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Showing 1 to 12 of 63 entries
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Ru/Cu Photoredox or Cu/Ag Catalyzed C4-H Sulfonylation of 1-Naphthylamides at Room Temperature.

The Journal of organic chemistry

Bai P, Sun S, Li Z, Qiao H, Su X, Yang F, Wu Y, Wu Y.
PMID: 29039195
J Org Chem. 2017 Dec 01;82(23):12119-12127. doi: 10.1021/acs.joc.7b01917. Epub 2017 Nov 01.

A mild and efficient protocol for C4-H sulfonylation of 1-naphthylamine derivatives with sodium sulfinates has been described. This C4 sulfonylation proceeded smoothly at room temperature under Ru/Cu photoredox catalysis or Cu/Ag cocatalysis and could tolerate various functional groups. In...

Localization of membrane-associated calcium following cytokinin treatment in Funaria using chlorotetracycline.

Planta

Saunders MJ, Hepler PK.
PMID: 24302427
Planta. 1981 Jul;152(3):272-81. doi: 10.1007/BF00385156.

We have investigated the changes in membrane-associated calcium that occur during cytokinin induced bud formation in Funaria hygrometrica Hedw. using the fluorescent Ca(2+)-chelate probe chlorotetracycline (CTC). In the target caulonema cells a localization of CTC fluorescent material becomes evident...

Reaction of alpha-oxoketene-N,S-arylaminoacetals with Vilsmeier reagents: an efficient route to highly functionalized quinolines and their benzo/hetero-fused analogues.

The Journal of organic chemistry

Mahata PK, Venkatesh C, Syam Kumar UK, Ila H, Junjappa H.
PMID: 12737579
J Org Chem. 2003 May 16;68(10):3966-75. doi: 10.1021/jo034053l.

A simple, highly efficient, and regioselective synthesis of functionalized quinolines through Vilsmeier cyclization of a variety of alpha-oxoketene-N,S-anilinoacetals has been reported. The cyclization is found to be facile with N,S-acetals bearing strongly activating groups on aniline, whereas yields of...

Selective potentiometric determination of nitrite ion using a novel (4-sulphophenylazo-)1-naphthylamine membrane sensor.

Talanta

Hassan SS, Marzouk SA, Sayour HE.
PMID: 18969014
Talanta. 2003 May 01;59(6):1237-44. doi: 10.1016/S0039-9140(03)00034-1.

A novel polymeric membrane sensor sensitive to (4-sulphophenylazo-)1-naphthylamine (SPAN) based on the use of tris(bathophenanthroline) Ni(II)-SPAN ion pair as an ion exchanger in plasticised PVC membrane is described. The sensor exhibits a linear calibration plot with near-Nernstian anionic slope...

Application of microwave-assisted desorption/headspace solid-phase microextraction as pretreatment step in the gas chromatographic determination of 1-naphthylamine in silica gel adsorbent.

Talanta

Yan CT, Jen JF, Shih TS.
PMID: 19071553
Talanta. 2007 Mar 30;71(5):1993-7. doi: 10.1016/j.talanta.2006.09.005. Epub 2006 Oct 17.

Pretreatment of silica gel sample containing 1-naphthylamine by microwave-assisted desorption (MAD) coupled to in situ headspace solid phase microextraction (HS-SPME) has been investigated as a possible alternative to conventional methods prior to gas chromatographic (GC) analysis. The 1-naphthylamine desorbs...

Comparison of Complexation-Induced pK.

The journal of physical chemistry. B

Lazar AI, Rohacova J, Nau WM.
PMID: 29168919
J Phys Chem B. 2017 Dec 21;121(50):11390-11398. doi: 10.1021/acs.jpcb.7b10651. Epub 2017 Dec 11.

1-Aminopyrene and 1-naphthylamine-5-sulfonic acid were converted to the putrescine (1,4-diaminobutane)-substituted derivatives (dyes 1 and 2). The diaminobutyl anchor serves as a common binding motive for cation-receptor macrocycles such as cucurbit[n]urils (n = 6-8) and p-sulfonatocalix[4]arene. When protonated, they are...

Palladium-Catalyzed C8-H Acylation of 1-Naphthylamines with Acyl Chlorides.

Organic letters

Yu X, Yang F, Wu Y, Wu Y.
PMID: 30843701
Org Lett. 2019 Mar 15;21(6):1726-1729. doi: 10.1021/acs.orglett.9b00283. Epub 2019 Mar 07.

A facile and efficient protocol for palladium-catalyzed regioselective C8-H acylation of 1-naphthylamine derivatives with acyl chlorides has been developed. The reaction exhibits broad functional group tolerance, and both aromatic and α,β-unsaturated acyl chlorides can be effectively coupled with 1-naphthylamines....

Excitation spectroscopic and synchronous fluorescence spectroscopic analysis of the origin of aggregation-induced emission in N,N-diphenyl-1-naphthylamine-o-carborane derivatives.

Physical chemistry chemical physics : PCCP

Kim SY, Lee JD, Cho YJ, Son MR, Son HJ, Cho DW, Kang SO.
PMID: 29911708
Phys Chem Chem Phys. 2018 Jun 27;20(25):17458-17463. doi: 10.1039/c8cp02603c.

We have synthesised mono-(NpCb) and bis-[(N,N-phenyl-1-naphthylamino)benzo]-o-caboranes (NpCbNp), which show anomalously intense aggregation-induced emission (AIE) at long wavelengths and monomer emission at short wavelengths. The actual concentration of the aggregator in intense AIE is very low, so absorption spectroscopy is...

The Effect of Molecular Properties on Active Ingredient Release from Electrospun Eudragit Fibers.

Pharmaceutics

Burgess K, Li H, Abo-Zeid Y, Williams GR.
PMID: 30042323
Pharmaceutics. 2018 Jul 24;10(3). doi: 10.3390/pharmaceutics10030103.

The formation of nanoscale fibers from pH-sensitive polymers is a route which has been widely explored for targeted drug delivery. In particular, the Eudragit L100 and S100 families of polymers have received significant attention for this purpose. However, while...

Towards enantioselective ultrahigh performance liquid chromatography-mass spectrometry-based metabolomics of branched-chain fatty acids and anteiso-fatty acids under reversed-phase conditions using sub-2-μm amylose- and cellulose-derived chiral stationary phases.

Chirality

Geibel C, Zhang L, Serafimov K, Gross H, Lämmerhofer M.
PMID: 35032056
Chirality. 2022 Jan 14; doi: 10.1002/chir.23413. Epub 2022 Jan 14.

Branched-chain fatty acids (BCFAs) are mostly saturated fatty acids with one or more methyl, seldom ethyl, branches in the alkyl chain. They are derived from branched-chain amino acids, ruminant-derived food, or biosynthetic side products of acetyl-CoA carboxylase. They possess...

Experimental and Theoretical Studies of Novel Azo Benzene Functionalized Conjugated Polymers: In-vitro Antileishmanial Activity and Bioimaging.

Scientific reports

Singh N, Arish M, Kumar P, Rub A, Riaz U.
PMID: 31919477
Sci Rep. 2020 Jan 09;10(1):57. doi: 10.1038/s41598-019-56975-x.

To study the effect of insertion of azobenzene moiety on the spectral, morphological and fluorescence properties of conventional conducting polymers, the present work reports ultrasound-assisted polymerization of azobenzene with aniline, 1-naphthylamine, luminol and o-phenylenediamine. The chemical structure and polymerization...

Palladium-catalyzed C8-H alkoxycarbonylation of 1-naphthylamines with alkyl chloroformates.

Organic & biomolecular chemistry

Shi Y, Yang F, Wu Y.
PMID: 32520064
Org Biomol Chem. 2020 Jun 24;18(24):4628-4637. doi: 10.1039/d0ob00586j.

A simple and efficient protocol for palladium-catalyzed C8-H alkoxycarbonylation of 1-naphthylamine derivatives with alkyl chloroformates has been developed, exhibiting broad functional group tolerance, high regioselectivity, and oxidant-free conditions. Furthermore, the reaction features its ease of further functionalization and transformation....

Showing 1 to 12 of 63 entries