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Showing 1 to 12 of 50 entries
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Electrons Mediate the Gas-Phase Oxidation of Formic Acid with Ozone.

Chemistry (Weinheim an der Bergstrasse, Germany)

van der Linde C, Tang WK, Siu CK, Beyer MK.
PMID: 27400953
Chemistry. 2016 Aug 26;22(36):12684-7. doi: 10.1002/chem.201603080. Epub 2016 Aug 01.

Gas-phase reactions of CO3 (.-) with formic acid are studied using Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. Signal loss indicates the release of a free electron, with the formation of neutral reaction products. This is corroborated by...

Photochemistry of glyoxylate embedded in sodium chloride clusters, a laboratory model for tropospheric sea-salt aerosols.

Physical chemistry chemical physics : PCCP

Bersenkowitsch NK, Ončák M, van der Linde C, Herburger A, Beyer MK.
PMID: 29517776
Phys Chem Chem Phys. 2018 Mar 28;20(12):8143-8151. doi: 10.1039/c8cp00399h. Epub 2018 Mar 08.

Although marine aerosols undergo extensive photochemical processing in the troposphere, a molecular level understanding of the elementary steps involved in these complex reaction sequences is still missing. As a defined laboratory model system, the photodissociation of sea salt clusters...

The structure of gas-phase [Al·nH2O]+: hydrated monovalent aluminium Al+ (H2O)n or hydride-hydroxide HAlOH+ (H2O)(n-1)?.

Physical chemistry chemical physics : PCCP

van der Linde C, Beyer MK.
PMID: 21399775
Phys Chem Chem Phys. 2011 Apr 21;13(15):6776-8. doi: 10.1039/c1cp00048a. Epub 2011 Mar 11.

Theoretical studies predict that [Al·nH(2)O](+) clusters are present as hydride-hydroxide species HAlOH(+)(H(2)O)(n-1) in gas-phase experiments, energetically favoured by 200 kJ mol(-1) over Al(+)(H(2)O)(n). After collisions with D(2)O, however, no H/D scrambling occurs between H(2)O and D(2)O in clusters with...

Selective formic acid synthesis from nanoscale electrochemistry.

Angewandte Chemie (International ed. in English)

Höckendorf RF, Siu CK, van der Linde C, Balaj OP, Beyer MK.
PMID: 20859983
Angew Chem Int Ed Engl. 2010 Oct 25;49(44):8257-9. doi: 10.1002/anie.201004134.

No abstract available.

The reaction of CF2Cl2 with gas-phase hydrated electrons.

Physical chemistry chemical physics : PCCP

Lengyel J, van der Linde C, Fárník M, Beyer MK.
PMID: 27523883
Phys Chem Chem Phys. 2016 Sep 14;18(34):23910-5. doi: 10.1039/c6cp01976e. Epub 2016 Aug 15.

The reaction of dichlorodifluoromethane (CF2Cl2) with hydrated electrons (H2O)n(-) (n = 30-86) in the gas phase was studied using Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. The hydrated electron reacts with CF2Cl2, forming (H2O)mCl(-) with a rate constant...

Diatomic [CuO]+ and its role in the spin-selective hydrogen- and oxygen-atom transfers in the thermal activation of methane.

Angewandte Chemie (International ed. in English)

Dietl N, van der Linde C, Schlangen M, Beyer MK, Schwarz H.
PMID: 21520367
Angew Chem Int Ed Engl. 2011 May 16;50(21):4966-9. doi: 10.1002/anie.201100606. Epub 2011 Apr 21.

No abstract available.

Photochemical Hydrogen Evolution at Metal Centers Probed with Hydrated Aluminium Cations, Al.

Chemistry (Weinheim an der Bergstrasse, Germany)

Heller J, Pascher TF, van der Linde C, Ončák M, Beyer MK.
PMID: 34636449
Chemistry. 2021 Nov 25;27(66):16367-16376. doi: 10.1002/chem.202103289. Epub 2021 Nov 05.

Hydrated aluminium cations have been investigated as a photochemical model system with up to ten water molecules by UV action spectroscopy in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Intense photodissociation was observed starting at 4.5 eV...

Cell-Type-Specific Circadian Bioluminescence Rhythms in .

Journal of biological rhythms

Smith CB, van der Vinne V, McCartney E, Stowie AC, Leise TL, Martin-Burgos B, Molyneux PC, Garbutt LA, Brodsky MH, Davidson AJ, Harrington ME, Dallmann R, Weaver DR.
PMID: 35023384
J Biol Rhythms. 2022 Jan 13;7487304211069452. doi: 10.1177/07487304211069452. Epub 2022 Jan 13.

Circadian rhythms are endogenously generated physiological and molecular rhythms with a cycle length of about 24 h. Bioluminescent reporters have been exceptionally useful for studying circadian rhythms in numerous species. Here, we report development of a reporter mouse generated...

Gas-Phase Reactivity Studies of Small Molybdenum Cluster Ions with Dimethyl Disulfide.

Topics in catalysis

Baloglou A, Ončák M, van der Linde C, Beyer MK.
PMID: 31258300
Top Catal. 2018;61(1):20-27. doi: 10.1007/s11244-017-0864-3. Epub 2017 Nov 27.

Molybdenum sulfide is a potent hydrogen evolution catalyst, and is discussed as a replacement of platinum in large-scale electrochemical hydrogen production. To learn more about the elementary steps of MoS

Getting Ready for the Hydrogen Evolution Reaction: The Infrared Spectrum of Hydrated Aluminum Hydride-Hydroxide HAlOH.

Angewandte Chemie (International ed. in English)

Heller J, Tang WK, Cunningham EM, Demissie EG, van der Linde C, Lam WK, Ončák M, Siu CK, Beyer MK.
PMID: 34008243
Angew Chem Int Ed Engl. 2021 Jul 26;60(31):16858-16863. doi: 10.1002/anie.202105166. Epub 2021 Jun 04.

Hydrated singly charged aluminum ions eliminate molecular hydrogen in a size regime from 11 to 24 water molecules. Here we probe the structure of HAlOH

Structural Properties of Gas Phase Molybdenum Sulfide Clusters [Mo.

The journal of physical chemistry. C, Nanomaterials and interfaces

Baloglou A, Ončák M, Grutza ML, van der Linde C, Kurz P, Beyer MK.
PMID: 30984322
J Phys Chem C Nanomater Interfaces. 2019 Apr 04;123(13):8177-8186. doi: 10.1021/acs.jpcc.8b08324. Epub 2018 Oct 16.

Amorphous molybdenum sulfide (MoS

Decomposition of Copper Formate Clusters: Insight into Elementary Steps of Calcination and Carbon Dioxide Activation.

ChemistryOpen

Pascher TF, Ončák M, van der Linde C, Beyer MK.
PMID: 31871848
ChemistryOpen. 2019 Dec 17;8(12):1453-1459. doi: 10.1002/open.201900282. eCollection 2019 Dec.

The decomposition of copper formate clusters is investigated in the gas phase by infrared multiple photon dissociation of Cu(II)

Showing 1 to 12 of 50 entries