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Showing 1 to 12 of 39 entries
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Lowering water oxidation overpotentials using the ionisable imidazole of copper(2-(2'-pyridyl)imidazole).

Chemical communications (Cambridge, England)

Stott LA, Prosser KE, Berdichevsky EK, Walsby CJ, Warren JJ.
PMID: 27990513
Chem Commun (Camb). 2017 Jan 03;53(3):651-654. doi: 10.1039/c6cc09208j.

Rapid and low overpotential oxidation of water to dioxygen remains a key hurdle for storage of solar energy. Here, we address this issue by demonstrating that deprotonation of 2-(2'-pyridyl)-imidazole (pimH)-ligated copper complexes promotes water oxidation at low overpotential and...

A single case study: Striving for stability and work - "it's a real bastard of a disease".

Work (Reading, Mass.)

Tse SS, Yeats M, Walsh AE.
PMID: 12441430
Work. 1999;12(2):151-157.

This paper outlines a narrative description of the inner experience of one man with bipolar affective disorder highlighting his attempts to strive for work while maintaining on-going mental stability. The narrative is based upon a semi-structured interview, review of...

Carbon-centered strong bases in phosphonium ionic liquids.

The Journal of organic chemistry

Ramnial T, Taylor SA, Bender ML, Gorodetsky B, Lee PT, Dickie DA, McCollum BM, Pye CC, Walsby CJ, Clyburne JA.
PMID: 18173280
J Org Chem. 2008 Feb 01;73(3):801-12. doi: 10.1021/jo701289d. Epub 2008 Jan 04.

Phosphonium ionic liquids (PhosILs), most notably tetradecyl(trihexyl)phosphonium decanoate (PhosIL-C(9)H(1)9COO), are solvents for bases such as Grignard reagents, isocyanides, Wittig reagents (phosphoranes), and N-heterocyclic carbenes (NHCs). The stability of the organometallic species in PhosIL solution is anion dependent. Small bases,...

Roentgen Ray Diagnosis of Tuberculosis of the Bones and Joints.

Canadian Medical Association journal

Walkey AE.
PMID: 20314218
Can Med Assoc J. 1922 Oct;12(10):728-9.

No abstract available.

Multiple Myeloma.

Canadian Medical Association journal

Walkey AE.
PMID: 20314830
Can Med Assoc J. 1923 Dec;13(12):908-10.

No abstract available.

A stable open-shell redox active ditopic ligand.

Dalton transactions (Cambridge, England : 2003)

Bonanno NM, Lough AJ, Prosser KE, Walsby CJ, Poddutoori PK, Lemaire MT.
PMID: 26966736
Dalton Trans. 2016 Apr 07;45(13):5460-3. doi: 10.1039/c5dt04061b. Epub 2016 Mar 11.

Herein we describe the synthesis, structure and electronic properties of an unusual redox-active ditopic ligand with a stable open-shell configuration. This stable phenoxyl radical features intense and very low energy electronic transitions in the near infrared (NIR) part of...

Connectivity as a Predictor of Responsiveness to Transcranial Direct Current Stimulation in People with Stroke: Protocol for a Double-Blind Randomized Controlled Trial.

JMIR research protocols

Welsby E, Ridding M, Hillier S, Hordacre B.
PMID: 30341044
JMIR Res Protoc. 2018 Oct 18;7(10):e10848. doi: 10.2196/10848.

BACKGROUND: Stroke can have devastating consequences for an individual's quality of life. Interventions capable of enhancing response to therapy would be highly valuable to the field of neurological rehabilitation. One approach is to use noninvasive brain stimulation techniques, such...

TLR9 expression in chronic lymphocytic leukemia identifies a promigratory subpopulation and novel therapeutic target.

Blood

Kennedy E, Coulter E, Halliwell E, Profitos-Peleja N, Walsby E, Clark B, Phillips EH, Burley TA, Mitchell S, Devereux S, Fegan CD, Jones CI, Johnston R, Chevassut T, Schulz R, Seiffert M, Agathanggelou A, Oldreive C, Davies N, Stankovic T, Liloglou T, Pepper C, Pepper AGS.
PMID: 33512408
Blood. 2021 Jun 03;137(22):3064-3078. doi: 10.1182/blood.2020005964.

Chronic lymphocytic leukemia (CLL) remains incurable despite B-cell receptor-targeted inhibitors revolutionizing treatment. This suggests that other signaling molecules are involved in disease escape mechanisms and resistance. Toll-like receptor 9 (TLR9) is a promising candidate that is activated by unmethylated...

The daily integral of growth by Planktothrix rubescens calculated from growth rate in culture and irradiance in Lake Zürich.

The New phytologist

Bright DI, Walsby AE, Bucher MA, Suzuki T, Samuel DB.
PMID: 33862979
New Phytol. 2000 May;146(2):301-316. doi: 10.1046/j.1469-8137.2000.00640.x.

In Lake Zürich, populations of the cyanobacterium Planktothrix rubescens develop in the metalimnion during the summer and become gradually entrained in the deepening surface mixed layer during the autumn. It had previously been demonstrated that the daily integrals of...

A mild Pummerer-like reaction of carbohydrate-based selenoethers and thioethers involving linear ozonide acetates as putative intermediates.

Journal of the American Chemical Society

Veerapen N, Taylor SA, Walsby CJ, Pinto BM.
PMID: 16390151
J Am Chem Soc. 2006 Jan 11;128(1):227-39. doi: 10.1021/ja0557029.

Pummerer-like rearrangements of carbohydrate-based heterocycles containing selenium and sulfur were investigated. To the best of our knowledge, this is the first report on the Pummerer rearrangement in selenoheterocycles. Ozonization of 1,4-anhydro-D-galactitol or 1,5-anhydroxylitol derivatives containing sulfur or selenium as...

Shaping the future of our training.

The journal of the Royal College of Physicians of Edinburgh

Hollick RJ, Ripley DP, Walesby KE.
PMID: 26181522
J R Coll Physicians Edinb. 2015;45(2):100-3. doi: 10.4997/JRCPE.2015.202.

The Shape of Training Review proposed fundamental changes to the nature and delivery of medical training in the UK. In part this is to respond to the increasing care needs of our ageing population and importantly to address problems...

A catalytic antioxidant for limiting amyloid-beta peptide aggregation and reactive oxygen species generation.

Chemical science

Gomes LMF, Mahammed A, Prosser KE, Smith JR, Silverman MA, Walsby CJ, Gross Z, Storr T.
PMID: 30842826
Chem Sci. 2018 Dec 03;10(6):1634-1643. doi: 10.1039/c8sc04660c. eCollection 2019 Feb 14.

Alzheimer's disease (AD) is a multifaceted disease that is characterized by increased oxidative stress, metal-ion dysregulation, and the formation of intracellular neurofibrillary tangles and extracellular amyloid-β (Aβ) aggregates. In this work we report the large affinity binding of the...

Showing 1 to 12 of 39 entries