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Showing 1 to 12 of 69 entries
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Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes.

Nature communications

King DM, Cleaves PA, Wooles AJ, Gardner BM, Chilton NF, Tuna F, Lewis W, McInnes EJL, Liddle ST.
PMID: 27996007
Nat Commun. 2016 Dec 20;7:13773. doi: 10.1038/ncomms13773.

Determining the electronic structure of actinide complexes is intrinsically challenging because inter-electronic repulsion, crystal field, and spin-orbit coupling effects can be of similar magnitude. Moreover, such efforts have been hampered by the lack of structurally analogous families of complexes...

Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex.

Angewandte Chemie (International ed. in English)

Gardner BM, Balázs G, Scheer M, Wooles AJ, Tuna F, McInnes EJ, McMaster J, Lewis W, Blake AJ, Liddle ST.
PMID: 26510123
Angew Chem Int Ed Engl. 2015 Dec 07;54(50):15250-4. doi: 10.1002/anie.201508600. Epub 2015 Oct 28.

The HAsAsH molecule has hitherto only been proposed tentatively as a short-lived species generated in electrochemical or microwave-plasma experiments. After two centuries of inconclusive or disproven claims of HAsAsH formation in the condensed phase, we report the isolation and...

The effect of the meaning of buildings on behaviour.

Applied ergonomics

Wools R, Canter D.
PMID: 15676326
Appl Ergon. 1970 Jun;1(3):144-50. doi: 10.1016/0003-6870(70)90004-9.

The development of three semantic scales to appraise the physical environment is described. The scales were generated from the reactions of subjects to drawings but it is shown that the scales are valid in real situations. Using these scales...

Heterogeneous catalysts for the controlled ring-opening polymerisation of rac-lactide and homogeneous silsesquioxane model complexes.

Dalton transactions (Cambridge, England : 2003)

Jones MD, Davidson MG, Keir CG, Wooles AJ, Mahon MF, Apperley DC.
PMID: 18615210
Dalton Trans. 2008 Jul 28;(28):3655-7. doi: 10.1039/b805274c. Epub 2008 May 29.

In this communication we report, for the first time, the ring-opening polymerisation in the melt of rac-lactide with heterogeneous catalysts. Homogeneous model systems based on silsesquioxanes have been prepared for comparison.

Early metal bis(phosphorus-stabilised)carbene chemistry.

Chemical Society reviews

Liddle ST, Mills DP, Wooles AJ.
PMID: 21321726
Chem Soc Rev. 2011 May;40(5):2164-76. doi: 10.1039/c0cs00135j. Epub 2011 Feb 14.

Since the discovery of covalently-bound mid- and late-transition metal carbenes there has been a spectacular explosion of interest in their chemistry, but their early metal counterparts have lagged behind. In recent years, bis(phosphorus-stabilised)carbenes have emerged as valuable ligands for...

A Very Short Uranium(IV)-Rhodium(I) Bond with Net Double-Dative Bonding Character.

Angewandte Chemie (International ed. in English)

Lu E, Wooles AJ, Gregson M, Cobb PJ, Liddle ST.
PMID: 29665209
Angew Chem Int Ed Engl. 2018 May 28;57(22):6587-6591. doi: 10.1002/anie.201803493. Epub 2018 Apr 27.

Reaction of [U{C(SiMe

Crystalline Diuranium Phosphinidiide and μ-Phosphido Complexes with Symmetric and Asymmetric UPU Cores.

Angewandte Chemie (International ed. in English)

Rookes TM, Gardner BM, Balázs G, Gregson M, Tuna F, Wooles AJ, Scheer M, Liddle ST.
PMID: 28677144
Angew Chem Int Ed Engl. 2017 Aug 21;56(35):10495-10500. doi: 10.1002/anie.201706002. Epub 2017 Jul 24.

Reaction of [U(Tren

Thorium- and uranium-azide reductions: a transient dithorium-nitride .

Chemical science

Du J, King DM, Chatelain L, Lu E, Tuna F, McInnes EJL, Wooles AJ, Maron L, Liddle ST.
PMID: 30996964
Chem Sci. 2019 Feb 23;10(13):3738-3745. doi: 10.1039/c8sc05473h. eCollection 2019 Apr 07.

Molecular uranium-nitrides are now well known, but there are no isolable molecular thorium-nitrides outside of cryogenic matrix isolation experiments. We report that treatment of [M(Tren

Preparation of Heterobimetallic Ketimido-Actinide-Molybdenum Complexes.

Inorganic chemistry

Ayres AJ, Wooles AJ, Zegke M, Tuna F, Liddle ST.
PMID: 31532645
Inorg Chem. 2019 Oct 07;58(19):13077-13089. doi: 10.1021/acs.inorgchem.9b01993. Epub 2019 Sep 18.

During our attempts to prepare paddlewheel actinide-molybdenum complexes of the type [(X)An(MesNPR

Trapping of a Highly Bent and Reduced Form of 2-Phosphaethynolate in a Mixed-Valence Diuranium-Triamidoamine Complex.

Angewandte Chemie (International ed. in English)

Magnall R, Balázs G, Lu E, Tuna F, Wooles AJ, Scheer M, Liddle ST.
PMID: 31125153
Angew Chem Int Ed Engl. 2019 Jul 22;58(30):10215-10219. doi: 10.1002/anie.201904676. Epub 2019 Jun 13.

The chemistry of 2-phosphaethynolate is burgeoning, but there remains much to learn about this ligand, for example its reduction chemistry is scarce as this promotes P-C-O fragmentations or couplings. Here, we report that reduction of [U(Tren

Correlating axial and equatorial ligand field effects to the single-molecule magnet performances of a family of dysprosium bis-methanediide complexes.

Chemical science

Thomas-Hargreaves LR, Giansiracusa MJ, Gregson M, Zanda E, O'Donnell F, Wooles AJ, Chilton NF, Liddle ST.
PMID: 34163660
Chem Sci. 2021 Mar 02;12(11):3911-3920. doi: 10.1039/d1sc00238d.

Treatment of the new methanediide-methanide complex [Dy(SCS)(SCSH)(THF)] (

Performance Characteristics of the Ultrasound Strategy during Incidence Screening in the UK Collaborative Trial of Ovarian Cancer Screening (UKCTOCS).

Cancers

Kalsi J, Gentry-Maharaj A, Ryan A, Singh N, Burnell M, Massingham S, Apostolidou S, Sharma A, Williamson K, Seif M, Mould T, Woolas R, Dobbs S, Leeson S, Fallowfield L, Skates SJ, Parmar M, Campbell S, Jacobs I, McGuire A, Menon U.
PMID: 33670571
Cancers (Basel). 2021 Feb 18;13(4). doi: 10.3390/cancers13040858.

Randomised controlled trials of ovarian cancer (OC) screening have not yet demonstrated an impact on disease mortality. Meanwhile, the screening data from clinical trials represents a rich resource to understand the performance of modalities used. We report here on...

Showing 1 to 12 of 69 entries