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A Key concept in Magnesium Secondary Battery Electrolytes.

ChemSusChem

Bertasi F, Hettige C, Sepehr F, Bogle X, Pagot G, Vezzù K, Negro E, Paddison SJ, Greenbaum SG, Vittadello M, Di Noto V.
PMID: 26333149
ChemSusChem. 2015 Sep 21;8(18):3069-76. doi: 10.1002/cssc.201500339. Epub 2015 Sep 02.

A critical roadblock toward practical Mg-based energy storage technologies is the lack of reversible electrolytes that are safe and electrochemically stable. Here, we report on high-performance electrolytes based on 1-ethyl-3-methylimidazolium chloride (EMImCl) doped with AlCl3 and highly amorphous δ-MgCl2...

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Bertasi F, Hettige C, Sepehr F, et al. A Key concept in Magnesium Secondary Battery Electrolytes. ChemSusChem. 2015;8(18):3069-76doi: 10.1002/cssc.201500339.
Bertasi, F., Hettige, C., Sepehr, F., Bogle, X., Pagot, G., Vezzù, K., Negro, E., Paddison, S. J., Greenbaum, S. G., Vittadello, M., & Di Noto, V. (2015). A Key concept in Magnesium Secondary Battery Electrolytes. ChemSusChem, 8(18), 3069-76. https://doi.org/10.1002/cssc.201500339
Bertasi, Federico, et al. "A Key concept in Magnesium Secondary Battery Electrolytes." ChemSusChem vol. 8,18 (2015): 3069-76. doi: https://doi.org/10.1002/cssc.201500339
Bertasi F, Hettige C, Sepehr F, Bogle X, Pagot G, Vezzù K, Negro E, Paddison SJ, Greenbaum SG, Vittadello M, Di Noto V. A Key concept in Magnesium Secondary Battery Electrolytes. ChemSusChem. 2015 Sep 21;8(18):3069-76. doi: 10.1002/cssc.201500339. Epub 2015 Sep 02. PMID: 26333149.
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Immobilizing Tetraphenylethylene into Fused Metallacycles: Shape Effects on Fluorescence Emission.

Journal of the American Chemical Society

Zhou Z, Yan X, Saha ML, Zhang M, Wang M, Li X, Stang PJ.
PMID: 27672700
J Am Chem Soc. 2016 Oct 12;138(40):13131-13134. doi: 10.1021/jacs.6b07173. Epub 2016 Oct 04.

Herein, we describe the selective formation of a discrete fused metallarhomboid and a triangle by the careful control of the shape and stoichiometry of the building blocks. A tetraphenylethylene (TPE)-based tetrapyridyl donor is exploited as the bridging component, and...

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Zhou Z, Yan X, Saha ML, et al. Immobilizing Tetraphenylethylene into Fused Metallacycles: Shape Effects on Fluorescence Emission. J Am Chem Soc. 2016;138(40):13131-13134doi: 10.1021/jacs.6b07173.
Zhou, Z., Yan, X., Saha, M. L., Zhang, M., Wang, M., Li, X., & Stang, P. J. (2016). Immobilizing Tetraphenylethylene into Fused Metallacycles: Shape Effects on Fluorescence Emission. Journal of the American Chemical Society, 138(40), 13131-13134. https://doi.org/10.1021/jacs.6b07173
Zhou, Zhixuan, et al. "Immobilizing Tetraphenylethylene into Fused Metallacycles: Shape Effects on Fluorescence Emission." Journal of the American Chemical Society vol. 138,40 (2016): 13131-13134. doi: https://doi.org/10.1021/jacs.6b07173
Zhou Z, Yan X, Saha ML, Zhang M, Wang M, Li X, Stang PJ. Immobilizing Tetraphenylethylene into Fused Metallacycles: Shape Effects on Fluorescence Emission. J Am Chem Soc. 2016 Oct 12;138(40):13131-13134. doi: 10.1021/jacs.6b07173. Epub 2016 Oct 04. PMID: 27672700.
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Using invariom modelling to distinguish correct and incorrect central atoms in `duplicate structures' with neighbouring 3d elements.

Acta crystallographica Section B, Structural science, crystal engineering and materials

Wandtke CM, Weil M, Simpson J, Dittrich B.
PMID: 28980983
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2017 Oct 01;73:794-804. doi: 10.1107/S2052520617010745. Epub 2017 Sep 29.

Modelling coordination compounds has been shown to be feasible using the invariom method; for the best fit to a given set of diffraction data, additional steps other than using lookup tables of scattering factors need to be carried out....

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Wandtke CM, Weil M, Simpson J, et al. Using invariom modelling to distinguish correct and incorrect central atoms in `duplicate structures' with neighbouring 3d elements. Acta Crystallogr B Struct Sci Cryst Eng Mater. 2017;73:794-804doi: 10.1107/S2052520617010745.
Wandtke, C. M., Weil, M., Simpson, J., & Dittrich, B. (2017). Using invariom modelling to distinguish correct and incorrect central atoms in `duplicate structures' with neighbouring 3d elements. Acta crystallographica Section B, Structural science, crystal engineering and materials, 73794-804. https://doi.org/10.1107/S2052520617010745
Wandtke, Claudia M, et al. "Using invariom modelling to distinguish correct and incorrect central atoms in `duplicate structures' with neighbouring 3d elements." Acta crystallographica Section B, Structural science, crystal engineering and materials vol. 73 (2017): 794-804. doi: https://doi.org/10.1107/S2052520617010745
Wandtke CM, Weil M, Simpson J, Dittrich B. Using invariom modelling to distinguish correct and incorrect central atoms in `duplicate structures' with neighbouring 3d elements. Acta Crystallogr B Struct Sci Cryst Eng Mater. 2017 Oct 01;73:794-804. doi: 10.1107/S2052520617010745. Epub 2017 Sep 29. PMID: 28980983; PMCID: PMC5628397.
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Lanthanide coordination complexes framed by sodium ions: slow relaxation of the magnetization in the Dy(III) derivative.

Dalton transactions (Cambridge, England : 2003)

Konstantatos A, Sørensen MA, Bendix J, Weihe H.
PMID: 28426044
Dalton Trans. 2017 May 09;46(18):6024-6030. doi: 10.1039/c7dt00863e.

Using a new polydentate Schiff-base ligand (H

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Konstantatos A, Sørensen MA, Bendix J, et al. Lanthanide coordination complexes framed by sodium ions: slow relaxation of the magnetization in the Dy(III) derivative. Dalton Trans. 2017;46(18):6024-6030doi: 10.1039/c7dt00863e.
Konstantatos, A., Sørensen, M. A., Bendix, J., & Weihe, H. (2017). Lanthanide coordination complexes framed by sodium ions: slow relaxation of the magnetization in the Dy(III) derivative. Dalton transactions (Cambridge, England : 2003), 46(18), 6024-6030. https://doi.org/10.1039/c7dt00863e
Konstantatos, Andreas, et al. "Lanthanide coordination complexes framed by sodium ions: slow relaxation of the magnetization in the Dy(III) derivative." Dalton transactions (Cambridge, England : 2003) vol. 46,18 (2017): 6024-6030. doi: https://doi.org/10.1039/c7dt00863e
Konstantatos A, Sørensen MA, Bendix J, Weihe H. Lanthanide coordination complexes framed by sodium ions: slow relaxation of the magnetization in the Dy(III) derivative. Dalton Trans. 2017 May 09;46(18):6024-6030. doi: 10.1039/c7dt00863e. PMID: 28426044.
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Unique trapping of paddlewheel copper(ii) carboxylate by ligand-bound {Cu2} fragments for [Cu6] assembly.

Dalton transactions (Cambridge, England : 2003)

Chattopadhyay K, Shaw BK, Saha SK, Ray D.
PMID: 26979289
Dalton Trans. 2016 Apr 28;45(16):6928-38. doi: 10.1039/c6dt00103c.

The bridging nature of in situ generated hydroxide ions and carboxylates (RCOO(-); R = CH3, C2H5, CH2Ph) has been utilized to design a new family of [Cu6] coordination complexes: [Cu6(μ3-OH)2(μ-H2L)2(μ1,1,3-O2CCH3)2(μ1,3-O2CCH3)2(μ-ClO4)2](ClO4)2·H2O (), [Cu6(μ3-OH)2(μ-H2L)2(μ1,1,3-O2CC2H5)4(μ-ClO4)2](ClO4)2·2H2O () and [Cu6(μ3-OH)2(μ-H2L)2(μ1,3-O2CCH2Ph)4(ClO4)2](ClO4)2·2H2O (). Tetracarboxylate bridged {Cu2}...

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Chattopadhyay K, Shaw BK, Saha SK, et al. Unique trapping of paddlewheel copper(ii) carboxylate by ligand-bound {Cu2} fragments for [Cu6] assembly. Dalton Trans. 2016;45(16):6928-38doi: 10.1039/c6dt00103c.
Chattopadhyay, K., Shaw, B. K., Saha, S. K., & Ray, D. (2016). Unique trapping of paddlewheel copper(ii) carboxylate by ligand-bound {Cu2} fragments for [Cu6] assembly. Dalton transactions (Cambridge, England : 2003), 45(16), 6928-38. https://doi.org/10.1039/c6dt00103c
Chattopadhyay, Krishna, et al. "Unique trapping of paddlewheel copper(ii) carboxylate by ligand-bound {Cu2} fragments for [Cu6] assembly." Dalton transactions (Cambridge, England : 2003) vol. 45,16 (2016): 6928-38. doi: https://doi.org/10.1039/c6dt00103c
Chattopadhyay K, Shaw BK, Saha SK, Ray D. Unique trapping of paddlewheel copper(ii) carboxylate by ligand-bound {Cu2} fragments for [Cu6] assembly. Dalton Trans. 2016 Apr 28;45(16):6928-38. doi: 10.1039/c6dt00103c. PMID: 26979289.
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Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy).

Inorganic chemistry

Jepsen LH, Ley MB, Černý R, Lee YS, Cho YW, Ravnsbæk D, Besenbacher F, Skibsted J, Jensen TR.
PMID: 26196159
Inorg Chem. 2015 Aug 03;54(15):7402-14. doi: 10.1021/acs.inorgchem.5b00951. Epub 2015 Jul 21.

Fourteen solvent- and halide-free ammine rare-earth metal borohydrides M(BH4)3·nNH3, M = Y, Gd, Dy, n = 7, 6, 5, 4, 2, and 1, have been synthesized by a new approach, and their structures as well as chemical and physical...

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Jepsen LH, Ley MB, Černý R, et al. Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy). Inorg Chem. 2015;54(15):7402-14doi: 10.1021/acs.inorgchem.5b00951.
Jepsen, L. H., Ley, M. B., Černý, R., Lee, Y. S., Cho, Y. W., Ravnsbæk, D., Besenbacher, F., Skibsted, J., & Jensen, T. R. (2015). Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy). Inorganic chemistry, 54(15), 7402-14. https://doi.org/10.1021/acs.inorgchem.5b00951
Jepsen, Lars H, et al. "Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy)." Inorganic chemistry vol. 54,15 (2015): 7402-14. doi: https://doi.org/10.1021/acs.inorgchem.5b00951
Jepsen LH, Ley MB, Černý R, Lee YS, Cho YW, Ravnsbæk D, Besenbacher F, Skibsted J, Jensen TR. Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy). Inorg Chem. 2015 Aug 03;54(15):7402-14. doi: 10.1021/acs.inorgchem.5b00951. Epub 2015 Jul 21. PMID: 26196159.
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Highly emissive platinum(II) metallacages.

Nature chemistry

Yan X, Cook TR, Wang P, Huang F, Stang PJ.
PMID: 25803473
Nat Chem. 2015 Apr;7(4):342-8. doi: 10.1038/nchem.2201. Epub 2015 Mar 16.

Light-emitting materials, especially those with tunable wavelengths, attract considerable attention for applications in optoelectronic devices, fluorescent probes, sensors and so on. Many species evaluated for these purposes either emit as a dilute solution or on aggregation, with the former...

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Yan X, Cook TR, Wang P, et al. Highly emissive platinum(II) metallacages. Nat Chem. 2015;7(4):342-8doi: 10.1038/nchem.2201.
Yan, X., Cook, T. R., Wang, P., Huang, F., & Stang, P. J. (2015). Highly emissive platinum(II) metallacages. Nature chemistry, 7(4), 342-8. https://doi.org/10.1038/nchem.2201
Yan, Xuzhou, et al. "Highly emissive platinum(II) metallacages." Nature chemistry vol. 7,4 (2015): 342-8. doi: https://doi.org/10.1038/nchem.2201
Yan X, Cook TR, Wang P, Huang F, Stang PJ. Highly emissive platinum(II) metallacages. Nat Chem. 2015 Apr;7(4):342-8. doi: 10.1038/nchem.2201. Epub 2015 Mar 16. PMID: 25803473.
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Deciphering the Conformational Choreography of Zinc Coordination Complexes with Standard and Novel Proton NMR Techniques Combined with DFT Methods.

Chemphyschem : a European journal of chemical physics and physical chemistry

Pucheta JE, Prim D, Gillet JM, Farjon J.
PMID: 26845749
Chemphyschem. 2016 Apr 04;17(7):1034-45. doi: 10.1002/cphc.201501114. Epub 2016 Feb 04.

The presence of water has been shown to deeply impact the stability and geometry of Zn complexes in solution. Evidence for tetra- and penta-coordinated species in a pyridylmethylamine-Zn(II) model complex is presented. Novel (1) H NMR tools such as...

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Pucheta JE, Prim D, Gillet JM, et al. Deciphering the Conformational Choreography of Zinc Coordination Complexes with Standard and Novel Proton NMR Techniques Combined with DFT Methods. Chemphyschem. 2016;17(7):1034-45doi: 10.1002/cphc.201501114.
Pucheta, J. E., Prim, D., Gillet, J. M., & Farjon, J. (2016). Deciphering the Conformational Choreography of Zinc Coordination Complexes with Standard and Novel Proton NMR Techniques Combined with DFT Methods. Chemphyschem : a European journal of chemical physics and physical chemistry, 17(7), 1034-45. https://doi.org/10.1002/cphc.201501114
Pucheta, Jose Enrique Herbert, et al. "Deciphering the Conformational Choreography of Zinc Coordination Complexes with Standard and Novel Proton NMR Techniques Combined with DFT Methods." Chemphyschem : a European journal of chemical physics and physical chemistry vol. 17,7 (2016): 1034-45. doi: https://doi.org/10.1002/cphc.201501114
Pucheta JE, Prim D, Gillet JM, Farjon J. Deciphering the Conformational Choreography of Zinc Coordination Complexes with Standard and Novel Proton NMR Techniques Combined with DFT Methods. Chemphyschem. 2016 Apr 04;17(7):1034-45. doi: 10.1002/cphc.201501114. Epub 2016 Feb 04. PMID: 26845749.
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Divalent and trivalent gas-phase coordination complexes of californium: evaluating the stability of Cf(ii).

Dalton transactions (Cambridge, England : 2003)

Dau PD, Shuh DK, Sturzbecher-Hoehne M, Abergel RJ, Gibson JK.
PMID: 27424652
Dalton Trans. 2016 Aug 02;45(31):12338-45. doi: 10.1039/c6dt02414a.

The divalent oxidation state is increasingly stable relative to the trivalent state for the later actinide elements, with californium the first actinide to exhibit divalent chemistry under moderate conditions. Although there is evidence for divalent Cf in solution and...

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Dau PD, Shuh DK, Sturzbecher-Hoehne M, et al. Divalent and trivalent gas-phase coordination complexes of californium: evaluating the stability of Cf(ii). Dalton Trans. 2016;45(31):12338-45doi: 10.1039/c6dt02414a.
Dau, P. D., Shuh, D. K., Sturzbecher-Hoehne, M., Abergel, R. J., & Gibson, J. K. (2016). Divalent and trivalent gas-phase coordination complexes of californium: evaluating the stability of Cf(ii). Dalton transactions (Cambridge, England : 2003), 45(31), 12338-45. https://doi.org/10.1039/c6dt02414a
Dau, Phuong D, et al. "Divalent and trivalent gas-phase coordination complexes of californium: evaluating the stability of Cf(ii)." Dalton transactions (Cambridge, England : 2003) vol. 45,31 (2016): 12338-45. doi: https://doi.org/10.1039/c6dt02414a
Dau PD, Shuh DK, Sturzbecher-Hoehne M, Abergel RJ, Gibson JK. Divalent and trivalent gas-phase coordination complexes of californium: evaluating the stability of Cf(ii). Dalton Trans. 2016 Aug 02;45(31):12338-45. doi: 10.1039/c6dt02414a. PMID: 27424652.
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Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism.

Dalton transactions (Cambridge, England : 2003)

Krzystek J, Telser J.
PMID: 27722619
Dalton Trans. 2016 Oct 25;45(42):16751-16763. doi: 10.1039/c6dt01754a.

"Giant magnetic anisotropy" is a phenomenon identified fairly recently in coordination complexes of nd- and nf-block ions. It can have different origins but is commonly (if not always correctly) described through zero-field splitting (ZFS), which can reach values of...

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Krzystek J, Telser J. Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism. Dalton Trans. 2016;45(42):16751-16763doi: 10.1039/c6dt01754a.
Krzystek, J., & Telser, J. (2016). Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism. Dalton transactions (Cambridge, England : 2003), 45(42), 16751-16763. https://doi.org/10.1039/c6dt01754a
Krzystek, J, and Telser, Joshua. "Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism." Dalton transactions (Cambridge, England : 2003) vol. 45,42 (2016): 16751-16763. doi: https://doi.org/10.1039/c6dt01754a
Krzystek J, Telser J. Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism. Dalton Trans. 2016 Oct 25;45(42):16751-16763. doi: 10.1039/c6dt01754a. PMID: 27722619.
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Light-induced relaxation dynamics of the ferricyanide ion revisited by ultrafast XUV photoelectron spectroscopy.

Physical chemistry chemical physics : PCCP

Engel N, Bokarev SI, Moguilevski A, Raheem AA, Al-Obaidi R, Möhle T, Grell G, Siefermann KR, Abel B, Aziz SG, Kühn O, Borgwardt M, Kiyan IY, Aziz EF.
PMID: 28534587
Phys Chem Chem Phys. 2017 Jun 07;19(22):14248-14255. doi: 10.1039/c7cp01288h.

Photoinduced charge transfer in transition-metal coordination complexes plays a prominent role in photosynthesis and is fundamental for light-harvesting processes in catalytic materials. However, revealing the relaxation pathways of charge separation remains a very challenging task because of the complexity...

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Engel N, Bokarev SI, Moguilevski A, et al. Light-induced relaxation dynamics of the ferricyanide ion revisited by ultrafast XUV photoelectron spectroscopy. Phys Chem Chem Phys. 2017;19(22):14248-14255doi: 10.1039/c7cp01288h.
Engel, N., Bokarev, S. I., Moguilevski, A., Raheem, A. A., Al-Obaidi, R., Möhle, T., Grell, G., Siefermann, K. R., Abel, B., Aziz, S. G., Kühn, O., Borgwardt, M., Kiyan, I. Y., & Aziz, E. F. (2017). Light-induced relaxation dynamics of the ferricyanide ion revisited by ultrafast XUV photoelectron spectroscopy. Physical chemistry chemical physics : PCCP, 19(22), 14248-14255. https://doi.org/10.1039/c7cp01288h
Engel, Nicholas, et al. "Light-induced relaxation dynamics of the ferricyanide ion revisited by ultrafast XUV photoelectron spectroscopy." Physical chemistry chemical physics : PCCP vol. 19,22 (2017): 14248-14255. doi: https://doi.org/10.1039/c7cp01288h
Engel N, Bokarev SI, Moguilevski A, Raheem AA, Al-Obaidi R, Möhle T, Grell G, Siefermann KR, Abel B, Aziz SG, Kühn O, Borgwardt M, Kiyan IY, Aziz EF. Light-induced relaxation dynamics of the ferricyanide ion revisited by ultrafast XUV photoelectron spectroscopy. Phys Chem Chem Phys. 2017 Jun 07;19(22):14248-14255. doi: 10.1039/c7cp01288h. PMID: 28534587.
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A family of Ru(II) complexes built on a novel sexipyridine building block: synthesis, photophysical properties and the rare structural characterization of a triruthenium species.

Dalton transactions (Cambridge, England : 2003)

Laramée-Milette B, Lussier F, Ciofini I, Hanan GS.
PMID: 26037408
Dalton Trans. 2015 Jul 07;44(25):11551-61. doi: 10.1039/c5dt00631g.

A new tris-2'',4'',6''-(2,2'-bipyridin-4-yl)-1'',3'',5''-triazine ligand and its family of ruthenium coordination complexes are described along with their characterization by electrochemical and photophysical methods as well as a rare single crystal X-ray analysis of a triruthenium polypyridine complex.

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Laramée-Milette B, Lussier F, Ciofini I, et al. A family of Ru(II) complexes built on a novel sexipyridine building block: synthesis, photophysical properties and the rare structural characterization of a triruthenium species. Dalton Trans. 2015;44(25):11551-61doi: 10.1039/c5dt00631g.
Laramée-Milette, B., Lussier, F., Ciofini, I., & Hanan, G. S. (2015). A family of Ru(II) complexes built on a novel sexipyridine building block: synthesis, photophysical properties and the rare structural characterization of a triruthenium species. Dalton transactions (Cambridge, England : 2003), 44(25), 11551-61. https://doi.org/10.1039/c5dt00631g
Laramée-Milette, Baptiste, et al. "A family of Ru(II) complexes built on a novel sexipyridine building block: synthesis, photophysical properties and the rare structural characterization of a triruthenium species." Dalton transactions (Cambridge, England : 2003) vol. 44,25 (2015): 11551-61. doi: https://doi.org/10.1039/c5dt00631g
Laramée-Milette B, Lussier F, Ciofini I, Hanan GS. A family of Ru(II) complexes built on a novel sexipyridine building block: synthesis, photophysical properties and the rare structural characterization of a triruthenium species. Dalton Trans. 2015 Jul 07;44(25):11551-61. doi: 10.1039/c5dt00631g. PMID: 26037408.
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