x
Mogas T, Palomo MJ, Izquierdo MD, Paramio MT. Developmental capacity of in vitro matured and fertilized oocytes from prepubertal and adult goats. Theriogenology. 1997 Apr 15;47(6):1189-203. doi: 10.1016/s0093-691x(97)00099-x. PMID: 16728068.
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Enantioselective aza-Henry reactions assisted by Zn(II) and N-methylephedrine.

Angewandte Chemie (International ed. in English)

Palomo C, Oiarbide M, Halder R, Laso A, López R.
PMID: 16292782
Angew Chem Int Ed Engl. 2005 Dec 16;45(1):117-20. doi: 10.1002/anie.200502674.

No abstract available.

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Palomo C, Oiarbide M, Halder R, et al. Enantioselective aza-Henry reactions assisted by Zn(II) and N-methylephedrine. Angew Chem Int Ed Engl. 2005;45(1):117-20doi: 10.1002/anie.200502674.
Palomo, C., Oiarbide, M., Halder, R., Laso, A., & López, R. (2005). Enantioselective aza-Henry reactions assisted by Zn(II) and N-methylephedrine. Angewandte Chemie (International ed. in English), 45(1), 117-20. https://doi.org/10.1002/anie.200502674
Palomo, Claudio, et al. "Enantioselective aza-Henry reactions assisted by Zn(II) and N-methylephedrine." Angewandte Chemie (International ed. in English) vol. 45,1 (2005): 117-20. doi: https://doi.org/10.1002/anie.200502674
Palomo C, Oiarbide M, Halder R, Laso A, López R. Enantioselective aza-Henry reactions assisted by Zn(II) and N-methylephedrine. Angew Chem Int Ed Engl. 2005 Dec 16;45(1):117-20. doi: 10.1002/anie.200502674. PMID: 16292782.
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Conjugate addition of nitroalkanes to an acrylate equivalent. Stereocontrol at C-alpha of the nitro group through double catalytic activation.

Organic letters

García JM, Maestro MA, Oiarbide M, Odriozola JM, Razkin J, Palomo C.
PMID: 19663464
Org Lett. 2009 Sep 03;11(17):3826-9. doi: 10.1021/ol901351k.

An unprecedented highly selective direct conjugate addition of prochiral nitroalkanes (R not equal H) to acrylate equivalents is described. The method employs a unique Lewis acid/Brønsted base/MS ternary catalytic system and affords products with dr up to 97/3. With...

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García JM, Maestro MA, Oiarbide M, et al. Conjugate addition of nitroalkanes to an acrylate equivalent. Stereocontrol at C-alpha of the nitro group through double catalytic activation. Org Lett. 2009;11(17):3826-9doi: 10.1021/ol901351k.
García, J. M., Maestro, M. A., Oiarbide, M., Odriozola, J. M., Razkin, J., & Palomo, C. (2009). Conjugate addition of nitroalkanes to an acrylate equivalent. Stereocontrol at C-alpha of the nitro group through double catalytic activation. Organic letters, 11(17), 3826-9. https://doi.org/10.1021/ol901351k
García, Jesús M, et al. "Conjugate addition of nitroalkanes to an acrylate equivalent. Stereocontrol at C-alpha of the nitro group through double catalytic activation." Organic letters vol. 11,17 (2009): 3826-9. doi: https://doi.org/10.1021/ol901351k
García JM, Maestro MA, Oiarbide M, Odriozola JM, Razkin J, Palomo C. Conjugate addition of nitroalkanes to an acrylate equivalent. Stereocontrol at C-alpha of the nitro group through double catalytic activation. Org Lett. 2009 Sep 03;11(17):3826-9. doi: 10.1021/ol901351k. PMID: 19663464.
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Brønsted acid assisted regio- and enantioselective direct O-nitroso aldol reaction catalysed by alpha,alpha-diphenylprolinol trimethylsilyl ether.

Chemistry (Weinheim an der Bergstrasse, Germany)

Mielgo A, Velilla I, Gómez-Bengoa E, Palomo C.
PMID: 20437428
Chemistry. 2010 Jul 05;16(25):7496-502. doi: 10.1002/chem.201000376.

In the presence of p-nitrobenzoic acid, the O-nitroso aldol reaction of nitrosobenzene with enolisable aldehydes may be promoted by commercially available alpha,alpha-diphenylprolinol trimethylsilyl ether. The reaction proceeds with good yields and essentially complete enantioselectivity, with catalyst loadings in the...

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Mielgo A, Velilla I, Gómez-Bengoa E, et al. Brønsted acid assisted regio- and enantioselective direct O-nitroso aldol reaction catalysed by alpha,alpha-diphenylprolinol trimethylsilyl ether. Chemistry. 2010;16(25):7496-502doi: 10.1002/chem.201000376.
Mielgo, A., Velilla, I., Gómez-Bengoa, E., & Palomo, C. (2010). Brønsted acid assisted regio- and enantioselective direct O-nitroso aldol reaction catalysed by alpha,alpha-diphenylprolinol trimethylsilyl ether. Chemistry (Weinheim an der Bergstrasse, Germany), 16(25), 7496-502. https://doi.org/10.1002/chem.201000376
Mielgo, Antonia, et al. "Brønsted acid assisted regio- and enantioselective direct O-nitroso aldol reaction catalysed by alpha,alpha-diphenylprolinol trimethylsilyl ether." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 16,25 (2010): 7496-502. doi: https://doi.org/10.1002/chem.201000376
Mielgo A, Velilla I, Gómez-Bengoa E, Palomo C. Brønsted acid assisted regio- and enantioselective direct O-nitroso aldol reaction catalysed by alpha,alpha-diphenylprolinol trimethylsilyl ether. Chemistry. 2010 Jul 05;16(25):7496-502. doi: 10.1002/chem.201000376. PMID: 20437428.
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