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Showing 1 to 12 of 366 entries
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An Optically Transparent Iron Nickel Oxide Catalyst for Solar Water Splitting.

Journal of the American Chemical Society

Morales-Guio CG, Mayer MT, Yella A, Tilley SD, Grätzel M, Hu X.
PMID: 26200221
J Am Chem Soc. 2015 Aug 12;137(31):9927-36. doi: 10.1021/jacs.5b05544. Epub 2015 Aug 04.

Sunlight-driven water splitting to produce hydrogen fuel is an attractive method for renewable energy conversion. Tandem photoelectrochemical water splitting devices utilize two photoabsorbers to harvest the sunlight and drive the water splitting reaction. The absorption of sunlight by electrocatalysts...

Identification of Second Shell Coordination in Transition Metal Species Using Theoretical XANES: Example of Ti-O-(C, Si, Ge) Complexes.

The journal of physical chemistry. A

Spanjers CS, Guillo P, Tilley TD, Janik MJ, Rioux RM.
PMID: 27951643
J Phys Chem A. 2017 Jan 12;121(1):162-167. doi: 10.1021/acs.jpca.6b12197. Epub 2016 Dec 27.

X-ray absorption near-edge structure (XANES) is a common technique for elucidating oxidation state and first shell coordination geometry in transition metal complexes, among many other materials. However, the structural information obtained from XANES is often limited to the first...

Corrigendum to "Comprehensive assessment of estrogen receptor beta antibodies in cancer cell line models and tissue reveals critical limitations in reagent specificity" [Mol. Cell Endocrinol. 440 (2016) 138-150].

Molecular and cellular endocrinology

Nelson AW, Groen AJ, Miller JL, Warren AY, Holmes KA, Tarulli GA, Tilley WD, Katzenellenbogen BS, Hawse JR, Gnanapragasam VJ, Carroll JS.
PMID: 28183459
Mol Cell Endocrinol. 2017 Mar 05;443:175. doi: 10.1016/j.mce.2017.01.048.

No abstract available.

Solution transformation of Cu₂O into CuInS₂ for solar water splitting.

Nano letters

Luo J, Tilley SD, Steier L, Schreier M, Mayer MT, Fan HJ, Grätzel M.
PMID: 25585159
Nano Lett. 2015 Feb 11;15(2):1395-402. doi: 10.1021/nl504746b. Epub 2015 Jan 16.

Though Cu2O has demonstrated high performance as a photocathode for solar water splitting, its band gap is too large for efficient use as the bottom cell in tandem configurations. Accordingly, copper chalcopyrites have recently attracted much attention for solar...

Cyclometalated N-heterocyclic carbene complexes of ruthenium for access to electron-rich silylene complexes that bind the Lewis acids CuOTf and AgOTf.

Journal of the American Chemical Society

Liu HJ, Raynaud C, Eisenstein O, Tilley TD.
PMID: 25050912
J Am Chem Soc. 2014 Aug 13;136(32):11473-82. doi: 10.1021/ja5054237. Epub 2014 Aug 01.

The synthesis of the cyclometalated complexes Cp*Ru(IXy-H) (2) [IXy = 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene; IXy-H = 1-(2-CH2C6H3-6-methyl)-3-(2,6-dimethylphenyl)imidazol-2-ylidene-1-yl (the deprotonated form of IXy); Cp* = η(5)-C5Me5] and Cp*Ru(IXy-H)(N2) (3) was achieved by dehydrochlorination of Cp*Ru(IXy)Cl (1) with KCH2Ph. Complexes 2 and 3 activate...

Size and shape evolution of highly magnetic iron nanoparticles from successive growth reactions.

Chemical communications (Cambridge, England)

McGrath AJ, Cheong S, Henning AM, Gooding JJ, Tilley RD.
PMID: 28990039
Chem Commun (Camb). 2017 Oct 19;53(84):11548-11551. doi: 10.1039/c7cc06300h.

We present a synthetic protocol for the solution-phase synthesis of monocrystalline, metallic iron nanoparticles based on seed-mediated growth, showing near-single nanometre control over particle size. A shape evolution to cubic nanoparticles is also observed with increasing size. Magnetic properties...

An efficient, single-source molecular precursor to silicoaluminophosphates.

Journal of the American Chemical Society

Fujdala KL, Tilley TD.
PMID: 11592907
J Am Chem Soc. 2001 Oct 17;123(41):10133-4. doi: 10.1021/ja0167295.

No abstract available.

Stress electrocardiography: a review.

The Journal of the Arkansas Medical Society

Talley JD, Calandro V, Dietz T, Dinh H.
PMID: 9119816
J Ark Med Soc. 1997 Mar;93(10):490-3.

No abstract available.

Mechanistic aspects of samarium-mediated sigma-bond activations of arene C-H and arylsilane Si-C bonds.

Journal of the American Chemical Society

Castillo I, Tilley TD.
PMID: 11673984
J Am Chem Soc. 2001 Oct 31;123(43):10526-34. doi: 10.1021/ja011472w.

To investigate the potential role of Sm-Ph species as intermediates in the samarium-catalyzed redistribution of PhSiH3 to Ph2SiH2 and SiH4, the samarium phenyl complex [Cp*2SmPh]2 (1) was prepared by oxidation of Cp2*Sm (2) with HgPh2. Compound 1 thermally decomposes...

Synthesis, characterization, and catalytic performance of single-site iron(III) centers on the surface of SBA-15 silica.

Journal of the American Chemical Society

Nozaki C, Lugmair CG, Bell AT, Tilley TD.
PMID: 12405848
J Am Chem Soc. 2002 Nov 06;124(44):13194-203. doi: 10.1021/ja020388t.

A new molecular precursor strategy has been used to prepare a series of single-site catalysts that possess isolated iron centers supported on mesoporous SBA-15 silica. The iron centers were introduced via grafting reactions of the tris(tert-butoxy)siloxy iron(III) complex Fe[OSi(O(t)Bu)(3)](3)(THF)...

Cationic hafnium silyl complexes and their enhanced reactivity in sigma-bond metathesis processes with Si-H and C-H bonds.

Journal of the American Chemical Society

Sadow AD, Tilley TD.
PMID: 12889977
J Am Chem Soc. 2003 Aug 06;125(31):9462-75. doi: 10.1021/ja030024g.

Reaction of the mixed-ring silyl methyl complex CpCp*Hf[Si(SiMe3)3]Me (4) with B(C6F5)3 in bromobenzene-d5 yielded the zwitterionic hafnium silyl complex [CpCpHfSi(SiMe3)3][MeB(C6F5)3] (7), which is stable for at least 12 h in solution. Addition of PhSiH3 to 7 rapidly produced HSi(SiMe3)3,...

Analytical equilibrium gradient methods.

Analytical and bioanalytical chemistry

Wang Q, Tolley HD, LeFebre DA, Lee ML.
PMID: 12043014
Anal Bioanal Chem. 2002 Jun;373(3):125-35. doi: 10.1007/s00216-002-1286-y. Epub 2002 Apr 30.

Analytical equilibrium gradient methods are non-linear separation methods in which the separation mechanism involves a force gradient along the separation channel. These methods can be classified into two categories: those in which the gradient is a field gradient applied...

Showing 1 to 12 of 366 entries