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Facile interchange of 3d and 4f ions in single-molecule magnets: stepwise assembly of [Mn4 ], [Mn3Ln] and [Mn2Ln2 ] cages within calix[4]arene scaffolds.

Chemistry (Weinheim an der Bergstrasse, Germany)

Palacios MA, McLellan R, Beavers CM, Teat SJ, Weihe H, Piligkos S, Dalgarno SJ, Brechin EK.
PMID: 26121216
Chemistry. 2015 Jul 27;21(31):11212-8. doi: 10.1002/chem.201500001. Epub 2015 Jun 29.

The central Mn(II) ions in a series of calix[4]arene-stabilised butterflies can be sequentially replaced with Ln(III) ions, maintaining the structural integrity of the molecule but transforming its magnetic properties. The replacement of Mn(II) for Gd(III) allows for the examination...

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Palacios MA, McLellan R, Beavers CM, et al. Facile interchange of 3d and 4f ions in single-molecule magnets: stepwise assembly of [Mn4 ], [Mn3Ln] and [Mn2Ln2 ] cages within calix[4]arene scaffolds. Chemistry. 2015;21(31):11212-8doi: 10.1002/chem.201500001.
Palacios, M. A., McLellan, R., Beavers, C. M., Teat, S. J., Weihe, H., Piligkos, S., Dalgarno, S. J., & Brechin, E. K. (2015). Facile interchange of 3d and 4f ions in single-molecule magnets: stepwise assembly of [Mn4 ], [Mn3Ln] and [Mn2Ln2 ] cages within calix[4]arene scaffolds. Chemistry (Weinheim an der Bergstrasse, Germany), 21(31), 11212-8. https://doi.org/10.1002/chem.201500001
Palacios, Maria A, et al. "Facile interchange of 3d and 4f ions in single-molecule magnets: stepwise assembly of [Mn4 ], [Mn3Ln] and [Mn2Ln2 ] cages within calix[4]arene scaffolds." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 21,31 (2015): 11212-8. doi: https://doi.org/10.1002/chem.201500001
Palacios MA, McLellan R, Beavers CM, Teat SJ, Weihe H, Piligkos S, Dalgarno SJ, Brechin EK. Facile interchange of 3d and 4f ions in single-molecule magnets: stepwise assembly of [Mn4 ], [Mn3Ln] and [Mn2Ln2 ] cages within calix[4]arene scaffolds. Chemistry. 2015 Jul 27;21(31):11212-8. doi: 10.1002/chem.201500001. Epub 2015 Jun 29. PMID: 26121216.
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Non-Switching 1,2-Dithienylethene-based Diplatinum(II) Complex Showing High Cytotoxicity.

Inorganic chemistry

Presa A, Barrios L, Cirera J, Korrodi-Gregório L, Pérez-Tomás R, Teat SJ, Gamez P.
PMID: 27152916
Inorg Chem. 2016 Jun 06;55(11):5356-64. doi: 10.1021/acs.inorgchem.6b00362. Epub 2016 May 06.

A diplatinum(II) complex was prepared from a new 1,2-dithienylethene-based ligand containing N-methylimidazole groups as metal-binding units. Reaction of the ligand 1,2-bis[2-methyl-5-(1-methyl-1H-imidazol-2-yl)-3-thienyl]-cyclopentene (L2(H)) with cis-dichlorobis(dimethylsulfoxido)platinum(II) generated the bimetallic complex trans-[Pt2Cl4(DMSO)2(L2(H))] (DMSO = dimethyl sulfoxide), whose DNA-interacting properties were investigated using...

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Presa A, Barrios L, Cirera J, et al. Non-Switching 1,2-Dithienylethene-based Diplatinum(II) Complex Showing High Cytotoxicity. Inorg Chem. 2016;55(11):5356-64doi: 10.1021/acs.inorgchem.6b00362.
Presa, A., Barrios, L., Cirera, J., Korrodi-Gregório, L., Pérez-Tomás, R., Teat, S. J., & Gamez, P. (2016). Non-Switching 1,2-Dithienylethene-based Diplatinum(II) Complex Showing High Cytotoxicity. Inorganic chemistry, 55(11), 5356-64. https://doi.org/10.1021/acs.inorgchem.6b00362
Presa, Andreu, et al. "Non-Switching 1,2-Dithienylethene-based Diplatinum(II) Complex Showing High Cytotoxicity." Inorganic chemistry vol. 55,11 (2016): 5356-64. doi: https://doi.org/10.1021/acs.inorgchem.6b00362
Presa A, Barrios L, Cirera J, Korrodi-Gregório L, Pérez-Tomás R, Teat SJ, Gamez P. Non-Switching 1,2-Dithienylethene-based Diplatinum(II) Complex Showing High Cytotoxicity. Inorg Chem. 2016 Jun 06;55(11):5356-64. doi: 10.1021/acs.inorgchem.6b00362. Epub 2016 May 06. PMID: 27152916.
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Biomarkers and genetics of brain injury risk in diabetic ketoacidosis: A pilot study.

Journal of pediatric intensive care

Nett ST, Noble JA, Levin DL, Cvijanovich NZ, Vavilala MS, Jarvis JD, Flori HR.
PMID: 26097769
J Pediatr Intensive Care. 2014;3(2). doi: 10.3233/PIC-14091.

Diabetic ketoacidosis (DKA) is the primary cause of death for children with diabetes, especially when complicated by cerebral edema. Central nervous system (CNS) involvement is common, however the mechanism of, and predictors of CNS dysfunction/injury are largely unknown. In...

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Nett ST, Noble JA, Levin DL, et al. Biomarkers and genetics of brain injury risk in diabetic ketoacidosis: A pilot study. J Pediatr Intensive Care. 2014;3(2)doi: 10.3233/PIC-14091.
Nett, S. T., Noble, J. A., Levin, D. L., Cvijanovich, N. Z., Vavilala, M. S., Jarvis, J. D., & Flori, H. R. (2014). Biomarkers and genetics of brain injury risk in diabetic ketoacidosis: A pilot study. Journal of pediatric intensive care, 3(2), . https://doi.org/10.3233/PIC-14091
Nett, Sholeen T, et al. "Biomarkers and genetics of brain injury risk in diabetic ketoacidosis: A pilot study." Journal of pediatric intensive care vol. 3,2 (2014). doi: https://doi.org/10.3233/PIC-14091
Nett ST, Noble JA, Levin DL, Cvijanovich NZ, Vavilala MS, Jarvis JD, Flori HR. Biomarkers and genetics of brain injury risk in diabetic ketoacidosis: A pilot study. J Pediatr Intensive Care. 2014;3(2). doi: 10.3233/PIC-14091. PMID: 26097769; PMCID: PMC4472439.
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Genetic Diversity of Cultivated Lentil (Lens culinaris Medik.) and Its Relation to the World's Agro-ecological Zones.

Frontiers in plant science

Khazaei H, Caron CT, Fedoruk M, Diapari M, Vandenberg A, Coyne CJ, McGee R, Bett KE.
PMID: 27507980
Front Plant Sci. 2016 Jul 26;7:1093. doi: 10.3389/fpls.2016.01093. eCollection 2016.

Assessment of genetic diversity and population structure of germplasm collections plays a critical role in supporting conservation and crop genetic enhancement strategies. We used a cultivated lentil (Lens culinaris Medik.) collection consisting of 352 accessions originating from 54 diverse...

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Khazaei H, Caron CT, Fedoruk M, et al. Genetic Diversity of Cultivated Lentil (Lens culinaris Medik.) and Its Relation to the World's Agro-ecological Zones. Front Plant Sci. 2016;7:1093doi: 10.3389/fpls.2016.01093.
Khazaei, H., Caron, C. T., Fedoruk, M., Diapari, M., Vandenberg, A., Coyne, C. J., McGee, R., & Bett, K. E. (2016). Genetic Diversity of Cultivated Lentil (Lens culinaris Medik.) and Its Relation to the World's Agro-ecological Zones. Frontiers in plant science, 71093. https://doi.org/10.3389/fpls.2016.01093
Khazaei, Hamid, et al. "Genetic Diversity of Cultivated Lentil (Lens culinaris Medik.) and Its Relation to the World's Agro-ecological Zones." Frontiers in plant science vol. 7 (2016): 1093. doi: https://doi.org/10.3389/fpls.2016.01093
Khazaei H, Caron CT, Fedoruk M, Diapari M, Vandenberg A, Coyne CJ, McGee R, Bett KE. Genetic Diversity of Cultivated Lentil (Lens culinaris Medik.) and Its Relation to the World's Agro-ecological Zones. Front Plant Sci. 2016 Jul 26;7:1093. doi: 10.3389/fpls.2016.01093. eCollection 2016. PMID: 27507980; PMCID: PMC4960256.
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How Accurately Can Parents Judge Their Children's Boredom in School?.

Frontiers in psychology

Nett UE, Daschmann EC, Goetz T, Stupnisky RH.
PMID: 27445876
Front Psychol. 2016 Jun 30;7:770. doi: 10.3389/fpsyg.2016.00770. eCollection 2016.

The purpose of the present study was to explore what parents know about their Children's boredom in school; specifically, the frequency, intensity, and antecedents of their Children's boredom, as well as how they cope with boredom. A questionnaire was...

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Nett UE, Daschmann EC, Goetz T, et al. How Accurately Can Parents Judge Their Children's Boredom in School?. Front Psychol. 2016;7:770doi: 10.3389/fpsyg.2016.00770.
Nett, U. E., Daschmann, E. C., Goetz, T., & Stupnisky, R. H. (2016). How Accurately Can Parents Judge Their Children's Boredom in School?. Frontiers in psychology, 7770. https://doi.org/10.3389/fpsyg.2016.00770
Nett, Ulrike E, et al. "How Accurately Can Parents Judge Their Children's Boredom in School?." Frontiers in psychology vol. 7 (2016): 770. doi: https://doi.org/10.3389/fpsyg.2016.00770
Nett UE, Daschmann EC, Goetz T, Stupnisky RH. How Accurately Can Parents Judge Their Children's Boredom in School?. Front Psychol. 2016 Jun 30;7:770. doi: 10.3389/fpsyg.2016.00770. eCollection 2016. PMID: 27445876; PMCID: PMC4927813.
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Characterization of the periplasmic redox network that sustains the versatile anaerobic metabolism of Shewanella oneidensis MR-1.

Frontiers in microbiology

Alves MN, Neto SE, Alves AS, Fonseca BM, Carrêlo A, Pacheco I, Paquete CM, Soares CM, Louro RO.
PMID: 26175726
Front Microbiol. 2015 Jun 29;6:665. doi: 10.3389/fmicb.2015.00665. eCollection 2015.

The versatile anaerobic metabolism of the Gram-negative bacterium Shewanella oneidensis MR-1 (SOMR-1) relies on a multitude of redox proteins found in its periplasm. Most are multiheme cytochromes that carry electrons to terminal reductases of insoluble electron acceptors located at...

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Alves MN, Neto SE, Alves AS, et al. Characterization of the periplasmic redox network that sustains the versatile anaerobic metabolism of Shewanella oneidensis MR-1. Front Microbiol. 2015;6:665doi: 10.3389/fmicb.2015.00665.
Alves, M. N., Neto, S. E., Alves, A. S., Fonseca, B. M., Carrêlo, A., Pacheco, I., Paquete, C. M., Soares, C. M., & Louro, R. O. (2015). Characterization of the periplasmic redox network that sustains the versatile anaerobic metabolism of Shewanella oneidensis MR-1. Frontiers in microbiology, 6665. https://doi.org/10.3389/fmicb.2015.00665
Alves, Mónica N, et al. "Characterization of the periplasmic redox network that sustains the versatile anaerobic metabolism of Shewanella oneidensis MR-1." Frontiers in microbiology vol. 6 (2015): 665. doi: https://doi.org/10.3389/fmicb.2015.00665
Alves MN, Neto SE, Alves AS, Fonseca BM, Carrêlo A, Pacheco I, Paquete CM, Soares CM, Louro RO. Characterization of the periplasmic redox network that sustains the versatile anaerobic metabolism of Shewanella oneidensis MR-1. Front Microbiol. 2015 Jun 29;6:665. doi: 10.3389/fmicb.2015.00665. eCollection 2015. PMID: 26175726; PMCID: PMC4484225.
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Heterodimetallic [LnLn'] lanthanide complexes: toward a chemical design of two-qubit molecular spin quantum gates.

Journal of the American Chemical Society

Aguilà D, Barrios LA, Velasco V, Roubeau O, Repollés A, Alonso PJ, Sesé J, Teat SJ, Luis F, Aromí G.
PMID: 25203521
J Am Chem Soc. 2014 Oct 08;136(40):14215-22. doi: 10.1021/ja507809w. Epub 2014 Sep 26.

A major challenge for realizing quantum computation is finding suitable systems to embody quantum bits (qubits) and quantum gates (qugates) in a robust and scalable architecture. An emerging bottom-up approach uses the electronic spins of lanthanides. Universal qugates may...

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Aguilà D, Barrios LA, Velasco V, et al. Heterodimetallic [LnLn'] lanthanide complexes: toward a chemical design of two-qubit molecular spin quantum gates. J Am Chem Soc. 2014;136(40):14215-22doi: 10.1021/ja507809w.
Aguilà, D., Barrios, L. A., Velasco, V., Roubeau, O., Repollés, A., Alonso, P. J., Sesé, J., Teat, S. J., Luis, F., & Aromí, G. (2014). Heterodimetallic [LnLn'] lanthanide complexes: toward a chemical design of two-qubit molecular spin quantum gates. Journal of the American Chemical Society, 136(40), 14215-22. https://doi.org/10.1021/ja507809w
Aguilà, David, et al. "Heterodimetallic [LnLn'] lanthanide complexes: toward a chemical design of two-qubit molecular spin quantum gates." Journal of the American Chemical Society vol. 136,40 (2014): 14215-22. doi: https://doi.org/10.1021/ja507809w
Aguilà D, Barrios LA, Velasco V, Roubeau O, Repollés A, Alonso PJ, Sesé J, Teat SJ, Luis F, Aromí G. Heterodimetallic [LnLn'] lanthanide complexes: toward a chemical design of two-qubit molecular spin quantum gates. J Am Chem Soc. 2014 Oct 08;136(40):14215-22. doi: 10.1021/ja507809w. Epub 2014 Sep 26. PMID: 25203521; PMCID: PMC4195387.
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The First Red Azo Lake Pigment whose Structure is Characterized by Single Crystal Diffraction.

Angewandte Chemie (International ed. in English)

Kennedy AR, McNair C, Smith WE, Chisholm G, Teat SJ.
PMID: 10671284
Angew Chem Int Ed Engl. 2000 Feb;39(3):638-640. doi: 10.1002/(sici)1521-3773(20000204)39:3<638::aid-anie638>3.0.co;2-k.

A model for red azo pigment Ca4B was characterized structurally using synchrotron radiation. This highly anisotropic ladder structure represents a new structural class in azo pigment chemistry. The picture shows that the calcium atoms coordinate in a complex manner...

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Kennedy AR, McNair C, Smith WE, et al. The First Red Azo Lake Pigment whose Structure is Characterized by Single Crystal Diffraction. Angew Chem Int Ed Engl. 2000;39(3):638-640doi: 10.1002/(sici)1521-3773(20000204)39:3<638::aid-anie638>3.0.co;2-k.
Kennedy, A. R., McNair, C., Smith, W. E., Chisholm, G., & Teat, S. J. (2000). The First Red Azo Lake Pigment whose Structure is Characterized by Single Crystal Diffraction. Angewandte Chemie (International ed. in English), 39(3), 638-640. https://doi.org/10.1002/(sici)1521-3773(20000204)39:3<638::aid-anie638>3.0.co;2-k
Kennedy, et al. "The First Red Azo Lake Pigment whose Structure is Characterized by Single Crystal Diffraction." Angewandte Chemie (International ed. in English) vol. 39,3 (2000): 638-640. doi: https://doi.org/10.1002/(sici)1521-3773(20000204)39:3<638::aid-anie638>3.0.co;2-k
Kennedy AR, McNair C, Smith WE, Chisholm G, Teat SJ. The First Red Azo Lake Pigment whose Structure is Characterized by Single Crystal Diffraction. Angew Chem Int Ed Engl. 2000 Feb;39(3):638-640. doi: 10.1002/(sici)1521-3773(20000204)39:3<638::aid-anie638>3.0.co;2-k. PMID: 10671284.
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Hydrogen-bonding clusters leading to formation of supramolecular dimers of metalloporphyrin receptors: modulation of Lewis acidity by pi-pi interactions.

Chemistry (Weinheim an der Bergstrasse, Germany)

Nakash M, Clyde-Watson Z, Feeder N, Teat SJ, Sanders JK.
PMID: 10926215
Chemistry. 2000 Jun 16;6(12):2112-9. doi: 10.1002/1521-3765(20000616)6:12<2112::aid-chem2112>3.0.co;2-w.

Two remarkable crystal structures are reported of a cyclic receptor 1, containing two metalloporphyrin units. The overall crystal structure of 1 provides the first direct evidence that pi-stacking between two metalloporphyrins reduces the Lewis acidity of the metal ion...

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Nakash M, Clyde-Watson Z, Feeder N, et al. Hydrogen-bonding clusters leading to formation of supramolecular dimers of metalloporphyrin receptors: modulation of Lewis acidity by pi-pi interactions. Chemistry. 2000;6(12):2112-9doi: 10.1002/1521-3765(20000616)6:12<2112::aid-chem2112>3.0.co;2-w.
Nakash, M., Clyde-Watson, Z., Feeder, N., Teat, S. J., & Sanders, J. K. (2000). Hydrogen-bonding clusters leading to formation of supramolecular dimers of metalloporphyrin receptors: modulation of Lewis acidity by pi-pi interactions. Chemistry (Weinheim an der Bergstrasse, Germany), 6(12), 2112-9. https://doi.org/10.1002/1521-3765(20000616)6:12<2112::aid-chem2112>3.0.co;2-w
Nakash, et al. "Hydrogen-bonding clusters leading to formation of supramolecular dimers of metalloporphyrin receptors: modulation of Lewis acidity by pi-pi interactions." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 6,12 (2000): 2112-9. doi: https://doi.org/10.1002/1521-3765(20000616)6:12<2112::aid-chem2112>3.0.co;2-w
Nakash M, Clyde-Watson Z, Feeder N, Teat SJ, Sanders JK. Hydrogen-bonding clusters leading to formation of supramolecular dimers of metalloporphyrin receptors: modulation of Lewis acidity by pi-pi interactions. Chemistry. 2000 Jun 16;6(12):2112-9. doi: 10.1002/1521-3765(20000616)6:12<2112::aid-chem2112>3.0.co;2-w. PMID: 10926215.
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Cobalt-mediated synthesis of angular [4]phenylene: structural characterization of a metallacyclopentadiene(alkyne) intermediate and its thermal and photochemical conversion.

Organic letters

Dosa PI, Whitener GD, Vollhardt KP, Bond AD, Teat SJ.
PMID: 12049521
Org Lett. 2002 Jun 13;4(12):2075-8. doi: 10.1021/ol025956o.

[reaction: see text] The first X-ray crystal structure of a mononuclear metallacyclopentadiene(alkyne) complex has been obtained. This type of metallacycle is believed to be the key intermediate in the cobalt-mediated [2 + 2 + 2]cycloaddition of alkynes. Thermal treatment...

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Dosa PI, Whitener GD, Vollhardt KP, et al. Cobalt-mediated synthesis of angular [4]phenylene: structural characterization of a metallacyclopentadiene(alkyne) intermediate and its thermal and photochemical conversion. Org Lett. 2002;4(12):2075-8doi: 10.1021/ol025956o.
Dosa, P. I., Whitener, G. D., Vollhardt, K. P., Bond, A. D., & Teat, S. J. (2002). Cobalt-mediated synthesis of angular [4]phenylene: structural characterization of a metallacyclopentadiene(alkyne) intermediate and its thermal and photochemical conversion. Organic letters, 4(12), 2075-8. https://doi.org/10.1021/ol025956o
Dosa, Peter I, et al. "Cobalt-mediated synthesis of angular [4]phenylene: structural characterization of a metallacyclopentadiene(alkyne) intermediate and its thermal and photochemical conversion." Organic letters vol. 4,12 (2002): 2075-8. doi: https://doi.org/10.1021/ol025956o
Dosa PI, Whitener GD, Vollhardt KP, Bond AD, Teat SJ. Cobalt-mediated synthesis of angular [4]phenylene: structural characterization of a metallacyclopentadiene(alkyne) intermediate and its thermal and photochemical conversion. Org Lett. 2002 Jun 13;4(12):2075-8. doi: 10.1021/ol025956o. PMID: 12049521.
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Variable-temperature microcrystal X-ray diffraction studies of negative thermal expansion in the pure silica zeolite IFR.

Journal of the American Chemical Society

Villaescusa LA, Lightfoot P, Teat SJ, Morris RE.
PMID: 11389626
J Am Chem Soc. 2001 Jun 13;123(23):5453-9. doi: 10.1021/ja015797o.

Variable-temperature single-crystal X-ray diffraction using a synchrotron X-ray source has allowed the mechanism of negative thermal expansion in the pure silica zeolite IFR to be studied in greater detail than was previously possible over the temperature range 30-557 K....

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Villaescusa LA, Lightfoot P, Teat SJ, et al. Variable-temperature microcrystal X-ray diffraction studies of negative thermal expansion in the pure silica zeolite IFR. J Am Chem Soc. 2001;123(23):5453-9doi: 10.1021/ja015797o.
Villaescusa, L. A., Lightfoot, P., Teat, S. J., & Morris, R. E. (2001). Variable-temperature microcrystal X-ray diffraction studies of negative thermal expansion in the pure silica zeolite IFR. Journal of the American Chemical Society, 123(23), 5453-9. https://doi.org/10.1021/ja015797o
Villaescusa, L A, et al. "Variable-temperature microcrystal X-ray diffraction studies of negative thermal expansion in the pure silica zeolite IFR." Journal of the American Chemical Society vol. 123,23 (2001): 5453-9. doi: https://doi.org/10.1021/ja015797o
Villaescusa LA, Lightfoot P, Teat SJ, Morris RE. Variable-temperature microcrystal X-ray diffraction studies of negative thermal expansion in the pure silica zeolite IFR. J Am Chem Soc. 2001 Jun 13;123(23):5453-9. doi: 10.1021/ja015797o. PMID: 11389626.
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Tuning the optical properties of Prussian blue-like complexes.

Chemical communications (Cambridge, England)

Rogez G, Marvilliers A, Sarr P, Parsons S, Teat SJ, Ricard L, Mallah T.
PMID: 12189843
Chem Commun (Camb). 2002 Jul 21;(14):1460-1. doi: 10.1039/b202288e.

The rational design of the organic ligand allows to finely tune the degree of delocalization of mixed-valence Prussian blue-like molecules.

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Rogez G, Marvilliers A, Sarr P, et al. Tuning the optical properties of Prussian blue-like complexes. Chem Commun (Camb). 2002;(14):1460-1doi: 10.1039/b202288e.
Rogez, G., Marvilliers, A., Sarr, P., Parsons, S., Teat, S. J., Ricard, L., & Mallah, T. (2002). Tuning the optical properties of Prussian blue-like complexes. Chemical communications (Cambridge, England), (14), 1460-1. https://doi.org/10.1039/b202288e
Rogez, Guillaume, et al. "Tuning the optical properties of Prussian blue-like complexes." Chemical communications (Cambridge, England) vol. ,14 (2002): 1460-1. doi: https://doi.org/10.1039/b202288e
Rogez G, Marvilliers A, Sarr P, Parsons S, Teat SJ, Ricard L, Mallah T. Tuning the optical properties of Prussian blue-like complexes. Chem Commun (Camb). 2002 Jul 21;(14):1460-1. doi: 10.1039/b202288e. PMID: 12189843.
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